Transcription of Carbonyl Chemistry - Fundamentals
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Carbonyl Chemistry - Fundamentals
Carbonyl Chemistry - FundamentalsImages and Information from:Bruice, P. Organic Chemistry , Pearsons Prentice Hall. 2004 Hardinger, S. Chemistry 14D: Thinkbook. 2006. Lecture Supplement: Carbonyl Chemistry FundamentalsCarbonyl group a carbon double bonded to an oxygenAcyl group Carbonyl group attached to an alkyl or aryl groupCarbonyl compounds- compounds containing Carbonyl groupsCarbonyl compounds can be divided into two classes:- Has a group attached to the acyl group that can function as a leaving groupCompoundStructureCarboxylicAcidEste rAmideCarboxylateAcyl chlorideAnhydrideThioesteroacyl halides, acid anhydrides, esters, thioesters, carboxylates, and amides are carboxylicacid derivatives because they differ only by the chemical group that has replaced theOH groupSystematic Nomenclature for Class I-Carboxylic AcidsoFunctional group = carboxyl group -replac
– H and alkyl or aryl (-R or -Ar) groups of aldehydes and ketones are too basic to be replaced by a nucleophile Systematical Nomenclature for Class II
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