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Chemical Engineering 160/260 Important …
Chemical Engineering 160/260 Important Concepts, Lecture 9-16 Lecture 9: Introduction to Thermodynamic Models for Polymer/Solvent (and Polymer/Polymer Mixing) - Configurational Entropy without any chains (two species arranged randomly on a lattice) - Ideal Solution for two species o dHmix = 0 o dSmix is configurational only o dSmix from boltzman equation - Non-ideal situations: o First consider links between monomer units o Second consider energy interactions between monomers and solvent molecules - Consider one species having connections between segments: o Derive an expression for # ways to arrange a polymer given i-1 polymers already placed on the lattice. Parameters include ! Z coordination number of lattice !
Chemical Engineering 160/260 Important Concepts, Lecture 9-16 Lecture 9: Introduction to Thermodynamic Models for Polymer/Solvent (and Polymer/Polymer
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