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CHROMIUM, HEXAVALENT 7600

chromium , HEXAVALENT 7600. Cr(VI) MW: (Cr); (CrO3) CAS: 18540-29-9 RTECS: GB6262000. METHOD: 7600, Issue 2 EVALUATION: FULL Issue 1: 15 May 1989. Issue 2: 15 August 1994. OSHA : mg/m 3 (as CrO 3) PROPERTIES: oxidizing agent NIOSH: mg/m 3/10 h; carcinogen ACGIH: mg/m 3 (as Cr, soluble); some insoluble chromates are human carcinogens SYNONYMS: vary depending upon the compound SAMPLING MEASUREMENT. SAMPLER: FILTER TECHNIQUE: VISIBLE ABSORPTION. ( m PVC membrane) SPECTROPHOTOMETRY. FLOW RATE: 1 to 4 L/min ANALYTE: CrO 42--diphenylcarbazide complex VOL-MIN: 8 L @ mg/m 3. -MAX: 400 L EXTRACTION SOLUTION: N H 2SO 4 or 2% NaOH- 3% Na 2CO 3 (see steps 4 and 5). SHIPMENT: routine WAVELENGTH: 540 nm; 5-cm path length SAMPLE.

P&CAM 169 and S317 are essentially the same method and are suitable for soluble chromate and chromic acid. Method S317 was validated with generated samples of chromic acid mist [2,6], and P&CAM 169 was tested with field samples [1,7]. P&CAM 319 was developed because a method was needed to analyze for insoluble chromates [3].

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  Chromium, Hexavalent, Comheart

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