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Complexometric Titrations - cffet.net

Chapter 5. Complexometric Titrations Complexometric Titrations are based on the formation of a soluble complex upon the reaction of the species titrated with the titrant. M + L ML. In the module Chemistry 2 you were introduced to the basic terms and concepts of metal complexes. Use the next section as revision of these terms and concepts. Components of a complex: Metal ion Ligand Multidentate ligands Chelate rings How a complex forms: Type of bonding Multi-step formation Factors affecting the complex formation: Size and charge of metal ion Number of bonding sites on the ligand 36.

Chapter 5 39 As the formation complex for sodium and the other group 1 metals is very low the reaction is not suitable for titration. EDTA is usually used to titrate Main Groups 2-4 and the transition

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