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Distortions in Octahedral Geometry

Distortions in Octahedral Geometry L. L L. M. L L. L. Regular Octahedron: Complexes with regular Octahedral Geometry are expected to form, when all of the ligands are of the same kind Distorted Octahedron: Complexes C l with ith distorted di t t d Octahedral t h d l Geometry t are expected t d to t form, when the ligands are of different kinds Distortions in Octahedral Geometry If the th ground d electronic l t i configuration fi ti off a non-linear li complex l isi orbitally bit ll degenerate, the complex will distort so as to remove the degeneracy and achieve a lower energy. This is called the Jahn-Teller Effect d8 d9. eg eg t2g t2g Ni2+: Only one way of Cu2+: Two ways of filling the eg orbitals;. filling the orbitals; not there is degeneracy and Jahn-Teller degenerate and no Jahn- distortion is observed Teller distortion Jahn-Teller distortion in Cu(II) Complexes dx2-y2.

Distortions in Octahedral Geometry If theground elt ilectronicconfi tifiguration of anon-linear complex isorbit llbitally degenerate, the complex will …

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