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IMPEDANCE SPECTROSCOPY: A GENERAL …

CHAPTER 12 IMPEDANCE spectroscopy : A GENERAL INTRODUCTION AND APPLICATION TO DYE-SENSITIZED SOLAR CELLSJuan Bisquert and Francisco INTRODUCTIONI mpedance spectroscopy (IS) has become a major tool for investigating the properties and quality of dye-sensitized solar cell (DSC) devices. This chapter provides an intro-duction of IS interpretation methods focusing on the analysis of DSC IMPEDANCE data. It also presents a scope of the main results obtained so far. IS gives access to funda-mental mechanisms of operation of solar cells, for which reason we discuss our views of basic photovoltaic principles required to realize the interpretation of the experi-mental results.

Impedance spectroscopy 3 role of selective contacts [12.31-12.34]. Another central concept that appeared in the DSC area was a “conduction band capacitance” [12.26, 12.28, 12.30], later to be

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