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Infrared Spectroscopy

Chapter 15. Infrared Spectroscopy Sherman Hsu, Separation Sciences Research and Product Development Mallinckrodt, Inc. Mallinckrodt Baker Division Summary General Uses Identification of all types of organic and many types of inorganic compounds Determination of functional groups in organic materials Determination of the molecular composition of surfaces Identification of chromatographic effluents Quantitative determination of compounds in mixtures Nondestructive method Determination of molecular conformation (structural isomers) and stereochemistry (geometri- cal isomers). Determination of molecular orientation (polymers and solutions).

Absorbance ( A ) is the logarithm to the base 10 of the reciprocal of the transmit-tance ( T ). (15.2) ... It provides useful information to structural studies such as conformation and lattice dynamics of sam-ples. Near IR spectroscopy needs minimal or no sample preparation. It offers high-speed quantitative

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