Transcription of Introduction to Kinetics and Equilibrium
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Introduction to Kinetics and Equilibrium
Introduction to Kinetics and EquilibriumKinetics and Equilibrium are two of the most importantareasinchemistryEntirebooksandi mportant areas in chemistry. Entire books and courses at the undergraduate and graduate level are devoted to them. Chemical Kinetics the study of the rates of chemical processesEquilibrium the condition of a system in which competing influences are balancedChi lilib ithttihi hthttifthChemical Equilibrium the state in which the concentrations of thereactants and products have no net change over time13concentrations at Equilibrium aredetermined by thermodynamics ( rG )Physical Equilibrium14 Chemical Equilibrium1516Is Equilibrium Common?17 Demo Equilibrium 1: Hpressure balancedWe have physical Equilibrium : Equilibrium 1: H2pressure balanced by balloon wall surface tension Equilibrium 2: Balloon buoyancy H2and O2filled balloonqyybalanced by the string tensionballoonDo we have chemical Equilibrium ?
Example The reaction of CO with Cl 2 to form COCl 2 is another single-step reaction. A vessel is filled with only CO and Cl 2.Describe how equilibrium is achieved and the connection between the reaction rates and the equilibrium constant.
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