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ヨウ素系重合開始剤 Iodine-Containing Initiators for …

R- I Effective for BA ( Bu4NI at 110 oC )(70 oC )104ka(M-1s-1) = 2500 100 88 74 69 62 23 5 <1 Effective for MMA ( Bu3 MePI at 70 oC )( PhCN-I ) ( PhE-I ) ( EEMA-I ) ( CP-I ) ( CE-I ) ( PMMA-I ) ( EMA-I ) ( EA-I ) ( E-I )iodineFunctional groupTelechelic polymerStar polymer( EMA-III )ABA triblock copolymer( EMA-II ) ( PhE-II ) BCMH PAME MMMF PNMM PNMH IBME RAME AAMEBBDG BPDGTBTPPhCHCNIPhCHCIOEtOC CCIOEtOOOEtCCNICHCNICH2 CCIOOnCCIOEtOCHCIOEtOCH2 CIOEtOCCIOHOOOOIOIOOOIOIOOIOOIOOICHCIOOO H 63 May 28th, 2014 1F13 Iodine-Containing Initiators for Living Radical Polymerization -Iodo EstersEthyl 2-Iodopropanoate[31253-08-4]C5H9IO2( )RAME GSS-0003 Ethyl 2-Iodoacetate[623-48-3]C4H7IO2( )AAME GSS-0006 Ethyl 2-Iodoisobutyrate[7425-55-0]C6H11IO2

R - I モノマー Effective for BA ( Bu 4NI at 110 oC ) (70 oC ) 10 4 k a (M-1s-1) = 2500 100 88 74 69 62 23 5 <1

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