ヨウ素系重合開始剤 Iodine-Containing Initiators for …

1 R- I Effective for BA ( Bu4NI at 110 oC )(70 oC )104ka(M-1s-1) = 2500 100 88 74 69 62 23 5 <1 Effective for MMA ( Bu3 MePI at 70 oC )( PhCN-I ) ( PhE-I ) ( EEMA-I ) ( CP-I ) ( CE-I ) ( PMMA-I ) ( EMA-I ) ( EA-I ) ( E-I )iodineFunctional groupTelechelic polymerStar polymer( EMA-III )ABA triblock copolymer( EMA-II ) ( PhE-II ) BCMH PAME MMMF PNMM PNMH IBME RAME AAMEBBDG BPDGTBTPPhCHCNIPhCHCIOEtOC CCIOEtOOOEtCCNICHCNICH2 CCIOOnCCIOEtOCHCIOEtOCH2 CIOEtOCCIOHOOOOIOIOOOIOIOOIOOIOOICHCIOOO H 63 May 28th, 2014 1F13 Iodine-Containing Initiators for Living Radical Polymerization -Iodo EstersEthyl 2-Iodopropanoate[31253-08-4]C5H9IO2( )RAME GSS-0003 Ethyl 2-Iodoacetate[623-48-3]C4H7IO2( )AAME GSS-0006 Ethyl 2-Iodoisobutyrate[7425-55-0]C6H11IO2( )IBMEGSS-0008 Methyl 2-Iodoacetate[5199-50-8]C3H5IO2( )

2 AAMM GSS-0015 Ethyl 2-Iodobutyrate[7425-47-0]C6H11IO2( )BAME GSS-0019 Ethyl 2-Iodovalerate[31253-09-5]C7H13IO2( )VAME GSS-0023 Benzyl 2-Iodoisobutyrate[NA]C11H13IO2( )IBMB GSS-0030 Methyl 2-Iodoisobutyrate[67194-53-0]C5H9IO2( )IBMM GSS-0046 Benzyl IodidesHighly Activated CompoundsFunctionalized CompoundsMulti-Iodinated Compounds -Iodo -Iodo -Iodo -Iodo -IodoCarboxylic AcidLactones AmidesNitrilesKetonesHighly Activated CompoundsMulti-Iodinated CompoundsBenzyl Iodide[620-05-3]C7H7I ( )BNMH GSS-0017(1-Iodoethyl)benzene[10604-60-1] C8H9I ( )EBMH GSS-00054-Nitrobenzyl Iodide[3145-86-6]C7H6 INO2( )NTMH GSS-0045 -Iodo- -butyrolactone[31167-92-7]C4H5IO2( )BLMH GSS-00422-Iodoacetic Acid[64-69-7]C2H3IO2( )AAMH GSS-00072-Iodoisobutyric Acid[7425-20-9]C4H7IO2( )IBMHGSS-00142-Iodopropanoic Acid[598-80-1]C3H5IO2( )RAMHGSS-00042-Iodopropionamide[19221-80 -8]C3H6 INO ( )RAMA GSS-00212-Iodoacetonitrile[624-75-9]C2H2 IN ( )ANMH GSS-00132-Iodopropionitrile[104024-32-0] C3H4IN ( )PNMHGSS-00222-Iodoisobutyronitrile[1948 1-79-9]C4H6NI ( )PNMM GSS-00442-Iodoacetophenone[4636-16-2]C8H 7IO ( )APMHGSS-0031 -Iodobenzyl Cyanide[63450-93-1]C8H6IN ( )BCMH GSS-0018 Iododiphenylmethane[29704-39-0]C13H11I ( )PMMH GSS-00119-Iodo-9H-fluorene[64421-01-8]C1 3H9I ( )FLMH GSS-0012 Ethyl 2-Iodo-2-methylacetoacetate[1005452-92-5 ]C7H11IO3( )MAME GSS-0032 Ethyl 2-Iodo-2-phenylacetate[78489-65-3]C10H11 IO2( )PAME GSS-0009 Ethyl 2-Iodo-2-(4'-methylphenyl)acetate[NA]C11 H13IO2( )TAME GSS-0034 Ethyl 2-Iodo-2-(4'-nitrophenyl)acetate[NA]C10H 10 INO4( )NPME GSS-00262-Iodo-2-phenylacetic Acid[615256-95-6]C8H7IO2( )PAMH GSS-00202-Hydroxyethyl 2-Iodoisobutyrate[NA]C6H11IO3( )IBMOGSS-00362-Hydroxyethyl 2-Iodo-2-phenylacetate[NA]C10H11IO3( )

3 PAMO GSS-0039 Diethyl 2,5-Diiodoadipate[165334-67-8]C10H16I2O4 ( )ADDF GSS-0016 Ethylen Glycole Bis(2-iodo-2-phenylacetate)[NA]C18H16I2O 4( )BPDG GSS-0037p-Xylylene Diiodide[30362-89-1]C8H8I2( )PXDH GSS-00011,4-Bis(1'-iodoethyl)benzene[NA] C10H12I2( )PXDL GSS-00271,3,5-Tris(1'-iodoethyl)benzene[ NA]C12H15I3( )MSTK GSS-0028 Ethylene Glycol Bis(2-iodoisobutyrate)[NA]C10H16I2O4( )BBDG GSS-0024 Diethyl 2-Iodo-2-methylmalonate[119368-33-1]C8H1 3IO4( )MMMF GSS-0010 Glycerol Tris(2-iodoisobutyrate)[NA]C15H23I3O6( )TBTP GSS-0025 Iodine-Containing Initiators for Living Radical PolymerizationURL: : 104-0031 12-6 TEL03-3566-0341 FAX03-3566-0340 HEAD OFFICE12-6 Kyobashi 2-Chome, Chuo-ku, Tokyo 104-0031, JAPAN(+81-3-3566-0341)(+81-3-3566-0340) 299-4333 1365 TEL0475-32-1111 FAX0475-32-1115 CHIBA OFFICE1365 Nanaido, Chosei-mura, Chosei-gun, Chiba 299-4333, JAPAN(+81-475-32-1111)(+81-475-32-1115)