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Oxidation Reactions - UR

Prof. Dr. Burkhard K nig, Institut f r Organische Chemie, Uni Regensburg 1 Oxidation Reactions Chemoselectivity the reaction of one functional group in the presence of another Regioselectivity reaction at one point in an ambident functional group Stereoselectivity control of stereogenic centres in an absolute and/or (or both) relative fashion; control of double bond geometries. I. Oxidation of Alcohols Issues of Reactivity and Selectivity 1. Primary alcohols are generally more reactive than secondary alcohols and can sometimes be oxidised selectively. 2. Chemoselectivity - Oxidation of primary alcohols requires control as there are two potential products: the carboxylic acid or the aldehyde.

Prof. Dr. Burkhard König, Institut für Organische Chemie, Uni Regensburg 1 Oxidation Reactions . Chemoselectivity the reaction of one functional group in …

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