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Polyisobutylene: A Most Unusual Polymer

polyisobutylene : A most Unusual PolymerK. KUNAL,1M. PALUCH,2C. M. ROLAND,3J. E. PUSKAS,1Y. CHEN,1A. P. SOKOLOV11 Department of Polymer Science, The University of Akron, Akron, Ohio 44325-39092 Institute of Physics, Silesian University, ulica Uniwersytecka 4, 40-007 Poland3 Naval Research Laboratory, Chemical Division, Code 6120, Washington, District of Columbia 20375-5342 Received 22 February 2008; revised 7 April 2008; accepted 10 April 2008 DOI: online in Wiley InterScience ( ).ABSTRACT:The influence of molecular weight,M, on the fragility and fast dynamicsin polyisobutylene (PIB) was studied using dielectric and mechanical relaxation spec-troscopies, calorimetry, and Raman spectroscopy. The measurements indicate adecrease in fragility with increasingMfor shorter chains, in the range ofMwhereTgisM-dependent. Such behavior is not observed for other polymers and is at oddswith traditional theoretical models that predict an increase in fragility with chainlength.

Polyisobutylene: A Most Unusual Polymer K. KUNAL,1 M. PALUCH,2 C. M. ROLAND,3 J. E. PUSKAS, 1Y. CHEN, A. P. SOKOLOV1 1Department of Polymer Science, The University of ...

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