Transcription of X-ray Photoelectron Spectroscopy
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XX--ray Photoelectron Spectroscopyray Photoelectron SpectroscopyRoger Smart, Stewart McIntyre, Mike Roger Smart, Stewart McIntyre, Mike Bancroft, Igor Bancroft, Igor Bello Bello & Friends& FriendsDepartment of Physics and Materials ScienceDepartment of Physics and Materials ScienceCity University of Hong KongCity University of Hong KongSurface Science Western, UWOS urface Science Western, UWOP hotoelectric effectPhotoelectric effectEinstein, Nobel Prize 1921 Photoemission as an analytical toolKai Siegbahn, Nobel Prize 1981 IntroductionXPSX-ray Photoelectron SpectroscopyESCAE lectron Spectroscopy for chemical AnalysisUPSU ltraviolet Photoelectron SpectroscopyPESP hotoemission SpectroscopyXPS, also known as ESCA, is the most widely used surface analysis technique because of its relative simplicity in use and data Analytical Methods Analytical Methods KE = h -(EB+ ) Elemental identification and chemical state of element Rela
Chemical Effects in XPS Chemical shift: change in binding energy of a core electron of an element due to a change in the chemical bonding of that element. Qualitative view: Core binding energies are determined by: • electrostatic interaction between it and the nucleus, and reduced by: • the electrostatic shielding of the nuclear charge from all
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