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Yu-ran Luo

Bond dissociation energiesYu-ran LuoThe bond dissociation energy (enthalpy) is also referred to as bond disruption energy, bond energy, bond strength, or binding energy (abbreviation: BDE, BE, or D) . It is defined as the standard enthalpy change of the following fission: R X R + X . The BDE, denoted by Do(R X), is usually derived by the thermochemical equation, Do(R X) = fHo(R) + fHo(X) fHo(RX) . The enthalpy of formation fHo of a large number of atoms, free radicals, ions, clusters and compounds is available from the websites of NIST, NASA, CODATA, and IUPAC . Most authors prefer to use the BDE values at 298.

of formation ∆ f Ho of a large number of atoms, free radicals, ions, clusters and compounds is available from the websites of NIST, NASA, CODATA, and IUPAC . Most authors prefer to use the BDE values at 298 .15 K . The following seven tables provide essential information of ex-perimental BDE values of R−X and R+−X bonds .

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