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3-2 交換相互作用直接交換相互作用クーロン相互作用の期待値 ϕa χa ϕb χb = − +2 1 ⋅ 2 2 1 Kab Jab s s r r H 1 2 12 2 (1) (2) (1) (2)drdr r e Jab a b a b rr =∫ϕ∗ ϕ∗ ϕ ϕ 超交換相互作用（transferの2次摂動）

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