DIETHANOLAMINE (DEA) - Alliance Chemicals

1 SAFETY DATA SHEET according to Regulation (EC) No. 1907/ 2006 DIETHANOLAMINE (DEA) Version 3 Revision date Print date GB / EN 1/135 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product identifier Trade name : DIETHANOLAMINE (DEA) Substance name : 2,2'-iminodiethanol Index-No. : 603-071-00-1 REACH Registration Number : 01-2119488930-28-0006 Relevant identified uses of the substance or mixture and uses advised against Use of the Substance/Mixture : Specific use(s): Refer to attached exposure scenario Annex. Details of the supplier of the safety data sheet Company : Akzo Nobel Functional Chemicals AB SE 444 85 Stenungsund Sweden Telephone : +4630385000 Telefax : +46303770551 E-mail address : Emergency telephone number Emergency telephone number : 24 hours emergency response number: +31 57 06 79211 Kemiakuten-SE: 020 99 60 00 SECTION 2.

2 HAZARDS IDENTIFICATION Classification of the substance or mixture Classification (REGULATION (EC) No 1272/2008) Acute toxicity, 4, H302 Skin irritation, 2, H315 Serious eye damage, 1, H318 Specific target organ toxicity - repeated exposure, 2, Blood, H373, Liver, Kidney For the full text of the H-Statements mentioned in this Section, see Section 16. Label elements DIETHANOLAMINE (DEA) Version 3 Revision date Print date GB / EN 2 / 135 Labelling (REGULATION (EC) No 1272/2008) Pictogram : Signal word : Danger Hazard statements : H302 Harmful if swallowed.

3 H315 Causes skin irritation. H318 Causes serious eye damage. H373 May cause damage to organs (Blood, Liver, Kidney) through prolonged or repeated exposure if swallowed. Precautionary statements : Prevention: P260 Do not breathe mist, vapours or spray. P264 Wash skin thoroughly after handling. P280 Wear protective gloves/ eye protection/ face protection. Response: P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P314 Get medical advice/ attention if you feel unwell.

4 Disposal: P501 Dispose of contents/container in accordance with local regulation. Hazardous components which must be listed on the label: DIETHANOLAMINE 111-42-2 Other hazards Do not add nitrites or other nitrosating agents - May form suspected cancer-causing nitrosamines. No further data available. PBT and vPvB assessment : This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of or higher. DIETHANOLAMINE (DEA) Version 3 Revision date Print date GB / EN 3 / 135 SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Substances CAS-No.

5 : 111-42-2 Hazardous substance Chemical name PBT vPvB OEL CAS-No. EC-No. REACH No. Classif ication (REGULATION (EC) No 1272/2008) Concentration [%] DIETHANOLAMINE 111-42-2 203-868-0 01-2119488930-28 Acute Tox. 4; H302 Skin Irrit. 2; H315 Eye Dam. 1; H318 STOT RE 2; H373 90 - 100 For the full text of the H-Statements mentioned in this Section, see Section 16. REACH - Candidate List of Substances of Very High Concern for Authorisation (Article 59). Status : Not applicable SECTION 4: FIRST AID MEASURES Description of first aid measures General advice : Immediate medical attention is required.

6 Move out of dangerous area. Show this safety data sheet to the doctor in attendance. If inhaled : If breathed in, move person into fresh air. Consult a physician after significant exposure. In case of skin contact : Take off contaminated clothing and shoes immediately. Rinse immediately with plenty of water. If skin irritation persists, call a physician. In case of eye contact : Rinse with plenty of water. Get medical attention immediately. Continue to rinse during transport. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If swallowed : Clean mouth with water and drink afterwards plenty of water.

7 Never give anything by mouth to an unconscious person. Obtain medical attention. Most important symptoms and effects, both acute and delayed Symptoms : The symptoms and effects are as expected from the hazards as shown in section 2. No specific product related symptoms DIETHANOLAMINE (DEA) Version 3 Revision date Print date GB / EN 4 / 135 are known. Risks : Harmful if swallowed. Causes skin irritation. Causes serious eye damage. May cause damage to organs through prolonged or repeated exposure if swallowed. Indication of any immediate medical attention and special treatment needed Treatment : Treat symptomatically.

8 SECTION 5: FIREFIGHTING MEASURES Extinguishing media Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special hazards arising from the substance or mixture Specific hazards during firefighting / Specific hazards arising from the chemical : Do not allow run-off from fire fighting to enter drains or water courses. Combustion products : Carbon oxides Nitrogen oxides (NOx) Advice for firefighters Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus.

9 Further information : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations . SECTION 6: ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions : Use personal protective equipment. Wear respiratory protection. Ensure adequate ventilation. Environmental precautions Environmental precautions : Do not flush into surface water or sanitary sewer system.

10 If the product contaminates rivers and lakes or drains inform respective authorities. Methods and materials for containment and cleaning up Methods for cleaning up / Methods for containment : Contain spillage, and then collect with non-combustible absorbent material, ( sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). DIETHANOLAMINE (DEA) Version 3 Revision date Print date GB / EN 5 / 135 Reference to other sections Additional advice : For personal protection see section 8.