Killem Biocide - Buffalo Building Survey

1 MATERIAL SAFETY DATA SHEET Effective Date: October 2009 Chemical Product and Company Identification: FPPF Chemical Co., 117 West Tupper St., Buffalo , NY 14201-2193; (800) 735-FPPF (3773). Emergency Phone: ChemTrec (800) 424-9300 Product Trade Name: Killem Biocide Product Codes: 00119, 90119, 00191P, 00120 Chemical Family Class: Pesticide mixture, water-based CAS #: Not applicable to mixtures Composition Data: OSHA ACGIH PEL TLV STEL Hazardous Components1 % CAS # ppm ppm ppm Disodium ethylenebisdithiocarbamate3 15 142-59-6 N/E N/E N/A Sodium Dimethyldithiocarbamate3 15 128-04-1 N/E N/E N/A Ethylene Thiourea2,3,4 < 96-45-7 N/E N/E N/A 1 Components presenting a physical or health hazard or subject to CERCLA or SARA reporting requirements and found at or above 1% ( if identified as a carcinogen).

2 Other components may be listed if deemed appropriate. 2 Chemical subject to reporting requirements of CERCLA (40 CFR ). 3 Chemical subject to reporting requirements of SARA Section 313 (40 CFR 372). 4 Chemical present at less than 1%, determined to be a carcinogen in laboratory animals. Note: N/E = Not Established; N/A = Not Applicable Typical Physical Data (not specifications): Boiling Point, F (typical): >212 Solubility in Water: Complete Specific Gravity @ room temp: ca. Appearance: Yellow-green solution Vapor Pressure @ 20 C, mm Hg: approx.

3 NA Odor: Characteristic sulfur odor Vapor Density (air = 1):N/A Physical State: Liquid Evaporation Rate: Equal to water Percent Volatile (approx.): 70% (water) Fire and Explosion Hazard Data: Specific Hazard: Material is Non-Flammable as supplied. Flash Point, typical (TCC): None Autoignition Temperature: N/A Flammability Limits: Upper: N/A Lower: N/A Extinguishing media: Foam, CO2 or Dry Chemical as appropriate to surrounding materials. FPPF Chemical Co. Killem Biocide Material Safety Data Sheet Page 2 Fire and Explosion Hazard Data (Continued): Special Fire Fighting Procedures: Use of self-contained breathing apparatus with full face mask is recommended for all chemical fires.

4 Unusual Fire or Explosion Hazards: Do not rely on ambient air for breathing air supply during fires. Fire may result in release of toxic gases such as oxides of carbons, nitrogen and sulfur. Reactivity Data: Stability: Stable under ordinarily expected conditions. Hazardous Polymerization: Will not occur. Incompatibilities: Mineral acids such as sulfuric, nitric and hydrochloric. Conditions to avoid: Acidification releases flammable gases. Hazardous Combustion or Decomposition Products: Combustion of dry film may produce oxides of carbon, nitrogen and sulfur.

5 Thermal decomposition may release gases such as amines and carbon disulfide. Health Hazard Data: Primary Routes of Entry: Inhalation, ingestion, skin contact. Acute Exposure Effects: Swallowing: May cause nausea and vomiting. Skin Contact: Slightly irritating to skin. Inhalation: Vapors may be irritating to nose, throat, and respiratory tract, producing symptoms of nausea in poorly ventilated areas. Eye Contact: Exposure is possibly irritating to the eyes. Chronic Exposure Effects: Target Organ Effect: Product contains < 1% Ethylene thiourea, which has been determined to be a teratogen and oncogen in laboratory animals.

6 Carcinogenicity: Product contains < 1% Ethylene thiourea, which has been determined to be a carcinogen in laboratory animals. Delayed effects: N/E FPPF Chemical Co. Killem Biocide Material Safety Data Sheet Page 3 First Aid: Ingestion: If patient is fully conscious, dilute by drinking copious amounts of water. Obtain immediate medical attention. Never give anything by mouth if patient is unconscious or drowsy. Skin Contact: Remove contaminated clothing. Wash exposed skin with soap and water.

7 Obtain medical attention. Inhalation: Remove affected individual to fresh air and seek medical attention. If breathing is labored, administer oxygen. If breathing has stopped, administer artificial respiration. Eye Contact: Flush eyes with plenty of running water for at least 20 minutes while holding eyelids apart. Obtain medical attention. Handling and Storage: Precautions: Keep out of reach of children. Keep containers tightly closed when not in use. Wash thoroughly after handling, and particularly before eating, drinking, or smoking.

8 Do not transfer to unmarked containers. Wear appropriate protective clothing when handling. NOTICE: Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or solid), all hazard precautions given in this data sheet must be observed. Accidental Release, Spill or Leak Procedures: Spill Procedures: Evacuate all non-essential personnel. Personal Protective Equipment appropriate to the nature of the spill must be worn. Ventilate spill area.

9 Stop spill at source. Prevent entry into sewers and waterways. Collect free liquid for disposal. Residual liquid may be absorbed using inert material. Transfer contaminated absorbent, soil, etc. into containers for disposal. The floor may be slippery. Use caution to avoid falls. Material is detrimental to the environment. Spills may be reportable under CERCLA, SARA, or DOT criteria, depending on quantities involved. Disposal Methods: Hazardous waste: Dispose of liquid or solid materials in conformance with all applicable Federal, State or Local regulations.

10 Personal Protective Equipment and Protection Information: Respiratory Protection: None required if good ventilation is maintained. If airborne exposure limit for any component is exceeded, wear self-contained breathing apparatus (Pressure Demand, NIOSH/MSHA-approved or equivalent). OSHA regulations may also permit other respirators under specified conditions. Consult your Industrial Hygienist for guidance. Implement engineering or administrative controls to reduce exposure. Ventilation: Provide sufficient mechanical (General and/or Local Exhaust) ventilation to control mists or vapors and maintain exposure below TLV s.