Chlor-Mate HW SAFETY DATA SHEET Liquid

1 Chlor-Mate HWLiquidSAFETY data SHEETP reparation Date: 09-Jul-2008 Revision Date: 16-Jul-2014 Revision Number: 11. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKINGP roduct Identifier Product NameChlor-Mate HW LiquidOther means of identification Item#:1823 SynonymsNoneRecommended use of the chemical and restrictions on use Recommended useChlorinated alkaline detergent. Restricted to professional advised againstNo information availableDetails of the supplier of the SAFETY data SHEET Emergency Telephone Number Chemtrec 1-800-424-93002. HAZARDS IDENTIFICATIONC lassification Skin Corrosion/IrritationCategory 1 Sub-category ASerious eye damage/eye irritationCategory 1 Label Elements Emergency OverviewSupplierDeLaval Cleaning Solutions11100 N. Congress City, MO 64153 Tel: 816-891-7700, 8am 5pm M-FCorrosive to metalsCategory 1 DANGERH azard StatementsCauses severe skin burns and eye damageMay be corrosive to metals_____Appearance Light yellowPage 1 / 7 Physical state LiquidOdor Slight chlorine_____1823 Chlor-Mate HW LiquidRevision Date: 16-Jul-2014 Precautionary Statements - PreventionDo not breathe dust/fume/gas/mist/vapors/sprayWash face, hands and any exposed skin thoroughly after handlingWear protective gloves/protective clothing/eye protection/face protectionPrecautionary Statements - ResponseImmediately call a POISON CENTER or doctor/physicianIF IN EYES: Rinse cautiously with water for several minutes.

2 Remove contact lenses, if present and easy to do. Continue rinsingImmediately call a POISON CENTER or doctor/physicianIF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/showerWash contaminated clothing before reuseIF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathingImmediately call a POISON CENTER or doctor/physicianIF SWALLOWED: Rinse mouth. Do NOT induce vomitingPrecautionary Statements - StorageStore locked upPrecautionary Statements - DisposalDispose of contents/container to an approved waste disposal plantHazards not otherwise classified (HNOC) Other information May be harmful if swallowed Toxic to aquatic life with long lasting effects Toxic to aquatic lifeUnknown Acute Toxicity0% of the mixture consists of ingredient(s) of unknown toxicity3.

3 COMPOSITION/ information ON INGREDIENTSC hemical NameCAS-NoWeight %Trade SecretPotassium hydroxide1310-58-310 - 20%*Sodium hypochlorite7681-52-90 - 10%** The exact percentage (concentration) of composition has been withheld as a trade FIRST AID MEASURESFIRST AID MEASURESEye contactImmediately flush with plenty of water. After initial flushing, remove any contact lenses andcontinue flushing for at least 15 minutes. Call a physician contactWash off immediately with plenty of water for at least 15 minutes. Call a to fresh air. If breathing is difficult, give oxygen. If symptoms persist, call a not induce vomiting. Drink 1 or 2 glasses of water. Call a physician or Poison ControlCentre immediately. Never give anything by mouth to an unconscious important symptoms and effects, both acute and delayedMost Important Symptoms andEffects_____According to our experience and to the information provided to us, the product does nothave any harmful effects if it is used and handled as of any immediate medical attention and special treatment neededNotes to PhysicianPage 2 / 7 Treat Chlor-Mate HW LiquidRevision Date: 16-Jul-20145.

4 FIRE-FIGHTING MEASURESS uitable Extinguishing MediaUse extinguishing measures that are appropriate to local circumstances and the surrounding environmentUnsuitable Extinguishing MediaNo information hazards arising from the chemicalThe product causes burns of eyes, skin and mucous Equipment and Precautions for FirefightersAs in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and fullprotective ACCIDENTAL RELEASE MEASURESP ersonal precautions, protective equipment and emergency procedures Avoid contact with skin, eyes and clothing. Use personal protective Precautions Prevent further leakage or spillage if safe to do and material for containment and cleaning up Soak up with inert absorbent material. Keep in suitable, closed containers for HANDLING AND STORAGEP recautions for Safe HandlingHandlingAvoid contact with skin, eyes and for safe storage, including any incompatibilitiesStorageKeep containers tightly closed in a dry, cool and well-ventilated Materialsacids, organic materials, light metals8.

5 EXPOSURE CONTROLS/PERSONAL PROTECTIONC ontrol parameters Keep out of the reach of childrenChemical NameACGIH TLVOSHA PELNIOSH IDLHP otassium hydroxide 1310-58-3 Ceiling: 2 mg/m3 Ceiling: 2 mg/m3 Appropriate engineering controlsEngineering ControlsEnsure adequate ventilation, especially in confined protection measures, such as personal protective equipmentEye/face and body protection_____Wear protective gloves and protective ProtectionPage 3 / 7If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approvedrespiratory protection should be worn. Positive-pressure supplied air respirators may berequired for high airborne contaminant concentrations. Respiratory protection must beprovided in accordance with current local Chlor-Mate HW LiquidRevision Date: 16-Jul-2014 General Hygiene ConsiderationsHandle in accordance with good industrial hygiene and SAFETY practice.

6 Remove and washcontaminated clothing before PHYSICAL AND CHEMICAL PROPERTIESI nformation on basic physical and chemical propertiesPhysical stateLiquidExplosive PropertiesNo information availableOxidizing PropertiesNo information availableOther informationSoftening PointNo information availableMolecular WeightNo information availableVOC ContentNo information lb/galBulk DensityNo information available10. STABILITY AND REACTIVITYR eactivity Chemical Stability Stable under normal of hazardous reactions May develop chlorine if mixed with acidic solutions. Gives off hydrogen by reaction with some metals ( aluminum).Conditions to Avoid Extremes of temperature and direct Materials acids, organic materials, light metalsHazardous decomposition products yellowOdorSlight chlorineColorNo information availableOdor ThresholdNo information availableProperty Values Remarks/ Method pH13 Melting point/freezing pointNo information availableBoiling Point/RangeNo information availableFlash PointNo information availableEvaporation rateNo information availableFlammability (solid, gas)No information availableFlammability Limit in AirUpper flammability limitNo information availableLower flammability limitNo information availableVapor PressureNo information availableVapor DensityNo information availableSpecific SolubilitysolubleSolubility in other solventsNo information availablePartition coefficient.

7 N-octanol/waterNo information availableAutoignition TemperatureNo information availableDecomposition temperatureNo information availableViscosity of ProductNo information available_____Dynamic viscosityNo information availablePage 4 / 7No data available_____1823 Chlor-Mate HW LiquidRevision Date: 16-Jul-201411. TOXICOLOGICAL INFORMATIONI nformation on likely routes of exposure InhalationNo data contactNo data contactNo data data NameLD50 OralLD50 DermalLC50 InhalationPotassium hydroxide 1310-58-3= 284 mg/kg ( Rat )--Sodium hypochlorite 7681-52-9= 8200 mg/kg ( Rat )10000 mg/kg ( Rabbit )- information on toxicological effects SymptomsNo information and immediate effects as well as chronic effects from short and long-term exposure SensitizationNo information effectsNo information information NameACGIHIARCNTPOSHAS odium hypochlorite 7681-52-9-Group 3--Reproductive EffectsNo information - single exposureNo information exposureNo information HazardNo information measures of toxicity - Product information Unknown Acute Toxicity0% of the mixture consists of ingredient(s)

8 Of unknown toxicityThe following values are calculated based on chapter of the GHS document .12. ECOLOGICAL INFORMATIONE cotoxicity of the mixture consists of components(s) of unknown hazards to the aquatic environmentChemical NameAlgae/aquatic plantsFishMicrotoxWaterfleaPotassium hydroxide 1310-58-3-80: 96 h Gambusia affinismg/L LC50 static--Sodium hypochlorite : 24 h Skeletonemacostatum mg/L EC50LC50 (96 h) - : 48 h Daphniamagna mg/L EC50 : 96 h Daphnia magnamg/L EC50 Persistence and degradabilityNo information information NamePartition coefficientPotassium hydroxide 5 / 7_____1823 Chlor-Mate HW LiquidRevision Date: 16-Jul-2014 Other adverse effectsNo information available13. DISPOSAL CONSIDERATIONSW aste treatment methodsWaste Disposal MethodDispose of in accordance with local regulations.

9 Should not be released into PackagingEmpty containers should be taken for local recycling, recovery or waste TRANSPORT INFORMATIONDOT UN-No3266 Proper Shipping NameCORROSIVE Liquid , BASIC, INORGANIC, ( contains, Sodium hypochlorite,Potassium hydroxide )Hazard Class8 Packing GroupII15. REGULATORY INFORMATIONI nternational Inventories TSCATSCADSL/NDSLDSL/NDSLEINECS/ELINCSC ompliesENCSDoes not ComplyCHINAC ompliesKECLC ompliesPICCSC ompliesAICSC ompliesTSCA - United States Toxic Substances Control Act Section 8(b) InventoryDSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances ListENCS - Japan Existing and New Chemical SubstancesIECSC - China Inventory of Existing Chemical SubstancesKECL - Korean Existing and Evaluated Chemical SubstancesPICCS - Philippines Inventory of Chemicals and Chemical SubstancesAICS - Australian Inventory of Chemical SubstancesChemical NameCWA - ReportableQuantitiesCWA - Toxic PollutantsCWA - Priority PollutantsCWA - HazardousSubstancesPotassium hydroxide 1310-58-31000 lb--XSodium hypochlorite 7681-52-9100 lb--XChemical NameRQCERCLA EHS RQsRQPotassium hydroxide 1310-58-31000_____-RQ 1000 lb final RQRQ 454 kg final RQSodium hypochlorite100 lbPage 6 / 7-RQ 100 lb final RQ_____1823 Chlor-Mate HW LiquidRevision Date.

10 16-Jul-2014 7681-52-9RQ kg final RQState Regulations California Proposition 65 This product does not contain any Proposition 65 NameNew JerseyMassachusettsPennsylvaniaSodium hydroxide 1310-73-2 XXXS odium hypochlorite EPA Label information EPA Pesticide registration numberNot applicable16. OTHER INFORMATIONP reparation Date:09-Jul-2008 Revision Date:16-Jul-2014 Revision NoteNo information availableDisclaimerThe information provided on this SDS is correct to the best of our knowledge, information and belief at the date of itspublication. The information given is designed only as a guide for safe handling, use, processing, storage,transportation, disposal and release and is not to be considered as a warranty or quality specification. The informationrelates only to the specific material designated and may not be valid for such material used in combination with any othermaterial or in any process, unless specified in the of SDSNFPA Health 3 Flammability 0 Instability 1_____Physical Hazard -Page 7 / 7