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Search results with tag "Kinetic isotope effects"
Isotope Effects Kinetic Isotope Effects (K.I.E.)
personal.utdallas.eduIsotope Effects! Kinetic isotope effects are further delineated according to what change ! is occurring in a given reaction mechanism at the isotopic substitution! Primary isotope effect (1˚ KIE)! Occurs whenever the bond to the isotopic substituent is broken in the rate determining step! CH3 Consider a radical halogenation mechanism !
Isotope Effects Kinetic Isotope Effects (K.I.E.)
utdallas.eduIsotope Effects! Kinetic Isotope Effects (K.I.E.): ! the rate of a reaction changes with an isotopic substitution! At first glance, this might seem counterintuitive because an isotopic substitution !