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Search results with tag "Enolates"
Ch. 7 - Enolates - Purdue University
www.chem.purdue.edu651.06 209 Enolates Enolates are the conjugate anions of carbonyl compounds. Although they have been known and used since the turn of the 20th Century, it was the development of “specific enolates” (see below) by H. O. House of MIT in the 1960-1970s that made carbanion
O O E+ E - University of Texas at Dallas
www.utdallas.eduEnols and Enolates! A type of reaction with carbonyl compounds is an α-substitution! (an electrophile adds to the α carbon of a carbonyl)! O O
123.312 Advanced Organic Chemistry: Retrosynthesis
www.massey.ac.nzCO2H FGI hydrolysis CO2Et C=C CO2Et CHO CO2Et PPh3 The second is probably the hardest; there is no simple enolate disconnections so we have to look slightly further a field.
O NUC O H C CH H C CH NUC O - The University of Texas at ...
utdallas.eduReactions at α-Position! 2) To make a carbonyl compound even more nucleophilic at the α-position, ! a base can be added to form an enolate! H3C O