改正された産業廃棄物の検定方法 （環告13号）の …

1 24 . G4 .. 1.. (1) .. (2) .. 2. 13 . 2010 2012 .. 2012 9 13 . 2013 2 . 2013 2 3 7 8 . 2013 6 . 3. 13 . 2012 .. 5 .. 2013 .. 100 . 4. 2013 .. (pH ). 50 g 500 mL.. ( L/S=10).. 1 m GFF.. / .. 5.. 2 2 .. 2 . 2 13 .. 2 . 2008 . JIS . 2 . 6. 24 .. (1) .. ICP ICP . 2 .. Hg, Cd, Pb, As,Cr6+,Se, ( ICP ) Be, Cu, Zn Hg, Cd, Pb, As, Cr6+, Se, (ICP ) Be, Cu, Zn Na K Ca . (2) .. 14 . 4 .. 5mm 1mm 5mm . 1mm .. 1 2 .. 400g . (2) .. 1 .. 2 .. 2 .. 3 . 3 .. 4 . 50% . As260mg/kg Cd280mg/kg . Cd Pb As . 10. (3) .. As Se ICP . As Se . Be .. As Se Be .. 500mL .. L001 L002 L003 L004. 100 g 50 g 50 g 50 g 2000 mL 1000 mL 1000 mL 1000 mL. 5 cm cm 4 cm cm 200 200 200 200 .. 21 20 21 18 .. TAITEC TS-10 TAITEC TS-20.

2 NR-150 . 3210 3275 3000 3000 . 27 cm 25 cm cm cm . G 3000 3000 1880 1882 .. 1000 1000 650 650 . 10 20 20 22 .. CR7 KOKUSAN H-700SL 8800 KUBOTA 8100. 13.. L001 L002 L003 L004.. PTFE .. A100A047A. ADVANTEC H100A090C A100A090C ADVANTEC. (ADVANTEC). 1 m 1 m 1 m m 47 mm 90 mm 90 mm 47 mm .. EYELA A-1000S ULVAC . ULVAC-DA- S. MDA-015. 1 4 7 2 1 2 2 3 3 10 14 5 . 4 3 3 270 4 1 2 3 2 . 1 1 2 1 . 2 1 1 . 3 10 4 1 . 3 3 5 4 . 14.. 1. 50g 100g 50% .. 2. 4-5cm 200 .. 1 7cm 150 /.. 3.. 8 4 .. 15.. 2 3000G . L 650mL 500mL .. 8 6 . 2 PTFE . PTFE .. L001 . 10 16.. L001 L002 L003 L004. Hg . AA NIC RA-3A NIC RA-3A NIC RA-3A NIC RA-2A. Cd . AA .. Z-2000. kw kw kw kw 14 L/min L/min L/min 15 L/min L/min L/min L/min L/min ICP-AES L/min L/min L/min L/min.

3 ICPS-8000E Varian 720-ES. kw kw kw kw 15 L/min 15 L/min 17 L/min L/min ICP-MS L/min L/min L/min L/min L/min L/min L/min 1 L/min Agilent 7700x Agilent 7500c Varian 820-MS Thermo Fisher X-7. 17.. L001 L002 L003 L004. As .. AA CIROS. Aanalyst 100. kw kw kw 1 kw L/min L/min L/min L/min L/min L/min L/min L/min ICP-AES L/min L/min L/min L/min . Varian 720-ES. kw kw kw kw L/min 15 L/min L/min 15 L/min L/min L/min L/min L/min ICP-AES L/min L/min L/min L/min . Agilent 720-ES Varian VISTA-PRO. kw kw kw kw 15 L/min 15 L/min 17 L/min L/min ICP-MS L/min L/min L/min L/min L/min L/min L/min 1 L/min Agilent 7700x Agilent 7500c Varian 820-MS Thermo Fisher X-7. 18.. L001 L002 L003 L004 L005 L006 L007 L008.

4 (nm) AA.. AA (nm) ( ) ICP-AES Y Y Y Y Y - ( ) - ( ) 111 111 111 111 111 111 111. ICP-MS He - - He + H 2 He He - ( ) Rh In Re In In In Ge . AA (nm) ( ) ICP-AES Y Y Y Y Y - ( ) - ( ) 208 208 208 208 208 207 208. ICP-MS . - - - He + H 2 - He - ( ) Tl Tl Re Tl In Ir Ge 19.. (nm) AA. ( ) . - ICP-AES. ( ) - ( ) ICP-AES - Y - ( ) - - ( ) 75 75 75 75 75 75 75. ICP-MS He He H 2 He + H 2 He He - ( ) Ge Ga Re In In Y Ge . 540 540 540 540 540.. AA. ( ) . - ICP-AES. ( ) - ( ) ICP-AES - Y - ( ) - - ( ) 78 78 78 78 78 78 82. ICP-MS He H2 H 2 He + H 2 H2 H2 - ( ) Ge Ga Re In In Y Ge 20.. 10% 10%.. 5mm .. ) pH pH .. PTFE .. 21.. 22.. ICP .. ICP .. 8 . AA ICP. ICP . 23. pH . pH .. 2 3 2 3.

5 1 4 1 4 .. ( ( .. [S/m] [S/m] [S/m] [S/m] [S/m]. L001 L002 L003 L004 L005 L006. L007 L008.. PTFE .. 24.. 1( 2 3 4 .. [mg/L] [mg/L]. L001 < < < < < L002 < < < < < L003 < < < < < L004 < < < < < L005 < < < < < L006 < < < < < L007 < < < < < L008 < < < < < / 25.. 5 . 4 .. AA ICP-AES ICP-MS ICP-MS AA ICP-AES ICP-MS ICP-AES ICP-MS. AA. [mg/L] [mg/L] [mg/L] [mg/L] [mg/L] [mg/L] [mg/L] [mg/L] [mg/L] [mg/L]. L001 L002 L003 L004 L005 L006 L007 L008 / .. 26.. AA ICP-AES ICP-MS ICP-AES ICP-MS ICP-AES ICP-MS. AA .. [mg/L] [mg/L] [mg/L] [mg/L] [mg/L] [mg/L] [mg/L]. [mg/L] [mg/L]. L001 L002 L003 L004 L005 L006 L007 L008 / / . AA ICP . ICPMS ICPMS CV . 10% . CV 70%. 27.. 2 3 4 . 1(.))))

6 ICP-MS ICP-AES ICP-MS ICP-AES ICP-MS ICP-AES ICP-MS. AA AA AA.. [mg/L] [mg/L] [mg/L] [mg/L] [mg/L] [mg/L] [mg/L] [mg/L] [mg/L] [mg/L]. L001 261 246 275 L002 313 L003 219 L004 292 217 L005 244 L006 246 L007 261 258 261 L008 232 252 261 253 256 ppb ICPMS .. 100 ICPMS 10% . 28.. 5 .. AA ICP-MS ICP-AES AA ICP-MS ICP-AES. AA ICP-MS ICP-AES. ICP-ASE ICP-ASE ICP-ASE.. [mg/L] [mg/L] [mg/L] [mg/L] [mg/L] [mg/L] [mg/L] [mg/L]. [mg/L] [mg/L] [mg/L] [mg/L]. L001 L002 L003 L004 L005 L006 L007 L008 / AA ICPAES ICPMS . CV 10% . 29.. 2( ) 3( ) 4 .. ICP-MS ICP-AES AA ICP-MS ICP-AES AA ICP-MS ICP-AES. AA ICP-ASE ICP-ASE ICP-ASE.. [mg/L] [mg/L] [mg/L] [mg/L] [mg/L] [mg/L] [mg/L] [mg/L] [mg/L] [mg/L] [mg/L] [mg/L].

7 L001 L002 L003 L004 L005 L006 L007 L008 CV 20% ICPAES .. 10ppb ICPMS 40%. 30.. 5 .. ICP-AES . ICP-AES ICP-MS ICP-AES ICP-MS.. [mg/L] [mg/L] [mg/L] [mg/L] [mg/L] [mg/L] [mg/L]. L001 L002 L003 L004 L005 ( ) ( ) ( ) ( ). L006. L007. L008. ICP-AES ICP-MS . JIS K0102 65 9 11 .. 50% . Se . ICPAES Cr(III) . 31.. 5 .. AA ICP-MS ICP-AES AA ICP-MS ICP-AES. AA ICP-MS ICP-AES. ICP-ASE ICP-ASE ICP-AES. [mg/L] [mg/L] [mg/L] [mg/L] [mg/L] [mg/L] [mg/L] [mg/L]. [mg/L] [mg/L] [mg/L] [mg/L]. L001 L002 L003 L004 L005 L006 L007 L008 / . 0,2mg/L CV 20-30%. 32.. 1( 2( ).. ICP-MS ICP-AES ICP-MS ICP-AES. AA ICP-ASE AA ICP-ASE. [mg/L] [mg/L] [mg/L] [mg/L] [mg/L] [mg/L] [mg/L] [mg/L]. L001 L002 L003 L004 L005 L006 L007 L008 ICPMS CV 20%.)

8 1mg/L CV 20-30%. 33.. 5 .. ICP-AES ICP-MS ICP-AES ICP-MS ICP-AES ICP-MS. AA AA.. [mg/L] [mg/L] [mg/L] [mg/L]. [mg/L] [mg/L] [mg/L] [mg/L] [mg/L]. L001 L002 L003 L004 L005 L006. L007 L008 / 108% 103% ICPAES ICPMS . CV 10% . 34. 24 . G4 .. 35. 13 .. (2mm . ) .. pH .. 50g . 500mL 2 . 10 .. 36.. 16 24 6 .. m GFP .. 3000 / . 3000G G . 2. 1 m 1118 R N 10-8. G (G . R (cm . N rpm .. 37.. 1 m .. 38. H24 .. 6 2 . PTFE EPN .. PTFE .. 39.. 3000G . 3000G .. 1 m .. 1 m . 1 m .. 40.. \2,950,000 \2,440,000 \1,050,000.. 4,215,000 2,030,000 \2,670,000 1,263,000 \2,150,000 \ 946,000.. \2,380,000.. 41.. 42.))