Transcription of JX日鉱日石金属における レア ... - jsmcwm.or.jp
1 2010 7 8 .. / . CODELCO 1,740. Nippon Mining & Metals Group 1,050. Phelps Dodge 890. Grupo Mexico 610. KGHM Polska Miedz 560.. Source : Brook Hunt Copper Metal Service 2006. &.. (LIB) .. 1 100 .. 100,000 .. / % . Co 7,000,000 130,000 Ni 64,000,000 1,700,000 Li 4,100,000 150,000 In 2,800 1,700 61. Pt 71,000 2,500 Mo 8,600,000 230,000 Ta 43,000 4,400 10. W 2,900,000 57,000 .. Cu 19% Mn 1,160ppm Al 9% Pd 1,110ppm Fe 8% Mg 520ppm Ni 1% Ba 390ppm Sn 1% Au 340ppm Cr Bi 150ppm Pb Li 120ppm Nd Co 80ppm Ta Ru 50ppm W Zr 50ppm Ag Be 40ppm Ti Sr 40ppm .. 53% Cr Si 14% Tl Cu 12% Sb Fe Mg Ca Ag Al Zr Sn Sr Pb K Zn Mn Ni Sm Ba As W Na.
2 Ppm .. (t/month). Amount of Precious Metal Scrap Recycled 6,000. 5,000. 4,000. 3,000. 2,000. 1,000. 0. 2001 2002 2003 2004 2005 2006 2007 2008 2009. Year .. CuFeS2 SiO2 Au,Ag,Pt,Pd,Cu 90% .. [ ].. H2SO4.. CuFeS2+SiO2+O2 Cu2S FeS+2 FeO SiO2+SO2+Reaction Heat [ ].. PS- .. ( ). Cu2S FeS+SiO2+O2. Cu+2 FeO SiO2+SO2+Reaction Heat . (Se,Te). (Au,Ag,Pt,Pd).. 90% .. + . + .. 6mH ..6m .. 11mH .. 22mL.. To PS- .. : CuFeS2 + SiO2 + O2 Cu2S FeS + 2 FeO SiO2 + SO2 + Reaction Heat Cu Conc. Flux Matte Slag Off-gas .. + .. (50). Peirce-Smith .. Au,Ag,Pt Pd,Cu,Se .. Au,Ag,Pt,Pd,Se . Au,Pt,Pd,Se Au.
3 Pt,Pd,Se Ag . SO2 .. Se .. Pt,Pd Au . Ag .. Solvent Extraction Plant .. & Solvent Extraction Plant .. (Hitachi Metal Recycling Complex).. (Hitachi Metal Recycling Complex).. - - . Cd, As, Cu) (Zn, Cu, As) (Pb,Sb,Bi,In,Cu) (Sb, Bi, As) (Sn, Pb, As) (Ni, Cu). Pb, As Zn,Cu,As Sn Cd Pb In Zn Sb, Bi Cd Sn . Cu, As Sb . Cu Bi Ni . Cu, As In . Bi . Cu Sb Sn Pb Cd Zn Bi In Ni .. ( ). Pb Sn Bi Ni ( ).. H2SO4 .. - HMC - .. m 6 mL.. HMC .. HMC .. HMC .. HMC . HMC .. HMC .. (10kg, 1kg) .. Co-Ni-Mn .. Ah V Wh/ Wh/kg 520 200. 5 110 40. 9 200 60. 32 12 80 40.. 1 .. 2 . Co: 4,000 /kg Ni 1,700 /kg Mn : 260 /kg Li2CO3 600 /kg.
4 LiCoO2 70 . LiNi1/3Mn1/3Co1/3O2 16 . 6 . LiMnO2 5 . LiFePO4 3 .. 50kg/ 5kg/ . 700.. 600.. 500.. 400. 300. 200. 100. 0. 2008 2009 2010 2011 2012 2013 2014 2015.. Ni-MH .. Co .. Co .. (Fe).. (Cu, Au & Ag) (Co).. Umicore, Akkuser(OMG Kokkola) etc.. Norilsk, Xstrata(Falconbridge) etc.. - - . - .. Ni Co-Mn-Li) .. UMICORE .. Hoboken Li Mn . 2,500 .. (Ni,Co) 7,000 / . ( ,Hofors) 2011 .. ( ,Olen).. Akkuser .. Akkuser . 400 / .. Co,Ni Ni : Norilsk Nickel . Co : OMG Kokkola Chemical .. TOXCO .. 2007 3 .. Mn Co Ni Li .. RH. RH NiR2 NiR2 RH RH RH. RH. RH NiR2 RH RH RH. RH RH. H+ Ni2+ SO42- Ni2+.
5 Ni2+ Ni2+ H+. H. +. H+ SO42- Ni2+. SO42- Ni2+ H+ H+.. Ni2+(aq) 2RH(org) NiR2(org) 2H+(aq). NiR2(org) 2H+(aq) SO42- (aq). Ni2+ (aq) SO42- (aq) 2RH(org).. 2009 9 2010 3 .. 21m 60m 16mH. 1,409m2 1,501m2.. 2010 3 .. 2009 .. ( Ni Co Mn Li ).. 50 t/ . 10 t/ . 6 t/ . 6 t/ 12 t/ .. ( ).
