AMINOETHYLETHANOLAMINE (AEEA) - Alliance Chemicals

1 SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 AMINOETHYLETHANOLAMINE ( aeea ) Version 3 Revision Date Print Date GB / EN 1/14 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product identifier Trade name : AMINOETHYLETHA NOLAMINE ( aeea ) Substance name : 2-(2-aminoethylamino)ethanol REACH Registration Number : 01-2119456894-24-0002 Relevant identified uses of the substance or mixture and uses advised against Use of the Substance/Mixture : Specific use(s): Chemical intermediate Details of the supplier of the safety data sheet Company : Akzo Nobel Functional Chemicals AB SE 444 85 Stenungsund Sweden Telephone : +4630385000 Telefax : +46303770551 E-mail address : Emergency telephone number Emergency telephone number : 24 hours emergency response number: +31 57 06 79211 Kemiakuten-SE: 020 99 60 00 SECTION 2.

2 HAZARDS IDENTIFICATION Classification of the substance or mixture Classification (REGULATION (EC) No 1272/2008) Skin corrosion, 1B, H314 Serious eye damage, 1, H318 Skin sensitisation, 1B, H317 Reproductive toxicity, 1B, H360Df Effects on or via lactation, H362 For the full text of the H-Statements mentioned in this Section, see Section 16. Label elements Labelling (REGULATION (EC) No 1272/2008) AMINOETHYLETHANOLAMINE ( aeea ) Version 3 Revision Date Print Date GB / EN 2 / 14 Pictogram : Signal word : Danger Hazard statements : H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H360Df May damage the unborn child. Suspected of damaging fertility. H362 May cause harm to breast-fed children. Precautionary statements : Prevention: P201 Obtain special instructions before use. P263 Avoid contact during pregnancy/ while nursing.

3 P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. Response: P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P308 + P313 IF exposed or concerned: Get medical advice/ attention. Hazardous components which must be listed on the label: AMINOETHYLETHANOLAMINE 111-41-1 Additional Labelling: Restricted to professional users. Other hazards No further data available. PBT and vPvB assessment : This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of or higher.

4 AMINOETHYLETHANOLAMINE ( aeea ) Version 3 Revision Date Print Date GB / EN 3 / 14 SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Substances Hazardous substance Chemical name PBT vPvB OEL CAS-No. EC-No. REACH No. Classif ication (REGULATION (EC) No 1272/2008) Concentration [%] AMINOETHYLETHANOLAMINE 111-41-1 203-867-5 01-2119456894-24 Skin Corr. 1B; H314 Eye Dam. 1; H318 Skin Sens. 1B; H317 Repr. 1B; H360Df Lact. H362 90 - 100 For the full text of the H-Statements mentioned in this Section, see Section 16. REACH - Candidate List of Substances of Very High Concern for Authorisation (Article 59). Status : Not applicable SECTION 4: FIRST AID MEASURES Description of first aid measures General advice : Immediate medical attention is required. Move out of dangerous area. Show this safety data sheet to the doctor in attendance.

5 If inhaled : If breathed in, move person into fresh air. Consult a physician after significant exposure. In case of skin contact : Take off contaminated clothing and shoes immediately. Rinse immediately with plenty of water. Immediate medical treatment is necessary as untreated wounds from corrosion of the skin heal slowly and with difficulty. If skin irritation persists, call a physician. In case of eye contact : Rinse with plenty of water. Get medical attention immediately. Continue to rinse during transport. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. Small amounts splashed into eyes can cause irreversible tissue damage and blindness. If swallowed : Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth to an unconscious person. AMINOETHYLETHANOLAMINE ( aeea ) Version 3 Revision Date Print Date GB / EN 4 / 14 Take victim immediately to hospital.

6 Do not induce vomiting! May cause chemical burns in mouth and throat. Most important symptoms and effects, both acute and delayed Symptoms : The symptoms and effects are as expected from the hazards as shown in section 2. No specific product related symptoms are known. Risks : May cause an allergic skin reaction. Causes serious eye damage. May damage the unborn child. Suspected of damaging fertility. May cause harm to breast-fed children. Causes severe burns. Indication of any immediate medical attention and special treatment needed Treatment : Treat symptomatically. SECTION 5: FIREFIGHTING MEASURES Extinguishing media Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special hazards arising from the substance or mixture Specific hazards during firefighting / Specific hazards arising from the chemical : Do not allow run-off from fire fighting to enter drains or water courses.

7 Combustion products : Carbon oxides Nitrogen oxides (NOx) Advice for firefighters Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus. Further information : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. SECTION 6: ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions : Use personal protective equipment. Wear respiratory protection. Ensure adequate ventilation. Environmental precautions Environmental precautions : Do not flush into surface water or sanitary sewer system. AMINOETHYLETHANOLAMINE ( aeea ) Version 3 Revision Date Print Date GB / EN 5 / 14 If the product contaminates rivers and lakes or drains inform respective authorities.

8 Methods and materials for containment and cleaning up Methods for cleaning up / Methods for containment : Contain spillage, and then collect with non-combustible absorbent material, ( sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Reference to other sections Additional advice : For personal protection see section 8. SECTION 7: HANDLING AND STORAGE Precautions for safe handling Advice on safe handling : For personal protection see section 8. Avoid formation of aerosol. Do not breathe vapours or spray mist. Avoid contact with skin. Smoking, eating and drinking should be prohibited in the application area. Dispose of rinse water in accordance with local and national regulations. Obtain special instructions before use.

9 : Persons with a history of skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used. Advice on protection against fire and explosion : Normal measures for preventive fire protection. Conditions for safe storage, including any incompatibilities Requirements for storage areas and containers : Prevent unauthorized access. Keep container tightly closed in a dry and well-ventilated place. Reacts with copper, aluminium, zinc and their alloys. Other data : No decomposition if stored and applied as directed. Specific end use(s) Specific use(s) : No information available. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components with workplace control parameters AMINOETHYLETHANOLAMINE ( aeea ) Version 3 Revision Date Print Date GB / EN 6 / 14 Contains no substances with occupational exposure limit values.

10 Exposure controls Engineering controls This substance should be handled under strictly controlled conditions as specified in REACH regulation article 18(4). Site documentation to support safe handling arrangements in accordance with risk-based management system should be available at each manufacturing site. During the whole lifecycle all necessary measures should be undertaken to minimize emissions and any resulting exposure. Effective exhaust ventilation system Ensure that eyewash stations and safety showers are close to the workstation location. Personal protective equipment Respiratory protection : In the case of vapour or aerosol formation use a respirator with an approved filter. Wear full face mask supplied with: Gas cartridge K (ammonia, green). Hand protection : butyl-rubber Eye protection : Safety glasses with side-shields conforming to EN166 Skin and body protection : Protective suit Hygiene measures : When using do not eat or drink.