Appendix I PID Correction Factors Appendix I PID ...

1 191 Appendix I PID Correction Factors Compound Name Formula C C C IP (eV) + Acetic AcidC2H4O2NR+22+ + Acetic AnhydrideC4H6O3NR+ + + + + + AcroleinC3H4O42+ + + Acrylic AcidC3H4O212+ + AcrylonitrileC3H3 NNR+ + Allyl + Allyl AmmoniaH3 NNR+ + + Amyl + + + + + + Benzyl BromoformCHBr3NR+ + + Bromopropane,1-C3H7Br150+ + + + Butadiene diepoxide,1,3-C4H6O225+ + ~10 Butanol, 1-C4H10O70+ + + Butene, Butoxyethanol, + + +<10 Compound Name Formula C C C IP (eV)Notes:1.

2 The values indicated by a plus (+) sign inthe C column are confirmed values; allothers are preliminary and subject to The Correction Factors in this table were mea-sured in dry air. Actual readings may varywith age and cleanliness of the lamp, rela-tive humidity, components in the sample,and other Factors . For accurate work, theinstrument should be calibrated regularlyunder the operational conditions in whichthe instrument is IP (eV) data was taken from the CRC Hand-book of Chemistry and Physics, 73rd Edition,and NIST Standard Ref.

3 Database 19A.(Courtesy of RAE Systems, Inc.) Appendix IPID Correction Factorsfor Various Gases and Lamps with Instrument Calibrated to Isobutylene192 Hazardous Gas Monitors Compound Name Formula C C C IP (eV) Butyl acetate, +10 Butyl acrylate, + + Butyl Carbon + Carbon tetrachlorideCCl4NR+NR+ + + Chloro-1,3-butadiene, 2-C4H5Cl3 + + + Chloro-1,1-difluoroethane, 1- (R-142B) ChloroethaneC2H5 ClNR+NR+ + Chloroethyl methyl ether,2-C3H7 ClO3 ChloroformCHCl3NR+NR+ + Chlorotoluene, Chlorotoluene, + + + + + + Cyanogen Cyanogen + + + + + + + + Diacetone Dibromoethane, 1,2-C2H4Br2NR+ + + Dichlorobenzene, + + + I PID Correction Factors Compound Name Formula C C C IP (eV)

4 DichlorodifluoromethaneCCl2F2NR+NR+ Dichloroethane, 1, Dichloroethane, 1,2-C2H4Cl2NR+ + Dichloroethene, 1, Dichloroethene, c-1, Dichloroethene, t-1, + + Dichloro-1-fluoroethane, 1,1- (R-141B)C2H3Cl2 FNR+NR+ + Dichloropropane, 1, Dichloro-1-propene, 2, + + +<10 Dichloro-1,1,1-trifluoro- ethane, 2,2- (R-123)C2 HCl2F3NR+NR+ + Diesel Fuel # + Diesel Fuel # + + DiethylamineC4H11N1 + Diethylaminopropylamine, DiethylmaleateC8H12O44 Dimethylacetamide, N, + + + Dimethyl + + + Dimethylformamide, N, Dimethylhydrazine, 1, + + Dimethyl sulfateC2H6O4S~23~20 + + Dioxane, 1, EpichlorohydrinC2H5 ClO~200 + + + EthaneC2H6NR+15+ EthanolC2H6O12+ Ethanolamine (Not Recommended)

5 C2H7NO~4+~3+ EtheneC2H410+ Ethoxyethanol, Ethyl + Gas Monitors Compound Name Formula C C C IP (eV) Ethyl + +(< ) + + + Ethylene glycolC2H6O216+6+ Ethylene oxideC2H4O19+3+ Ethyl + Ethyl Ethyl hexyl acrylate, + + Ethyl (S)-(-)-lactateC5H10O313+ + +~10 Ethyl Ethyl + + + Gasoline # + Gasoline #2, 92 + + + + + + HCFC-123 (see 2,2-Dichloro-1,1,1-trifluoroethane, R-123) HCFC-141B (see 1,1-Dichloro-1-fluoroethane) HCFC-142B (see 1-Chloro-1,1-difluoroethane) Heptane, + Hexamethyldisilazane,1,1, 1,3,3,3- + +~ Hexane, + + Hexene, 1-C6H12 + + HydrogenH2NR+NR+NR+ Hydrogen peroxideH2O2NR+NR+NR+ Hydrogen sulfideH2 SNR+ + + + + + IsobutaneC4H10100 + + IsobutanolC4H10O19+ + I PID Correction Factors Compound Name Formula C C C IP (eV)

6 + + + Isobutyl + + IsofluraneC3H2 ClF5O Isopar G + Isopar M + + + + + IsopropanolC3H8O500+ + Isopropyl Isopropyl Jet fuel 1151+ + Jet fuel + + Jet fuel + + Kerosene (C10-C16 - see Jet Fuels) + + + MethaneCH4NR+NR+NR+ MethanolCH4 ONR+NR+ + Methoxyethanol, + + + Methoxyethoxyethanol, + + +<10 Methyl Methyl + +( ) Methyl bromideCH3Br110+ + + Methyl t-butyl + Methyl cellosolve (see 2-Methoxyethanol) Methyl chlorideCH3 ClNR+NR+ + Methylene chlorideCH2Cl2NR+NR+ + Methyl ethyl + + + + + + Methyl isobutyl + Gas Monitors Compound Name Formula C C C IP (eV) Methyl isocyanateC2H3 NONR+ + Methyl Methyl + Methyl propyl + + Methyl-2-pyrrolidinone, + + + Methyl salicylateC8H8O32 Methylstyrene, Mineral spirits (Stoddard Solvent, see also Viscor 120B) + + Mineral Spirits Viscor 120B Calibration + + + Naphthalene (Mothballs)

7 + + + Nitric + + + + + Nitrogen dioxideNO2NR+NR+ Nitropropane, Octane, + + PentaneC5H1280+ + + Peracetic acidC2H4O3NR+NR+ + Peracetic/Acetic acid mix C2H4O3/C2H4O250+ + + + + + + + + + + + + + Phosphine in N2PH32+ Photocopier + + Picoline, Pinene, + I PID Correction Factors Compound Name Formula C C C IP (eV) Pinene, + + +~8 Piperylene, isomer + + + PropaneC3H8NR+ + Propanol, + Propyl acetate, Propylene + + + + + + RR7300 (70.)

8 30 PGME/PGMEA)C4H10O2 + + Stoddard Solvent - see Mineral Spirits + + + Sulfur dioxideSO2NR+NR+ Tetrachloroethane, 1,1,1, ~ Tetrachloroethane, 1,1,2,2-C2H2Cl4NR+NR+ +~ ~ Tetraethyl + +~ Tetrafluoroethane, 1,1,1,2-C2H2F4 NRNR TetrafluoromethaneCF4NR+NR+> + + + + + + + + Tolylene-2, + + + Trichloroethane, 1,1,1-C2H3Cl3NR+1+11 Trichloroethane, 1,1,2-C2H3Cl3NR+NR+ + + + + Trichlorotrifluoroethane, 1,1,2- Trifluoroethane, 1,1, Gas Monitors Compound Name Formula C C C IP (eV) Trimethylbenzene, 1,3,5- - (see Mesitylene) Vinyl Vinyl Vinyl chloride in + + Vinyl-2-pyrrolidinone, + + + Viscor 120B - see Mineral Spirits - Viscor 120B Calibration Fluid Xylene, + + + Xylene, + + Xylene, + +