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1 2016 419 6. 1 1 Dd HPLC 215 nm Dd-N 4 2 a JIS K 8891 b HPLC HPLC c HPLC d 1 mg/mL 1 C2H4N4 2 g mg 100 mL 6 e mg/mL 1 mg/mL 10 mL 100 mL f 10 g/mL 50 g/mL mg/mL 5 mL 25 mL 50 mL g 1 g/mL 10 g/mL 20 g/mL mL 25 mL 50 mL 1 2 98 % 1. 3 a HPLC JIS K 0124 HPLC 1 4 mm 6 mm 150 mm 250 mm 2 30 C 45 C 3 215 nm b c 8000 g 10000 g 2.

2 Hibar LiChrosorb NH2 Inertsil NH2 Unison UK-Amino Mightysil NH2 Shim-pack CLC-NH2 Shodex NH-5A Unisil Q NH2 2016 420 4 a g 200 mL 300 mL b 100 mL 3 10 c 4 mL d 8000 g 10000 g 5 5 e 1 mL 3 4 5 cm cm 10000 rpm 8100 g 10000 g 3. c e PTFE m JIS K 0124 HPLC a HPLC HPLC 1 4 mm 6 mm 150 mm 250 mm 5 m 2 30 C 40 C 3 6+1 4 1 mL/min 5 215 nm b 1 10 L HPLC 215 nm 2 215 nm c 1 10 L b 1 2 Dd Dd 3 Dd-N Dd-N % A MW1/MW2 A A Dd % MW1 4 2016 421 MW2 4.

3 3 2 6 % % % % % 1 % 1 2 25~31 (2009) 2 2 32~37 (2009) 5 1 2 sr4 RSDr5 sR6 RSDR7 1 % 3 % 3 % % 3 % 5 2 n= 2 6 3 7 4 200 mL 300 mL 100 mL 10 8000 g 10000 g 5 g 2016 422 HPLC 2 HPLC 1 100 ng 10 g/mL 10 L 2 HPLC Hibar LiChrosorb NH2 mm 25 cm 5 m a HPLC 2016 423 2 1 HPLC 190 nm Dd-N

4 B-N U-N Gu-N Gy-N 5 2 a JIS K 0557 A3 b JIS K 9007 c JIS K 9005 d Dd-N 2 mg/mL (1) C2H4N4 2 g mg 100 mL e Dd-N 200 g/mL B-N 2 mg/mL 10 mL 100 mL f Dd-N 50 g/mL 100 g/mL Dd-N 200 g/mL 25 mL 50 mL 100 mL g Dd-N 1 g/mL 50 g/mL Dd-N 100 g/mL 1 mL 50 mL 100 mL 1 2 98 % 1. 3 a HPLC JIS K 0124 HPLC 1 mm 100 mm 5 m 10 m 2 30 C 45 C 3 190 nm b c 8000 g 10000 g 2.

5 Asahipak ES-502C 7C 2016 424 4 a g 200 mL b 100 mL 10 c 3 4 mL d 8000 g 10000 g 5 5 3 Dd-N 4 5 cm cm 10000 rpm 8100 g 10000 g a g 100 mL b 50 mL c 6 4 mL d 8000 g 10000 g 5 5 6 Dd-N 3. c d c d PTFE m JIS K 0124 a 1 mm 100 mm 5 m 10 m 2 40 C 3 1 g g 1000 mL PTFE m 4 mL/min 5 10 L 6 190 nm 4.

6 G g 500 mL 10 PTFE m 2016 425 b 1 10 L HPLC 190 nm 2 Dd-N 190 nm c 1 10 L b 1 2 Dd-N Dd-N 5. B-N U-N Dd-N Gu-N Gy-N 5 5 g 200 mL 100 mL 10 g 100 mL 50 mL 8000 g 10000 g 5 2016 426 1 IC Cl 3 2 a JIS K 0557 A4 b 1 mol/L c 98 % d 6- (1)

7 97 % e 97 % f Cl- 1 mg/mL Cl- 1000 mg/L g Cl- 100 g/mL Cl- 1 mg/mL h Cl- 5 g/mL 50 g/mL Cl- 100 g/mL 5 mL 50 mL 100 mL i Cl- 1 g/mL 2 g/mL Cl- 20 mg/L 5 mL 10 mL 100 mL j 1 mol/L mL 1000 mL PTFE m (2) k g 6- g g 1000 mL 500 mL PTFE m (2)(3) 1 6- -n- 2 3 10 10 1. 2 Cl- mg/mL 3 a b 1700 g c IC JIS K 0127 IC 1 mm 250 mm 5 m 4 2016 427 (4) mm 100 mm 4 (5) 2 40 C 3 4 d m PTFE 4 Shodex IC SI-52 4E 5 Shodex IC NI-424 4 a g 200 mL b 100 mL 10 c 50 mL d 1700 g 5 (6) e 20 (7)

8 F m 6 cm 3000 rpm 1700 g 7 20 2. c d 3 JIS K 0127 IC a IC aa 1 4 4 mm 250 mm 5 m 2 40 C 3 2 4 mL/min 5 20 L 6 ab 1 4 mm 100 2016 428 mm 2 40 C 3 2 k 4 mL/min 5 20 L 6 b 1 20 L IC 2 c 1 20 L b 1 2 Cl 3. % % % 10 % % % % % % % % % % % % % % 1 % 2016 429 1 IC 8 50~60 (2015) 5 1 2)sr4)RSDr5)sI(T)6)RSDI(T)7)T1)(%)3)(%)3 )(%)(%)3)(%)

9 1 2 4 2 T 2 5 3 6 7 g 200 mL 100 mL 10 2000 g 10 20 PTFE m 2016 430 IC A B C) D) ) ) IC 1. Cl- Cl- Cl- Cl- Cl- 2016 431 1 mol/L Cl 2 a JIS K 0557 A3 b JIS K 8541 HNO3 60 % c mol/L 1 JIS K 8550 17 g 2000 mL 1000 mL JIS K 8005 600 C 25 C 1 g mg 250 mL (1)

10 Mol/L 10 mL 200 mL 5 g/100 mL mol/L mol/L mol/L f W1 A/100 1 V1/V2 1000/V3 1/C W1 A/V3 4 W1 g A % V1 10 mL V2 250 mL V3 mol/L mL C mol/L mol/L d 5 g/100 mL 1 JIS K 8312 5 g 100 mL 1 3 a b pH pH 1 pH 11 pH 1 1. pH UNIV 2016 432 4 a g 200 mL b 100 mL 10 c 3 a 25 mL 200 mL b pH pH 1+10 c 5 g/100 mL mol/L d Cl % V4 C f /W2 100/1000 V5/ V6 V4 f /W2 V4 mol/L mL C mol/L mol/L f mol/L V5 b 100 mL V6 a 25 mL W2 g 1 ~201 (1988)