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FLUORSPAR (Acid Grade) Material Safety Data Sheet

-PRODUCTIDENTIFICATIONP roductTradeName:FluorsparChemicalName/Sy nonyms:CalciumFluorideChemicalFormula:Ca F2 ChemicalFamily:CalciumFluoridesaltUtiliz ation:Fluxinferrousmetallurgy;Production ofglassandhydrofluoricacid, -HAZARDOUSINGREDIENTS/ IDENTITYINFORMATIONWHMIS(Canada)Notcontr olledClassification(EEC)Notcontrolled(Se esection15). , -PHYSICAL/CHEMICALCHARACTERISTICSNameCal ciumFluorideAmorphousSilicaCalciumCarbon ate7789-75-57631-86-91317-65-3 Percent(%) , :Mucousmembranes,upperrespiratorytract, -FIRE-FIGHTINGMEASURESF lashPointNotapplicableFlammableLimitsNot applicableAuto-IgnitionTemperatureNotapp licableProductsofCombustionCalciumoxide; Carbondioxide; :Flammablewhenexposedtoheator1 SECTION6 , (mechanicalimpact:staticdischarge), self-containedbreathingapparatus(SCBA).

SECTION 6 - ACCIDENTAL RELEASE MEASURES Measures Use appropriate tools to minimize dust generation. Put the spilled solid in a convenient recycling container.

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  Grade, Acid, Fluorspar, Acid grade

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Transcription of FLUORSPAR (Acid Grade) Material Safety Data Sheet

1 -PRODUCTIDENTIFICATIONP roductTradeName:FluorsparChemicalName/Sy nonyms:CalciumFluorideChemicalFormula:Ca F2 ChemicalFamily:CalciumFluoridesaltUtiliz ation:Fluxinferrousmetallurgy;Production ofglassandhydrofluoricacid, -HAZARDOUSINGREDIENTS/ IDENTITYINFORMATIONWHMIS(Canada)Notcontr olledClassification(EEC)Notcontrolled(Se esection15). , -PHYSICAL/CHEMICALCHARACTERISTICSNameCal ciumFluorideAmorphousSilicaCalciumCarbon ate7789-75-57631-86-91317-65-3 Percent(%) , :Mucousmembranes,upperrespiratorytract, -FIRE-FIGHTINGMEASURESF lashPointNotapplicableFlammableLimitsNot applicableAuto-IgnitionTemperatureNotapp licableProductsofCombustionCalciumoxide; Carbondioxide; :Flammablewhenexposedtoheator1 SECTION6 , (mechanicalimpact:staticdischarge), self-containedbreathingapparatus(SCBA).

2 Largeconcentrationsoffumesordust:Usea self-containedbreathingapparatus(SCBA) :Usea (respirabledust) ,Denmark,EU(Directive2000/39/EC)**,Finla nd,France,Greece,Ireland,Italy,Luxembour g,Mexico,Portugal,SouthAfrica:OEL(asF) :ACGIHTLV-TWA(asF) :OEL(asF) ;STEL(asF) Austria:OEL(asF) ;STEL(asF) (Frequencyx Durationinminutes/shift:2 x30).Estonia,Netherlands,Sweden:OEL(asF) :2 mg/m3 Germany:OEL(asF)(Inhalablefraction):1 * mg/m3;STEL(asF,15min.)(Inhalablefraction ):4(multiplicationfactor).Poland:MAC(asH F):1 mg/m3;MAC-STLV(asHF):3 :OEL(asF)(Inhalabledust):1 mg/m3;STEL(asF)(Inhalabledust): 4( Durationinminutes/shift:4xiS).Iceland,No rway:OEL(asF) :ACGIHTLV-TWAandOSHAPEL-TWA(asF) *IftheOELvalueiscompliedwith,thereshould benoriskofreproductivedamage.

3 **CommissionDirective2000/39/ECof8 June2000establishinga firstlistofindicativeoccupationalexposur elimitvaluesinimplementationofCouncilDir ective98/24/EContheprotectionofthehealth andsafetyofworkersfromtherisksrelatedtoc hemicalagentsat work,OJ(L142)47, :NameConditionsforstorageCalciumFluoride AmorphousSilicaCalciumCarbonateSECTION7 (acids). Ingestionorinhalation:Seekmedicaladvicei mmediatelyandprovidemedical():>,personne lwitha ~c::J0) ~SECTION8 -EXPOSURECONTROLS/PERSONALPROTECTIONC ontrolParametersUnitedKingdomOEL-TWA(mg/ m3)2 Amorphoussilica:ACGIHTLV-TWA(USA):Notest ablished;OSHAPEL-TWA(USA):80/%Si02;NIOSH REL-TWA 10hours):6 mg/m3;IDLH:3000mg/m3 Calciumcarbonate:ACGIHTLV-TWA(USA):Notes tablished;OSHAPEL-TWA(USA):80/%Si02 NIOSHREL-TWA 10hours):5 mg/m3(respirablefraction),10mg/m3(total) .

4 , -PHYSICALANDCHEMICALPROPERTIESP hysicalStateandAppearanceSolid( (1%soln/water)NotapplicableColorLightora ngetotanBoilingPoint2 500 C(4532 F)VolatilityN/AMeltingPoint1 420 C(2588 F)%Moisture9%(Max.) (Water=l) (inwater)N/AVaporDensityNotavailableDisp ersionN/ temperaturesabove1000 (above1000 C). :Acids,chemicallyactivemetals,reducingag ents, :Possibilityofproductionofhydrofluoricac id(Hydrogenfluoride).Amorphoussilica:Vio lentreactionwith:Fluoride,oxygendifluori de, :Alum,ammoniumsalts,mercuryandhydrogen,f luorine,magnesium, ;Calciumfluoride:NOTA CARCINOGEN(IARC);NOTCLASSIFIABLE(Human,A 4,ACGIH).Amorphoussilica:NOTCLASSIFIABLE (Human,Group3,IARC);NOTLISTED(ACGIH). :ORAL acute(LD50):4250mg/kg(Rat):INTRAPERITONE AL(LD50):>1 500mg/kg(rat);2 638mg/kg(Mouse).)

5 (RTECS).Amorphoussilica:ORAL acute(LD50):3 nose,throat, :coughing, :Targetorganforacuteandchronicoverexposu re(NIOSH90-117) (Fibrosisofthelungs). :skin,eyes, nose,throat, :sneezingandcoughing,useanantacid(smallq uantity); ,drinking, ,drinking, (Toxicity)RemarksonEnvironmentBOD5andCOD L agunaClayCompanyRiskPhrases(EEC)SafetyPh rases(EEC)CEPADSL(CANADA) :ORAL acute(LD50):3 160mg/kg(Rat).INTRAVENOUS acute(LD50):15mg/kg(Rat).(RTECS). DISPOSALCONSIDERATIONSD isposalmethodsRecycletoprocess, waste,materialshouldbetestedtodeterminei fitmustbeclassifiedasa hazardouswasteundertheResourceConservati onRecoveryAct( ).DiscardinfullcompliancewithFederal, (Transport) (EEC)EU: :EUConsolidatedInventories:numeroEC232-1 88-7 Amorphoussilica:EUConsolidatedInventorie s:ECNumber231-545-4 Calciumcarbonate:EUConsolidatedInventori es:numeroEC215-279-6 NotclassifiedintheAnnexIofDirective67/54 8/EECN otlistedintheAnnexIofCouncilRegulationNo (EC)304/2003 Notlistedina minimallyhazardouswheninitsdeliveredstat ecombinedwithabout10%maximumwaterasa (USA)(Pictograms)DSCL(Europe)(Pictograms )ADR(Europe)PictogramsSECTION16-OTHERINF ORMATIONR eferences-TLVsandBEIs(2009).

6 BasedontheDocumentationoftheThresholdLim itValuesforChemicalSubstancesandPhysical Agents& ,Cincinnati,OH- (2009)- CanadianCentreforOccupationalHealthandSa fety- (2008).EmergencyResponseGuidebook,USDepa rtmentofTransportation,TransportCanada,e tIeSecretariatofCommunicationsandTranspo rtationofMexico-HSDB(2009)- Networkofdatabasesontoxicology,hazardous chemicals, ,USNationalLibraryofMedicine, NHI,8600 RockvillePike,Bethesda,MD20894- :C&L(ClassificationandLabeling),substanc esorpreparationsinaccordancewithDirectiv e67/548/EEC(substances)and1999/45/EC(pre parations),-ESIS:EINECS(EuropeanInventor yofExistingCommercialChemicalSubstances) , 54 ,2002/C54 MonographsontheEvaluationofCarcinogenicR iskstoHumans(collection)- (1999).

7 Merck&Co.,Inc.,lthedition-NIOSHUS(2009)- PocketGuidetoChemicalHazards- 'sIndustrialHygieneandToxicology,3rdRevi sedEdition-Reglementsurlesproduitscontro les(Canada)-RTECS(2009).RegistryofToxicE ffectsofChemicalSubstances,NIOSH,CDC-Tox icologieindustrielle&intoxicationprofess ionnelle,3eedition,Lauwerys-TSCA(2009)-U SEPAT oxicSubstanceControlAct, (SoR),SubstanceRegistryServices, :HSDB:IARC:NIOSH:NTP:OSHA.


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