台湾のGHS分類基準について - isha.org.tw

1 GHS ( ) GHS 2 GHS ( ) GHS Building block approach ( GHS GHS GHS Building block approach EU 2008 REACH CPL (EU) 1272/2008 GHS Cut-off value /concentration limits / Cut-off value Concentration limits Cut-off value/concentration limits EU 2008 REACH Concentration limits EU Cut-off value/concentration limits Cut-off value GHS MSDS GHS EU Concentration limits 3 2006 GHS Cut-off value/ concentration limits)

2 Cut-off value concentrationlimits GHS GHS MSDS GHS 2008 GHS JIS Cut-off value concentration limits EU 2009 GHS JIS GHS MSDS 2008 GHS GHS CNS 15030-Z1051 CNS15030-Z1051 GHS 2 Cut-off value/ concentration limits GHS / GHS GHS MSDS 2006 GHS 4 EU REACH (2007 6 GHS Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006, concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC.)

3 OJ L 396, , p. 1 849 (EN) GHS (CLP 2008 12 )Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, and amendingand repealing Directive 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. (Dec. 31 2008) :L:2008:353:0001: 1355:EN:PDF GHS RIP )RIP 3 RIP : Guidance on Classification and Labeling under Global Harmonized System. Building block CLP EU SDS E U5EU CLP REGULATION (EC) No 1272/2008 2 31 cut-off value means a threshold of any classified impurity, additive or individual constituent in a substance or in a mixture, above which threshold these shall be taken into account for determining if the substance or the mixture, respectively, shall be classified; cut-off value 32 concentration limit means a threshold of any classified impurity, additive or individual constituent in a substance or in a mixture that may trigger classification of the substance or the mixture, respectively.

4 Concentration limit JETOC No. 256 21 3 6 Building block SDS 2 EU CLP / / TOST

5 Building block ( 06/12 ) MSDS SDS MSDS JIS Z 7250-2005 JIS Z 7251-2006 MSDS GHS MSDS ( 05/12- 06/6)( 06/7)( 05/5- 06/6)( 05/4)( 04/5)( 06/5)( 08/3)( 06/3) ( 1stVer.)( StRev.)( 2ndRev.) ( 08/3) GHS JIS Z 7252-2009 GHS ( 09 9 )( 09 6 ) 9( )( ) (JIS JIS GHS JIS Z 7252 : 2009 2009 9 JISGHS JIS Z XXXX 2009 JIS MSDS 1 : JIS Z 7250 : 2005 2005 12 JIS GHS JIS Z 7251 :2006 2006 3 21 6 10 GHS GHS Gr.)

6 (2005 12 ) GHS (2009 6 )GHS GHS GHS (2006 2 ) GHS JIS GHS 19 GHS GHS (2008 3 )+++ GHS GHS GHS 11 GHS JIS (standardization).pdf GHS JIS Z 7252 : 2009 2009 6 GHS 2 Building block approach / GHS (JIS Z 7252-2009) GHS JIS / / TOST Building block 13 GHS (JIS Z 7252-2009)

7 (a) 10% (b) 10% ATEmix ( ) ATE (i) LD50 / LC50(ii) (iii) 100 ATEmix = CiATEi 100 ( C unknown if > 10%)ATEmix = CiATEi 14 GHS (JIS Z 7252-2009) [ ][ ] 5% 5% 1% 10%(10 ) 10% pH 2 1% pH 1% 1% 3% 15 GHS (JIS Z 7252-2009) / [ ][ ] 3% 3% 1% / 10%(10 )

8 / 10% 3% 3% 1%10 / 10% pH 2 1% pH 1% 1% 3% 16 GHS (JIS Z 7252-2009) / 1 MSDS GHS / 1 1 1 17 / / GHS (JIS Z 7252-2009) 1 2 1 2 - 1 2 MSDS GHS GHS (JIS Z 7252-2009) 1 2 1 2 - 1 19 1 MSDS GHS GHS (JIS Z 7252-2009)

9 1 2 1 1 2 1 1 20 ( ) 1 10% MSDS GHS 2 20% 20% GHS (JIS Z 7252-2009) 10% 1 10% 10% 1 21 ( ) 1 10% MSDS GHS GHS (JIS Z 7252-2009) 10% 1 10% 10% 1 22 1 10% 40 C mm2/s GHS (JIS Z 7252-2009) 232323 (A) additivity formula LC50 EC50 (B) summation method a GHS (JIS Z 7252-2009) 1 M a 25% 1(M 10 1)

10 + 2 25% 2(M 100 1)+(10 2)+ 3 25% 3 1 M a 25% 1(M 10 1)+ 2 25% 2(M 100 1)+(10 2)+ 3 25% 3 1+ 2+ 3+ 4 25% 4 Ci L ( E ) C 50m = Ci L ( E ) C 50i n [ 3 ]24 1986 11 26 17 1998 5 5 2000 2 (1974 4 16 5 7 (2008 10 ) CNS15030-Z1051 CNS15030-Z1051 GHS 2 2008 12 GHS 2007 10 19 2008 12 31 GHS 250 1 1062 2008 12 31 2009 25 CNS15030-Z1051 CNS15030 CNS15030-1 CNS15030.)