Glass Transition Temperature - MIT OpenCourseWare
FAST V XL (T) SLOW T FAST (T) W Free volume, V F – extra space beyond what is present in an ordered crystalline packing (beyond the interstitial volume). V F (T) ≡V(T) – V 0 (T) • V 0 is occupied specific volume of atoms or molecules in the xline state and the spaces between them: ~ V XL. V(T) • V α l F
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