MARASPERSE N-22 - POWDER

1 SECTION 1: Identification of the substance/preparation and of the Product identifierTrade name: MARASPERSE N-22 - POWDERS ynonyms:Sodium Relevant identified uses of the substance or mixture and uses advised againstRecommended uses:Binder Dispersing Details of the supplier of the safety data sheetSupplierCompany:LignoTech USA, IncAddress:100 Grand AvenueRothschild, WI 54474-1198 Country:UNITED Emergency Telephone Number+1(715)359-6544 (Emergency phone) +1(800)424-9300 (Chemtrec phone) (24h)SECTION 2: Hazards Classification of the substance or mixtureCLP Classification - otherinformation:The product does not have to be Label elementsSignal Other hazardsNuisance dust.

2 OSHA Hazard Category: Combustible Dust. Warning. May form combustible dust concentrations in 3: Composition/information on MixturesSubstanceCAS numberEC NoREACH 91%Water7732-18-523-17-912 9%Issued: 15-05-2015 Safety Data SheetMARASPERSE N-22 - POWDER1 / 6 Copyright 1995 - 2015 DGOffice A/S, : 15-05-2015 Safety Data SheetMARASPERSE N-22 - POWDERP lease see section 16 for the full text of R-phrases and 4: First aid Description of first aid measuresInhalation:Seek fresh :Wash out mouth thoroughly and drink 1-2 glasses of water in small contact:Wash the skin with water. Remove contaminated contact:Flush with water (preferably using eye wash equipment) until irritation subsides.

3 Seekmedical advice if symptoms Most important symptoms and effects, both acute and delayedNuisance Indication of any immediate medical attention and special treatment 5: Fire-fighting Extinguishing mediaSuitable extinguishing media:Extinguish with POWDER , foam, carbon dioxide or water extinguishingmedia:Do not use water stream, as it may spread the Special hazards arising from the substance or mixtureNote the risk of dust Advice for fire-fightersWear Self-Contained Breathing Apparatus (SCBA) with a chemical protection 6: Accidental release Personal precautions, protective equipment and emergency proceduresFor non-emergency personnel:Avoid formation of dust.

4 Provide good Environmental precautionsAvoid unnecessary release to the environment. Prevent spillage from entering drains and/or surface Methods and material for containment and cleaning upSweep up/collect spills for possible reuse or transfer to suitable waste Reference to other sectionsSee section 8 for type of protective equipment. See section 13 for instructions on 7: Handling and storage2 / 6 Copyright 1995 - 2015 DGOffice A/S, : 15-05-2015 Safety Data SheetMARASPERSE N-22 - Precautions for safe handlingWork under effective process ventilation ( local exhaust ventilation). Conditions for safe storage, including any incompatibilitiesStore in a dry, cool, well-ventilated area.

5 Avoid accumulation of Specific end use(s)SECTION 8: Exposure controls/personal Control parametersOccupational exposure limitSubstance nameTime periodppmmg/m3 CommentRemarksNuisance dust(OSHA PELV)8h15totalNuisance dust(OSHA PELV)8h5respirableBiological threshold values:Avoid formation of Exposure controlsAppropriate engineeringcontrols:Provide good protective equipment,eye/face protection:Wear safety goggles if there is a risk of dust contact with protective equipment,skin protection:In the event of direct skin contact, wear protective gloves:Personal protective equipment,respiratory protection:Wear respiratory protective equipment with P2 filter when performing dusty work.

6 NIOSH approved dust mask 9: Physical and chemical Information on basic physical and chemical propertiesParameterValue/unitStatePowder ColourBrownOdourMildSolubilityWater propertiesOxidising propertiesParameterValue/unitRemarkspH (solution for use)8(3% sol)pH (concentrate)Not point CNot point CNot boiling point and boiling range CNot Point CNot rateNot (solid, gas)Not / 6 Copyright 1995 - 2015 DGOffice A/S, : 15-05-2015 Safety Data SheetMARASPERSE N-22 - POWDERF lammability limitsNot limitsvol%LEL: UEL: pressurekPaNot densityNot densityNot coefficient n-octonol/water100% temperature> 400 C(for dust)Decomposition temperature> 200 CViscositycStNot thresholdppmNot Other - g/ml (bulkdensity)Combustible Dust CharacteristicsMIE: 1130 mJoule; Kst: St1 (0-200 bar*m/s); Partsize: 100% < 150 10: Stability and ReactivityNot Chemical Possibility of hazardous reactionsNone Conditions to avoidAvoid formation of dust.

7 Avoid spark due to static Incompatible materialsStrong Hazardous decomposition productsTypical combustion 11: Toxicological Information on toxicological effectsAcute toxicity - oralSodium lignosulfonateOrganismTest TypeExposure timeValueConclusionTest methodSourceRat > 7000mg/kgBased on existing data, the classification criteria are deemed not to have been toxicity - inhalation:The product does not have to be / 6 Copyright 1995 - 2015 DGOffice A/S, : 15-05-2015 Safety Data SheetMARASPERSE N-22 - POWDERSkin corrosion/irritation:The product does not have to be eye damage/eyeirritation:The product does not have to be sensitisation orskin sensitisation:None cell mutagenicity:None properties:The product does not have to be 12: Ecological ToxicitySodium lignosulfonateOrganismSpeciesExposure timeTest TypeValueConclusionTest methodSourceAcute algaeScenedesmussubspicatus24, 48, 72hEC50 > 600mg/lSimilar productAcute DaphniaDaphniamagna24, 48hEC50 > 1000mg/lSimilar productAcute fishBrachydaniorerioEC50 > 1000mg/lSimilar productNo effect on the environment.

8 Based on existing data, the classification criteria are deemed not to have been Persistence and degradabilityPartially biodegradable BOD: 300g 02/kg ( solution) & COD: 1200g 02/kg ( solution) Bioaccumulative potentialNo bioaccumulation Mobility in soilSolubility in water: Completely Results of PBT and vPvB assessmentThe product does not contain any PBT or vPvB Other adverse effectsNone 13: Disposal Waste treatment methodsDispose of in accordance with Local Authority 14: Transport UN-No.:Not Packing group:Not UN proper shippingname:Not Environmentalhazards:Not / 6 Copyright 1995 - 2015 DGOffice A/S, : 15-05-2015 Safety Data SheetMARASPERSE N-22 - Transport hazardclass(es):Not Special precautions for Transport in bulk according to Annex II of MARPOL73/78 and the IBC codeNot Information:DOT Class 55 Lignin Pitch - Harmonized Tariff Code for 15: Regulatory Safety, health and environmental regulations/legislation specific for the substance or mixtureSpecial Provisions:ADR/RID (2007) ECHA FAQ GHS / CLP (EC NO1272/2008) GHS USA June, / limitations:Global inventory status: Australia.

9 On AICS Australian Inventory of Chemical Substances,June 1996 Ed Canada: On DSL Supplement to Canada Gazette, Part I, January 26, 1991 China: On IECSC Inventory of Existing Chemical Substances in China, 2013 Japan: OnENCS Unlisted chemical name. For ENCS chemical class or category name, refer to ENCSNo. 8-209. Korea: On ECL Korean Existing Chemicals List, January 1997, ECL Serial No.:KE-04572 Mexico: On INSQ National Inventory of Chemical Substances in Mexico, 2012 New Zealand: On NZIoC New Zealand Inventory of Chemicals, 2006 May be used as asingle component chemical under an appropriate group standard. Philippines: On PICCSP hilippines Inventory of Chemicals and Chemical Substances, 2000 Switzerland: OnSWISS Giftliste 1 (List of Toxic Substances 1), 31 May 1999, SWISS No.

10 : G-44534 USA:On TSCA Inventory January 2015 TSCA Inventory EPA Flags: XU Exempt from Update Chemical Safety AssessmentOther Information:The product does not have to be 16: Other informationOther Information:Government regulations for use of this product are summarized below: 21 CFR -Adhesives 21 CFR ; ; ; - Paper and paperboardcomponents 21 CFR - Defoamers 21 CFR - Polymers 21 CFR Animal feed 21 CFR - Substances generally recognized as safe 40 CFR ; ; ; 21 CFR ; - Pesticides for FoodVendor notes:Information given in this safety data sheet is in accordance with our information, and to thebest of our knowledge, was correct on the last revision date.