MATERIAL SAFETY DATA SHEET (JURA Model)

1 Monomeric MDI, Japan Urethane Raw Materials Association, 0333 1 13 Creation Date March 31, 1993 Revision Date June 23, 2010 Issue Date MATERIAL SAFETY data SHEET ( jura model ) 1. CHEMICAL PRODUCT & COMPANY IDENTIFICATION CHEMICAL PRODUCT Product name Monomeric MDI Other means of identificaition Diphenylmethane-4,4 -diisocyanate; Bis(1,4-isocyanatophenyl)methane; Methylene bisphenyl isocyanate; MDI COMPANY IDENTIFICATION Company name Japan Urethane Raw Materials Association Address Department Telephone Emergency telephone Fax e-mail address MSDS No 0333 RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE The main use is polyurethane raw materials ( flexible and semi-rigid foam, rigid foam, elastomer, artificial leather and synthetic leather, spandex fiber, paint, glue, binder, etc ).

2 2. HAZARD IDENTIFICATION GHS CLASSIFICATION OF THE SUBSTANCE OR MIXTURE PHYSICAL HAZARDS Explosives Not applicable Flammable gases Not applicable Flammable aerosols Not applicable Oxidizing gases Not applicable Gases under pressure Not applicable Flammable liquids Not applicable Flammable solids Not classified Self-reactive substances and mixtures Not applicable Pyrophoric liquids Not applicable Pyrophoric solids Not classified Self-heating substances and mixtures Not classified Substances and mixtures

3 Which, in contact with water, emit flammable gases Not classified Oxidizing liquids Not applicable Oxidizing solids Not classified Monomeric MDI, Japan Urethane Raw Materials Association, 0333 2 13 Revision Date June 23, 2010 Organic peroxides Not applicable Corrosive metals Not classified HEALTH HAZARDS Acute toxicity (oral) Not classified Acute toxicity (skin) Not classified Acute toxicity (inhalation: gas) Not applicable Acute toxicity (inhalation: vapour) Not applicable Acute toxicity (inhalation: dust, mist) Category 4 Skin corrosion / irritation Category 2 Serious eye damages / eye irritation Category 2B Respiratory sensitization Category 1 Skin sensitization Category 1 Germ cell mutagenicity Not classified Carcinogenicity Not classified Reproductive toxicity Not classified Specific target organ toxicity: single exposure Category 3 (respiratory tract irritation) Specific target organ toxicity.

4 Repeated exposure Not classified Aspiration hazard Not classified ENVIRONMENTAL HAZARDS Aquatic toxicity (acute) Not classified Aquatic toxicity (chronic) Not classified GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS SYMBOL SIGNAL WORD Danger HAZARD STATEMENT Harmful if inhaled Causes skin irritation Causes serious eye irritation May cause allergy or asthma symptoms or breathing difficulties if inhaled May cause respiratory irritation PRECAUTIONARY STATEMENT Prevention Do not handle until all SAFETY precautions have been read and understood.

5 Obtain special instructions before use. Do not eat, drink or smoke when using this product. Monomeric MDI, Japan Urethane Raw Materials Association, 0333 3 13 Revision Date June 23, 2010 Wear respiratory protection/protective gloves / protective clothing / eyes protection / face protection. Use only outdoors or in a well-ventilated area. Do not breathe dust / fume / mist. Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Keep away from any possible contact with water and alkali.

6 Response If inhaled Remove victim to fresh air and keep at rest in a position comfortable for breathing. If swallowed: Rinse mouth with water. Do not induce vomiting. If in eyes Rinse cautiously with water for 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If on skin Wash with plenty of soap and water. If skin irritation occurs, get medical advice/attention. Take off contaminated clothing and wash before reuse. Get medical advice/attention if you feel unwell. In case of fire: Use powder, carbon dioxide, foam for extinction.

7 When a fire is spread, large volumes of spray water should be used. When leaking out, collect as much as possible to the container and so on. After that, spray and neutralize with an ammonia water, alcohol and so on, and then absorb it with sands. If exposed or concerned Get medical attention/advice. Storage Store in a dry place. Keep container tightly closed in the locked place. Dispasal Dispose of contents / container to waste in accordance with local / regional / national / international regulations (to be specified).

8 3. COMPOSITION/INFORMATION ON INGREDIENTS SUBSTANCE/MIXTURE Substance CHEMICAL NAME Diphnylmethane-4,4'-diisocyanate PURITY > 98 METI No (4)-118 * Class Reference No in The Gazetted List (for Existing Chemical Substances) ISHA No Existing (A chemical substance for which public notice has been given by METI No to 1979 June 29th) * Class Reference No in The Gazetted List (Industrial SAFETY and Health Act) CAS No 101-68-8 (Diphenylmethane-4,4 -diisocyanate) 26447-40-5 (Diphenylmethane diisocyanate) HAZARDOUS INGREDIENT(s)

9 Diphenylmethane-4,4 -diisocyanate 4. FIRST-AID MEASURES IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing. Monomeric MDI, Japan Urethane Raw Materials Association, 0333 4 13 Revision Date June 23, 2010 Get medical attention / advice immediately. When breathing stops, give an artificial respiration after securing the loosening respiratory tract in the clothing. Get medical advice/attention immediately when the cough and phlegm, etc. are awful. IF ON SKIN Wash off with soap and water immediately.

10 Remove/Take off immediately all contaminated clothing. If skin irritation or rash occurs, get medical advice/attention. Take off contaminated clothing and wash before reuse. IF IN EYES Even if very small amount contact, rinsing by clean water for at least 15 minutes, and get ophthalmologist's examination. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists, get medical advice/attention. IF SWALLOWED After rinse mouth immediately with water, give about 250 ml of water or milk to thin in the stomach, and do not induce to vomit.