MATERIAL SAFETY DATA SHEET - MSC Industrial Direct

1 Page 1 of 5 DATE OF PREPARATIONSep 29, 2014 MATERIAL SAFETY data SHEET160105 00 SECTION 1 PRODUCT AND COMPANY IDENTIFICATIONPRODUCT NUMBER1601 PRODUCT NAMEKRYLON Interior/Exterior paint , Gloss BlackMANUFACTURER'S NAMETHE SHERWIN-WILLIAMS COMPANYKRYLON Industrial PRODUCTS GROUPC leveland, OH 44115 Telephone Numbers and WebsitesProduct Information(800) Information(216) Emergency(216) 566-2917 Transportation Emergency*(800) 424-9300for Chemical Emergency ONLY (spill, leak, fire, exposure, or *accident)SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS% by WeightCAS NumberIngredientUnitsVapor Pressure1474-98-6 PropaneACGIH TLV1000 PPM760 mmOSHA PEL1000 PPM6106-97-8 ButaneACGIH TLV1000 PPM760 mmOSHA PEL800 PPM1100-41-4 EthylbenzeneACGIH mmOSHA PEL100 PPMOSHA PEL125 PPM STEL81330-20-7 XyleneACGIH mmACGIH TLV150 PPM STELOSHA PEL100 PPMOSHA PEL150 PPM STEL3967-64-1 AcetoneACGIH TLV500 PPM180 mmACGIH TLV750 PPM STELOSHA PEL1000 PPM1578-93-3 Methyl Ethyl KetoneACGIH mmACGIH TLV300 PPM STELOSHA PEL200 PPMOSHA PEL300 PPM STEL6108-65-61-Methoxy-2-Propanol AcetateACGIH TLVNot mmOSHA PELNot BlackACGIH 3 HAZARDS IDENTIFICATIONROUTES OF EXPOSUREINHALATION of vapor or spray 2 of POINTP ropellant < 0 FHMIS CodesHealth2*Flammability3

2 Reactivity0 EYE or SKIN contact with the product, vapor or spray OF :Prolonged or repeated exposure may cause :Irritation of the upper respiratory cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly overexposure to hazardous ingredients in Section 2 may cause adverse chronic effects to the following organs or systems:the liverthe urinary systemthe hematopoietic (blood-forming) systemthe reproductive systemSIGNS AND SYMPTOMS OF OVEREXPOSUREH eadache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray and itching or burning sensation may indicate eye or excessive skin CONDITIONS AGGRAVATED BY EXPOSURENone generally INFORMATIONFor complete discussion of toxicology data refer to Section 4 FIRST AID MEASURESEYES:Flush eyes with large amounts of water for 15 minutes.

3 Get medical :Wash affected area thoroughly with soap and contaminated clothing and launder before :If affected, remove from exposure. Restore breathing. Keep warm and :Do not induce vomiting. Get medical attention 5 FIRE FIGHTING MEASURESEXTINGUISHING MEDIAC arbon Dioxide, Dry Chemical, FoamUNUSUAL FIRE AND EXPLOSION HAZARDSC ontainers may explode when exposed to extreme to hot surfaces requires special emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical FIRE FIGHTING PROCEDURESFull protective equipment including self-contained breathing apparatus should be spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme 6 ACCIDENTAL RELEASE MEASURESSTEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLEDR emove all sources of ignition.

4 Ventilate the with inert 7 HANDLING AND STORAGESTORAGE CATEGORYNot AvailablePRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGEKeep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of NFPA Code. Use approved Bonding and Grounding under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of 8 EXPOSURE CONTROLS/PERSONAL PROTECTIONPRECAUTIONS TO BE TAKEN IN USEUse only with adequate contact with skin and eyes.

5 Avoid breathing vapor and spray hands after 3 of 5 This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction).VENTILATIONL ocal exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards , , PROTECTIONIf personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint , or the GLOVESNone required for normal application of aerosol products where minimal skin contact is expected.

6 For long or repeated contact, wear chemical resistant PROTECTIONWear SAFETY spectacles with unperforated PRECAUTIONSI ntentional misuse by deliberately concentrating and inhaling the contents can be harmful or 9 PHYSICAL AND CHEMICAL PROPERTIESPRODUCT lb/gal754 g/lSPECIFIC POINT<0 - 302 F<-18 - 150 CMELTING POINTNot AvailableVOLATILE VOLUME93%EVAPORATION RATEF aster than etherVAPOR DENSITYH eavier than airSOLUBILITY IN WATERNot ORGANIC COMPOUNDS (VOC Theoretical - As Packaged)Volatile Weight Water and Federally Exempt SolventsSECTION 10 STABILITY AND REACTIVITYSTABILITY StableCONDITIONS TO AVOIDNone DECOMPOSITION PRODUCTSBy fire: Carbon Dioxide, Carbon MonoxideHAZARDOUS POLYMERIZATIONWill not occurSECTION 11 TOXICOLOGICAL INFORMATIONCHRONIC HEALTH HAZARDSM ethyl Ethyl Ketone may increase the nervous system effects of other have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system is classified by IARC as possibly carcinogenic to humans (2B) based on inadequate evidence in humans and sufficient evidence in laboratory animals.

7 Lifetime inhalation exposure of rats and mice to high ethylbenzene concentrations resulted in increases in certain types of cancer, including kidney tumors in rats and lung and liver tumors in mice. These effects were not observed in animals exposed to lower concentrations. There is no evidence that ethylbenzene causes cancer in black is classified by IARC as possibly carcinogenic to humans (group 2B) based on experimental animal data , however, there is insufficient evidence in humans for its 4 of 5 TOXICOLOGY DATACAS Name74-98-6 PropaneLC50 RAT4 HRNot AvailableLD50 RATNot Available106-97-8 ButaneLC50 RAT4 HRNot AvailableLD50 RATNot Available100-41-4 EthylbenzeneLC50 RAT4 HRNot AvailableLD50 RAT3500 mg/kg1330-20-7 XyleneLC50 RAT4HR5000 ppmLD50 RAT4300 mg/kg67-64-1 AcetoneLC50 RAT4 HRNot AvailableLD50 RAT5800 mg/kg78-93-3 Methyl Ethyl KetoneLC50 RAT4 HRNot AvailableLD50 RAT2740 mg/kg108-65-61-Methoxy-2-Propanol AcetateLC50 RAT4 HRNot AvailableLD50 RAT8500 mg/kg1333-86-4 Carbon BlackLC50 RAT4 HRNot AvailableLD50 RATNot AvailableSECTION 12 ECOLOGICAL INFORMATIONECOTOXICOLOGICAL INFORMATIONNo data 13 DISPOSAL CONSIDERATIONSWASTE DISPOSAL METHODW aste from this product may be

8 Hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR must be tested for ignitability to determine the applicable EPA hazardous waste not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding 14 TRANSPORT INFORMATIONM ulti-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for Ground (DOT)May be classed as LTD.

9 QTY. OR ORM-DUN1950, AEROSOLS, , LIMITED QUANTITY, (ERG#126)Canada (TDG)May be classed as LTD. QTY. OR ORM-DUN1950, AEROSOLS, CLASS , LIMITED QUANTITY, (ERG#126)IMOMay be shipped as Limited QuantityUN1950, AEROSOLS, CLASS , LIMITED QUANTITY, EmS F-D, S-UIATA/ICAOUN1950, AEROSOLS, FLAMMABLE, , LIMITED QUANTITYSECTION 15 REGULATORY INFORMATIONSARA 313 SUPPLIER NOTIFICATION(40 CFR )CAS by WT% Element100-41-4 Ethylbenzene11330-20-7 Xylene8 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive CERTIFICATIONAll chemicals in this product are listed, or are exempt from listing, on the TSCA 5 of 5 SECTION 16 OTHER INFORMATIONThis product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the above information pertains to this product as currently formulated, and is based on the information available at this time.

10 Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information.