Material Safety Data Sheet - Northern States …

1 paraloid B-72 of 61/18/2008 11:55 AMMaterial Safety data Sheet1. PRODUCT AND COMPANY IDENTIFICATION paraloid (TM) B-72 100% Resin Revision date:09/26/2003 SupplierRohm and Haas Company100 Independence Mall WestPhiladelphia, PA 19106-2399 United States of AmericaFor non-emergency information contact: 215-592-3000 Emergency telephone numberSpill Emergency215-592-3000 Health Emergency215-592-3000 Chemtrec800-424-93002. COMPOSITION/INFORMATION ON Acrylic polymer(s)Not - Individual residual monomersNot Required<= Toluene108-88-3<= HAZARDS IDENTIFICATIONE mergency OverviewAppearanceFormGranular solid Colourclear OdourAcrylic odor Hazard SummaryCAUTION!INHALATION OF DUST CAN CAUSE THE FOLLOWING:IRRITATION OF NOSE, THROAT, AND LUNGSHEADACHENAUSEAMAY CAUSE EYE/SKIN Health EffectsPrimary Routes of Entry:InhalationEye contactSkin contactEyes:Monomer vapors from heated product can cause the following:slight irritationSkin:Prolonged or repeated skin contact can cause the following:slight irritationInhalation:Inhalation of dust can cause the following:irritation of nose, throat, and lungsInhalation of monomer vapor from heated product can cause the following:May cause nose, throat, and lung B-72 of 61/18/2008 11:55 AMnauseaTolueneACGIHNot classifiable as a human CA65 CRTD evelopmental not possible from current suggests lack of FIRST AID MEASURESI nhalation:Move to fresh contact:Wash with water and soap as a precaution.

2 If skin irritation persists, call a contact:Flush eyes with water as a precaution. If eye irritation persists, consult a :Drink 1 or 2 glasses of water. Consult a physician if necessary. Never give anything by mouth to anunconscious FIRE-FIGHTING MEASURESF lash pointnot applicableIgnition C ( F) estimatedLower explosion limitnot applicableUpper explosion limitnot applicableSuitable extinguishing media:Use the following extinguishing media when fighting fires involving this Material :carbon dioxide (CO2)dry chemicalwater spraySpecific hazards during fire fighting: Material as sold is combustible; burns vigorously with intense protective equipment for fire-fighters:Wear self-contained breathing apparatus and protective information:Water mist may be used to cool closed breathing ACCIDENTAL RELEASE MEASURESP ersonal precautionsAppropriate protective equipment must be worn when handling a spill of this Material .

3 See SECTION 8, ExposureControls/Personal Protection, for exposed to Material during clean-up operations, see SECTION 4, First Aid Measures, for actions to precautionsCAUTION: Keep spills and cleaning runoff out of municipal sewers and open bodies of for cleaning upFloor may be slippery; use care to avoid all ignition the spilled Material to suitable containers for recovery or HANDLING AND STORAGEH andlingStore in a cool, dry, well ventilated place. Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Keep container tightly closed. Do not breathe vapours/dust. Static charges can accumulate: use bonding and groundingbetween transfer equipment and receiving containers and for anyother operations capable of generating static B-72 of 61/18/2008 11:55 AMStorageStorage conditions: Material can burn; limit indoor storage to approved areas equipped with automatic sprinklers.

4 Ground all metal containers during storage and - C( - F)Further information:Monomer vapors can be evolved when Material is heated during processing operations. See SECTION 8, for types ofventilation EXPOSURE CONTROLS / PERSONAL PROTECTIONE xposure limit(s)Exposure limits are listed below, if they exist. ComponentRegulationType of listingValue TolueneRohm and HaasTWA 50 ppmRohm and HaasSTEL 75 ppmRohm and HaasAbsorbed via skin ACGIHTWA 50 ppmACGIHSKIN_DES OSHA/Z2 TWA 200 ppmOSHA/Z2 Ceiling 300 ppmOSHA/Z2 MAX. CONC 500 ppmZ1 ATWA375 mg/m3 100 ppmZ1 ASTEL560 mg/m3 150 ppmEye protection:Use Safety glasses with side shields (ANSI approved equivalent). Eye protection worn must becompatible with respiratory protection system protection:Cotton or canvas protection:A respiratory protection program meeting OSHA and ANSI requirements or equivalent must be followed whenever workplace conditions warrant a respirator's use.

5 None required under normaloperating conditions. When dusty conditions are encountered, wear a properly fitted NIOSH approved (or equivalent)half-mask, air-purifying respirator. Air-purifying respirators should be equipped with NIOSH approved (or equivalent)organic vapor cartridges and N95 filters. If oil mist is present, use R95 or P95 measures:Facilities storing or utilizing this Material should be equipped with an eyewash measures:Use local exhaust ventilation with a minimum capture velocity of 150 ft/min. ( m/sec.) at the point of dust or mist evolution. Refer to the current edition of "Industrial Ventilation: A Manual of RecommendedPractice" published by the American Conference of Governmental Industrial Hygienists for information on the design, installation, use, and maintenance of exhaust PHYSICAL AND CHEMICAL PROPERTIESA ppearance FormGranular solid Colourclear OdourAcrylic odor pH not applicableBoiling point/rangenot applicableMelting point/rangeno data availableFlash pointnot applicableIgnition temperature393 C ( F) estimatedLower explosion limitnot applicableUpper explosion limitnot applicableVapour pressure not applicableRelative vapour densitynot applicableWater solubilitypractically g/cm3 Bulk densityPARALOID B-72 of 61/18/2008 11:55 AMViscosity, dynamicnot applicableEvaporation ratenot applicablePercent volatility1 % maximumNOTE.

6 The physical data presented above are typical values and should not be construed as a STABILITY AND REACTIVITYH azardous reactionsNone Material is considered , avoid temperatures above 260C/500F. Thermal decompositionis dependent on time and to avoidThere are no known materials which are incompatible with this product. Hazardous decomposition productsThermal decomposition may yield acrylic monomers., polymerizationProduct will not undergo polymerization. 11. TOXICOLOGICAL INFORMATIONA cute oral toxicityLD50rat > 5,000 mg/kgToxicity data for a compositionally similar dermal toxicityLD50rabbit > 3,000 mg/kgToxicity data for a compositionally similar irritationrabbitslight irritationToxicity data for a compositionally similar irritationrabbitslight irritationToxicity data for a compositionally similar informationNo data are available for this Material . The information shown is based on profiles of compositionally similar :TolueneAcute inhalation toxicityLC50rat 4 mg/l12.

7 ECOLOGICAL INFORMATIONT here is no data available for this effectsToxicity to fish LC50 Rainbow trout96 h24 ppmToxicity to fish LC50 Fathead minnow (Pimephales promelas)96 h26 ppmToxicity to fish LC50 Bluegill sunfish96 h13 ppmToxicity to algae EC50 Algae96 h>433 ppmToxicity to aquatic invertebrates EC50 Daphnia magna48 ppm13. DISPOSAL CONSIDERATIONSE nvironmental precautions:CAUTION: Keep spills and cleaning runoff out of municipal sewers and open bodies of Classification:When a decision is made to discard this Material as supplied, it does not meet RCRA's characteristic definition of ignitability, corrosivity, or reactivity, and is not listed in 40 CFR The toxicity characteristic (TC), however, has not been evaluated by the Toxicity Characteristic Leaching Procedure (TCLP).For disposal, incinerate this Material at a facility that complies with local, state, and federal B-72 of 61/18/2008 11:55 AM14.

8 TRANSPORT INFORMATIONDOT Not regulated for transportIMO/IMDG Not regulated (Not dangerous for transport)15. REGULATORY INFORMATIONW orkplace ClassificationThis product is considered non-hazardous under the OSHA Hazard Communication Standard ( ).This product is a'controlled product' under the Canadian Workplace Hazardous Materials Information System (WHMIS). SARA TITLE III:Section 311/312 Categorizations (40 CFR370):This product is not a hazardous chemical under 29 CFR , and therefore is not covered by Title III of TITLE III:Section 313 Information (40 CFR372)This product does not contain a chemical which is listed in Section 313 at or above de minimis ( )Releases of this Material to air, land, or water are not reportable to the National Response Center under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) or to state and local emergency planning committees under the Superfund Amendments and Reauthorization Act (SARA) Title III Section Toxic Substances Control Act (TSCA) All components of this product are in compliance with theinventory listing requirements of the Toxic Substances Control Act (TSCA) Chemical Substance Material listed as "Not Hazardous" in the CAS REG NO.

9 Column of SECTION 2, Composition/Information On Ingredients, of this MSDS is a trade secret under the provisions of the Pennsylvania Worker and Community Right-to-Know (Proposition 65)This product contains a component or components known to the state of California to cause birth defects or other reproductive harm:Components:Toluene108-88-3 California (Proposition 65)This product contains trace levels of a component or components known to the state of California to cause cancer and birthdefects or other reproductive harm:Components:Benzene71-43-216. OTHER INFORMATIONH azard RatingHealthFireReactivity HMIS110 LegendACGIHA merican Conference of Governmental Industrial HygienistsBAcButyl acetateOSHAO ccupational Safety and Health AdministrationPELP ermissible Exposure LimitSTELS hort Term Exposure Limit (STEL):TLVT hreshold Limit ValueTWATime Weighted Average (TWA):|Bar denotes a revision from prior B-72 of 61/18/2008 11:55 AMThe information provided in this Safety data Sheet is correct to the best of our knowledge, information and belief at the date of its publication.

10 The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific Material designated and may not be valid for such Material used in combination with any other materials or in any process, unless specified in the Date:02/29/2004 Layout 208776