Material Safety Data Sheet Revision Date: Kodak

1 Revision Date: 08121/2013 Z17000000011 Nersion: Print Date: 12/05/2013 Page: 118 Material Safety data Sheet Kodak 11. Identification of the substance/mixture and of the company/undertaking Product name: Kodak Developer System Cleaner, Part A , Part A Product code: 10080942 Part A Supplier: EASTMAN Kodak COMPANY, 343 Stale Street, Rochester, New York 14650 For Emergency Health, Safety & Environmentallnformalion, call (585) 722-5151 (USA) For further information about th is product, call (800) 242 2424. Synonyms: p e e 5747 Product Use: photographic processing chem ical (developer/activator), For industrial use only, I 2.

2 Hazards Identification CONTAINS: Potassium permanganate (7722-64-7 ) WARNING! CONTAINS AN OXIDIZING Material . CAUSES EYE IRRITATION MAY BE HARMFUL IF SWALLOWED HMIS III Hazard Ratings: Health -2, Flammability -0, Physical Hazard -0 NFPA Hazard Ratings: Health -2, Flammability -0, Instability -0 NOTE: HMIS III and NFPA 704 (2007) hazard indexes involve data review and interpretation that may vary among companies. They are intended only for rapid, general identificatio n of the magnitude of the potential hazards. To adequately address safe handling, All information in th is MSDS m ust be considered.

3 1 3. Composition/Information on ingredients Weight percent 1 -5 Components - (CAS-No.) Potassium permanganate (7722-64-7 ) I 4. First aid measures Revision Date: 08121/2013 Z17000000011 Nersion: Print Date: 12/0512013 Page: 218 Material Safety data Sheet Inhalation: If inhaled, remove to fresh air. Get medical attention if symptoms occur. Eyes: In case of contact. immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact tens, if worn. Get medical attention. Skin: Wash off with soap and water. Get medical attention if symptoms occur.

4 Ingestion: If swallowed, DO NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician or poison control centre immediately. 1 5. Fire-fighting measures Extinguishing Media: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Special Fire-Fighting Procedures: None (noncombustib le) Hazardous Combustion Products: None (noncombustible) Unusual Fire and Explosion Hazards: Mixture contains an ox idizing Material and may increase the burning rate of combustible materials. Dried product residue can act as an oxidizer.

5 I 6. Accidental release measures Absorb spill with vermiculite or other inert Material , then place in a container for chemical waste. Cl ean surface thoroughly to remove residual contamination. 7. Handling and storage Personal precautions: Avoid breathing mist or vapour at concentrations greater than the exposure limits. Avoid contact with eyes, skin, and clothing. Use only with adequate ventilation. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Prevention of Fire and Explosion: Keep away from combustible Material . Remove and wash contaminated clothing promptly.

6 Storage: Keep container tightly closed to prevent the loss of water. Keep away from incompatible substances (see Incompatibility section.) I 8. Exposure controlsJpersonal protection Occupational exposure controls Chemical Name Regulatory Value Type Value Revision Date: 08/2112013 Z17000000Q11 Nersion: Print Date: 12/0512013 Page: 3/8 Potassium permanganate Potassium permanganate List ACGIH OSHA Material Safety data Sheet time weighted average time weighted average Ceiling Limit Value mglm3 Expressed as Mn mg/m3 Expressed as Mn 5 mglm3 Expressed as Mn Ventilation: Good general ventilation should be used.

7 Ventilation should be sufficient so that applicable occupational exposure li mits are not exceeded. Ventilation rales should be matched to conditions. Supplementary local exhaust ventilation, closed systems, or r espiratory protectio n may be needed in special circumstances. Respiratory protection: None should be needed. If engineering controls do nol maintain airborne concentrations below recommended exposure limits, an approved respirator must be worn. Respirator type: acid gas If respirators are used, a program should be instituted to assure compliance with applicable federal, state, commonwealth, provincial, or local laws and regulations.

8 Eye protection: Wear Safety glasses with side shields (or goggles). Hand protection: For operations where prolonged or r epeated skin contact may occur, impervious gloves should be worn. I 9. Physical and chemical properties Physical form: liquid Colour: purple Odour: odourless Specific gravity: Vapour pressure (at C ( OF : 24 mbar ( mm Hg) Vapour density: Boiling point/boiling range: > 100 C (> OF) Water solubility: complete pH: 7 Material Safety data Sheet Revision Date: 08121/2013 Z17000000011 Nersion: Print Date: 12/0512013 Page: 418 Fl ash point: does not flash 110.))

9 Stability and reactivity Stability: Stable under normal conditions. Incompatibility: Combustible Material , s trong reducing agents . Material can react violently wi th combustible materials or strong reducing agents. Hazardous decomposition products: None under normal conditions of use. Hazardous Polym erization: Hazardous polymerisation does not occur. 11. Toxicological information Effects of Exposure Inhalation : Expected to be a l ow hazard for recommended handling. Eyes: Causes eye irritation. Skin: Expected to be a low haza rd for recommended handling.

10 May stain skin brown. Ingestion: May be harmful if swallowed. data for Potassium permangan at e (CAS 7722-64-7): Acute Toxicity data : Oral LD50 (rat): 400 - 1,600 mglkg Skin irritation: irritating Eye irritation: Corrosive 112. Ecological infonnation The following properties are ESTIMATED from the components of the preparations. Po t ential Toxicit y: Toxicity to fish (LC50): >100mgll ToxiCity to daphnia (EC50): 10 -100 mgll Toxicity to algae (IC50): 10 -100 mg/l Material Safety data Sheet Revi sion Date: 08121/2013 Z17000000011 Ners ion: Print Date: 12/05/20 13 Page: 518 Toxicity to other organisms (ECSO): Persistence and degradabilrty: Chemical Oxygen Demand (COD): Biochemical Oxygen Demand (BOO): [ 13.]