MATERIAL SAFETY DATA SHEET - Smart Lab

1 No: F/QCL/008 INDONESIAMSDS HYDROCHLORIC ACID 37%Page 1 MATERIAL SAFETY DATA SHEETHYDROCHLORIC ACID 37%Revision : 01 Date: Number : 097 Section 1 - Chemical Product and Company Product Name:HYDROCHLORIC ACID 37%Synonyms:Hydrogen Chloride Solution, Muriatic AcidCAS No.:7647-01-0HS Code:2806 10 00 Molecular g/molChemical Formula:HClProduct Code:A-1050 IndonesiaAddress:Ruko Boulevard Taman Tekno Blok E ,BSD Sektor XI Serpong,Tangerang - information:Telp: +62-21- 7588 0205(Hunting) , fax:+62-21-7588 Application:General Chemical reagentEmergency Telephone:+62-21-7588 0205(Hunting)Section 2 - Hazards Classification of the substance or mixtureClassification according to Regulation (EC) No 1272/2008 Corrosive to metals (Category 1), H290 Skin corrosion (Category 1B), H314 Serious eye damage (Category 1), H318 Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335 For the full text of the H-Statements mentioned in this Section, see Section Label elementsLabelling according Regulation (EC) No 1272/2008 PictogramSignal wordDangerHazard statement(s)H290 May be corrosive to severe skin burns and eye cause respiratory statement(s)P260Do not breathe dust/ fume/ gas/ mist/ vapours/ face.

2 F/QCL/008 INDONESIAMSDS HYDROCHLORIC ACID 37%Page 2 MATERIAL SAFETY DATA SHEETHYDROCHLORIC ACID 37%Revision : 01 Date: Number : 097P303 + P361 + P353IF ON SKIN (or hair): Take off immediately allcontaminated clothing. Rinse skin with + P340 + P310IF INHALED: Remove person to fresh air and keepcomfortable for breathing. Immediately call a + P351 + P338 + P310IF IN EYES: Rinse cautiously with water for severalminutes. Remove contact lenses, if present and easy to Hazard information (EU) Other hazardsThis substance/mixture contains no components considered to be either persistent, bioaccumulative andtoxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of or 3 - Composition, Information on SubstancesSynonyms: Hydrogen Cholride solution, Muariatic AcidFormula: HClMolecular weight: g/molCAS-No.: 7647-01-0EC-No.: 231-595-71 Hazardous ingredients according to Regulation (EC) No 1272/2008 ComponentClassificationConcentrationHydr ochloric acidCAS-No.

3 Number 7647-01-0EC-No. 231-595-7 Index-No. 017-002-01-XMet. Corr. 1; Skin Corr. 1B; STOT SE3; H290, H314, H335 Concentrationlimits: >= 25 %: Skin Corr. 1B, H314;10 - < 25 %: Skin Irrit. 2, H315; 10 - <25 %: Eye Irrit. 2, H319; >= 10 %:STOT SE 3, H335; >= %: 1, H290; 25 - 50 % For the full text of the H-Statements mentioned in this Section, see Section 4 - First Aid Description of first aid measuresGeneral adviceConsult a physician. Show this SAFETY data SHEET to the doctor in inhaledIf breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a case of skin contactTake off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Take victimimmediately to hospital. Consult a : F/QCL/008 INDONESIAMSDS HYDROCHLORIC ACID 37%Page 3 MATERIAL SAFETY DATA SHEETHYDROCHLORIC ACID 37%Revision : 01 Date: Number : 097In case of eye contactRinse thoroughly with plenty of water for at least 15 minutes and consult a swallowedDo NOT induce vomiting.

4 Never give anything by mouth to an unconscious person. Rinse mouth with a Most important symptoms and effects, both acute and delayedThe most important known symptoms and effects are described in the labelling (see section ) and/or insection Indication of any immediate medical attention and special treatment neededNo data availableSection 5 - Firefighting Extinguishing mediaSuitable extinguishing mediaUse water spray, alcohol-resistant foam, dry chemical or carbon Special hazards arising from the substance or mixtureHydrogen chloride Advice for firefightersWear self-contained breathing apparatus for firefighting if Further informationUse water spray to cool unopened 6 - Accidental Release Personal precautions, protective equipment and emergency proceduresWear respiratory protection. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuatepersonnel to safe areas. For personal protection see section Environmental precautionsDo not let product enter drains.

5 \ Methods and materials for containment and cleaning upSoak up with inert absorbent MATERIAL and dispose of as hazardous waste. Keep in suitable, closed containersfor up with inert absorbent MATERIAL and dispose of as hazardous waste. Keep in suitable,closed containers for Reference to other sectionsFor disposal see section 7 - Handling and Precautions for safe handlingAvoid contact with skin and eyes. Avoid inhalation of vapour or mist. For precautions see section : F/QCL/008 INDONESIAMSDS HYDROCHLORIC ACID 37%Page 4 MATERIAL SAFETY DATA SHEETHYDROCHLORIC ACID 37%Revision : 01 Date: Number : Conditions for safe storage, including any incompatibilitiesStore in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which areopened must be carefully resealed and kept upright to prevent leakage. Storage class (TRGS 510): Non-combustible, corrosive hazardous Specific end use(s)Apart from the uses mentioned in section no other specific uses are stipulatedSection 8 - Exposure Controls, Personal Control Exposure controlsAppropriat engineering controlsHandle in accordance with good industrial hygiene and SAFETY practice.

6 Wash hands before breaks and atthe end of protective equipmentEye/face protectionTightly fitting SAFETY goggles. Faceshield (8-inch minimum). Use equipment for eye protectiontested and approved under appropriate government standards such as NIOSH (US) or EN166(EU).Skin protectionHandle with gloves. Gloves must be inspected prior to use. Use proper glove removaltechnique (without touching glove's outer surface) to avoid skin contact with this of contaminated gloves after use in accordance with applicable laws and goodlaboratory practices. Wash and dry selected protective gloves have to satisfy the specifications of EU Directive 89/686/EECand the standard EN 374 derived from contactMaterial: Nitrile rubberMinimum layer thickness: mmBreak through time: 480 minMaterial tested:Dermatril (KCL 740, Size M)Splash contactMaterial: Nitrile rubberMinimum layer thickness: mmBreak through time: 480 minMaterial tested:Dermatril (KCL 740, Size M)Body ProtectionComplete suit protecting against chemicals, The type of protective equipment must beselected according to the concentration and amount of the dangerous substance at the protectionWhere risk assessment shows air-purifying respirators are appropriate use (US) or typeABEK (EN 14387) respirator cartridges as a backup to enginee protection, use a full-facesupplied air respirator.

7 Use respirators and components tested and approved underappropriate government standards such as NIOSH (US) or CEN (EU).No: F/QCL/008 INDONESIAMSDS HYDROCHLORIC ACID 37%Page 5 MATERIAL SAFETY DATA SHEETHYDROCHLORIC ACID 37%Revision : 01 Date: Number : 097 Control of environmental exposurePrevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge intothe environment must be 9 - Physical and Chemical Information on basic physical and chemical propertiesAppearanceForm: liquidColour: light yellowOdourpungentOdour ThresholdNo data availablepHNo data availableMelting point/freezingpoint-30 CInitial boiling point and boiling range> 100 CFlash pointNot applicableEvaporation rateNo data availableFlammability (solid, gas)No data availableUpper/lower flammability orUpper explosion limit: 57 %(V)Lower explosion limit: 18 %(V)explosive limitsNo data availableVapour mmHg at mmHg at CVapour densityNo data availableRelative g/mL at 25 CWater solubilitysolublePartition coefficient.

8 Noctanol/waterNo data availableAuto-ignition temperatureNo data availableDecomposition temperatureNo data availableViscosityNo data availableExplosive propertiesNo data availableOxidizing propertiesNo data Other SAFETY informationNo data availableSection 10 - Stability and ReactivityNo data Chemical stabilityStable under recommended storage Possibility of hazardous reactionsNo data Conditions to avoidNo data Incompatible materialsBases, Amines, Alkali metals, Metals, permanganates, potassium permanganate, Fluorine, metalacetylides, hexalithium disilicideNo: F/QCL/008 INDONESIAMSDS HYDROCHLORIC ACID 37%Page 6 MATERIAL SAFETY DATA SHEETHYDROCHLORIC ACID 37%Revision : 01 Date: Number : Hazardous decomposition productsHazardous decomposition products formed under fire conditions. - Hydrogen chloride gasOther decomposition products - No data availableIn the event of fire: see section 5 Section 11 - Toxicological Information on toxicological effectsAcute toxicityHydrochloric acid Inhalation: Inhalation may provoke the following symptoms: Respiratory irritationCough Difficulty in breathing Pneumonia(Hydrochloric acid)Skin corrosion/irritationSkin - Rabbit(Hydrochloric acid)Result: Causes eye damage/eye irritationEyes - Rabbit(Hydrochloric acid)Result: Corrosive to eyesRespiratory or skin sensitisationDid not cause sensitisation on laboratory animals.

9 (Hydrochloric acid)Germ cell mutagenicityNo data available(Hydrochloric acid)CarcinogenicityThis product is or contains a component that is not classifiable as to its classification.(Hydrochloric acid) (Hydrochloric acid)IARC:3 - Group 3: Not classifiable as to its carcinogenicity to humans (Hydrochloric acid)Reproductive toxicityNo data available(Hydrochloric acid)Specific target organ toxicity - single exposureThe substance or mixture is classified as specific target organ toxicant, single exposure, category 3 withrespiratory tract irritation.(Hydrochloric acid)Specific target organ toxicity - repeated exposureThe substance or mixture is not classified as specific target organ toxicant, repeated hazardNo aspiration toxicity classification(Hydrochloric acid)Additional InformationRTECS: MW4025000 Inhalation of vapors may cause:, burning sensation, Cough, wheezing, Shortness of breath, spasm,inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi, pneumonitis,pulmonary edema(Hydrochloric acid)No: F/QCL/008 INDONESIAMSDS HYDROCHLORIC ACID 37%Page 7 MATERIAL SAFETY DATA SHEETHYDROCHLORIC ACID 37%Revision : 01 Date: Number.

10 097 Section 12 - Ecological ToxicityToxicity to fishLC50 - Lepomis macrochirus (Bluegill) - - 96 h(Hydrochloric acid)Toxicity to daphnia and other aquatic invertebratesEC50 - Daphnia magna (Water flea) - mg/l -48 h(Hydrochloric acid) Persistence and degradabilityNo data Bioaccumulative potentialNo data Mobility in soilNo data Results of PBT and vPvB assessmentThis substance/mixture contains no components considered to be either persistent, bioaccumulative andtoxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of or Other adverse effectsMay be harmful to aquatic organisms due to the shift of the pH. Do not empty into 13 - Disposal Waste treatment methodsProductOffer surplus and non-recyclable solutions to a licensed disposal packagingDispose of as unused productSection 14 - Transport UN numberADR/RID: 1789 IMDG: 1789 IATA: UN proper shipping nameADR/RID: HYDROCHLORIC ACIDIMDG:HYDROCHLORIC ACIDIATA:Hydrochloric Transport hazard class(es)ADR/RID: 8 IMDG: 8 IATA: Packaging groupADR/RID: IIIMDG: IIIATA: Environmental hazardsADR/RID: noIMDG Marine pollutant: noIATA: Special precautions for userNo data availableNo: F/QCL/008 INDONESIAMSDS HYDROCHLORIC ACID 37%Page 8 MATERIAL SAFETY DATA SHEETHYDROCHLORIC ACID 37%Revision : 01 Date: Number : 097 Section 15 - Regulatory SAFETY , health and environmental regulations/legislation specific for the substance or mixtureThis SAFETY datasheet complies with the requirements of Regulation (EC) No.