MATERIAL SAFETY DATA SHEET - Vance Brothers

1 HMIS HAZARD RATING1 HEALTH0 FIRE0 REACTIVITYMATERIAL SAFETY data SHEET5201 Brighton, Box 300107 Kansas City, MO 64130 Phone: 816-923-4325/ 800-821-8549 FAX: 816-923-6472 Emergency Phone Number (CHEMTREC): 800-424-9300I. PRODUCT INFORMATIONTRADE NAMESS-1, SS-1H ASPHALT NUMBERM ixtureSYNONYMSTack Oil, Fog Seal, Slurry OilPRODUCT CODE NUMBER298-307II. PHYSICAL DATABOILING POINT @ 760 MM Hg212 F% VOLATILES BY VOLUME30-35%SOLUBILITY IN H20 BY WEIGHT %Highly @ 60 FMELTING POINTNot ApplicableEVAPORATION RATE (BUTYL ACETATE = 1)SlowerVAPOR DENSITY (AIR = 1)> PRESSURENot DeterminedAPPEARANCE AND ODORB rown to Black MaterialIII. HAZARDOUS NUMBERMATERIAL OR COMPONENT%HAZARD DATA8052-42-4[1] Asphalt60-67 TLV/TWA-5mg/m3for asphalt fumesTLV/STEL-10 mg/m3for asphalt fumes7732-18-5[2] Water33-40 Not applicable[3]ProprietaryEmulsifier0-4 Not applicableIV.

2 HEALTH HAZARD INFORMATIONEXPOSURELIMITSTLV/TWA5 mg/m3for oilmistTLV/STEL5 mg/m3for oil mistTLV/PELNot EstablishedODOR THRESHOLD LIMITNot ApplicableROUTES OF EXPOSURE AND EFFECTSAS REQUIRED BY which are released during the curing process are not known to contain hazardousmaterials. However, effects from raw materials include irritation to the eye, nose, andrespiratory tracts of test animals. Health effects are not be expected if proper personalsafety and hygiene is viscosity oils, asphalt, have been shown to be less toxic when ingested than lowerviscosity, higher volatility oils. Product contains alkaline MATERIAL ( ) and could causeburns in the mouth, esophagus, and ABSORPTIONSkin absorption could occur through normal skin contact and/or through wounds exposedto asphalt products.

3 Product contains less than alkaline MATERIAL . Effects couldinclude irritation and possibletissue damage or dermatitis. Health effects are not beexpected if proper personal SAFETY and hygiene is CONTACTP roduct contains less than alkaline MATERIAL . Direct contact may cause irritationand/or itching. Pre-existing skin disorders may be aggravated by exposure to this effects could include tissue burns, irritation and CONTACTD ocumentation indicates that contact lenses should not be worn when exposed to thisproduct. This product contains less than alkaline MATERIAL and can causeinflammation, irritation, and possible corneal OVEREXPOSURESkin effects may include irritation and itching. Product contains less that alkalinematerial and may cause tissue burns or dermatitis.

4 Any pre-existing skin conditions maybe aggravated by exposure to this OVEREXPOSUREC hronic health effects are not expected if proper personal SAFETY and hygiene is skin disorders may be aggravated by repeatedor prolonged exposure to EMERGENCY AND FIRST AID PROCEDURESINHALATIONV apors which are released during the curing process are not known to contain hazardousmaterials. However, if breathing is difficult, move person to fresh air and seek promptmedical NOT induce vomiting. In general, emesis induction is unnecessary for high viscosity,low volatility oils such as asphalt and grease. Avoid all digestible oils, fats, and alcoholwhich may increase intestinal absorption. Seek medical CONTACTF lush area with water to affected area with waterless hand cleaner, followedby water and a mild detergent.

5 DO NOT use solvents! For relief from irritation, apply handlotion. If irritation persists, seek medical CONTACTF lush eyes with water for 15 minutes while holding eyelids open. If subject is wearingcontact lenses, immediately seek an ophthalmologist for , SS-1H ASPHALT EMULSION MSDS, Page 2 of 4VI. SPECIAL PROTECTION INFORMATIONVENTILATIONCare must be taken to assure that the TLV/TWA of 5mg/m3for oil mist is not exceeded. Normal exterior applicationshould not require the need for mechanical must be made downwind from PROTECTIVEEQUIPMENTRESPIRATORYPROTECTION If needed, use an approved OSHA/NIOSH particulate andorganic vapor canister respirator, or a positive atmospheresupplied air respirator as described in 29 CFR VAPORRESPIRATOREYEPROTECTIONG oggles and full-face shield are recommended when handlingthis SHIELDSKIN PROTECTIONF lannel-lined Neoprene or Nitrile gloves are RESISTANTGLOVESOTHER PPER ubber or leather footwear is recommended.

6 All clothingsaturated with this product should be FIRE AND EXPLOSION DATAFLASH POINTNot ApplicableAUTOIGNITION TEMPERATURENot ApplicableLOWER FLAMMABLE LIMITU nknownEXTINGUISHING MEDIAThis product contains water and will not burn until all moisture has been fire should occur, extinguish with foam, carbon dioxide or dry chemical FIRE FIGHTING PROCEDURESFire fighters should wear full protective equipment and self-contained breathing FIRE AND EXPLOSION HAZARDSW ater sprayed on burning product may cause frothing, steam, and REACTIVITY DATACONDITIONS CONTRIBUTING TO INSTABILITYS ince this is a water-based emulsion, settling will occur. The settling rate is dependent onthe dilution and storage temperature. NOTE: Care should be taken to prevent this materialfrom MATERIAL is incompatible with acids.

7 DO NOT heat above 212 F. All additives shouldbe evaluated before use in the DECOMPOSITION PRODUCTSI rritating or toxic vapors may be released when this MATERIAL is CONTRIBUTING TO HAZARDOUS POLYMERIZATIONNone , SS-1H ASPHALT EMULSION MSDS, Page 3 of 4IX. SPILL AND LEAK PROCEDURESSPILL CONTROL PROCEDUREIf possible, stop source of leak. Dike and contain to eliminate environmental small spills, squeegee into thin layer and cover with dirt or aggregate. If MATERIAL entersa waterway, notify police, local EPA and the National Response Center (1-800-424-8802)NEUTRALIZING CHEMICALSDO NOT use water. This MATERIAL is highly miscible and water will increase the volume ofthe spill. If appropriate, pump MATERIAL into holding vessel and bind with sand or lime DISPOSALIf disposal is necessary, contact your state environmental agency for guidance withdisposal methods and waste receiving locations in your SPECIAL PRECAUTIONSENVIRONMENTAL1.

8 This product is considered an oil under EPA-CWA Section 311. Spills into watersources must be reported to If this product becomes a wastematerial, refer to 40 CFR (RCRA) forlatest waste disposal regulations and waste stream This product is listed in the EPA/TSCA inventory (40 CFR 700 to end).LABELING1. "KEEP FROM FREEZING" labels are This MATERIAL is not regulated by the Department of REFERENCES1. BITUMEN SAFETY CODE (ISBN-085501-319-2)7. HYGIENE AND SANITATION, VOLUME 332. CAUSTIC SODA HANDBOOK, VULCAN CHEMICAL8. NFPA 325M, 7043. CLINICAL TOXICOLOGY OF COMMERCIAL PRODUCTS, 5TH EDITION9. POISONING, TOXICOLOGY, SYMPTOMS, TREATEMENTS4. DOCUMENATION OF THRESHOLD LIMIT VALUES, 4TH EDITION10. 29 CFR, 40 AS NOTED WITHIN5. ENCYCLOPEDIA OF SURFACTANTS,VOLUME III11. REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES6.

9 EPA/CWA SECTION 311 NOTE: This MATERIAL SAFETY data SHEET is intended as a source of information for persons involvedin any and all phases of handling this MATERIAL , from production to final application,as required by 29 CFR The health data provided is based on the nature of the raw constituents. This MATERIAL is a mixture and the health effects as such have not ENVIRONMENTAL INFORMATION1. THIS PRODUCT CONTAINS THE FOLLOWING EXTREMELY HAZARDOUS SUBSTANCE(S)4. THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS(SECTION 302 AND 304):COMPONENTTPQ(LBS)RQ(BLS)(SECTION 313):COMPONENTCAS#WEIGHT %N/AN/AN/AN/AN/AN/A2. THIS PRODUCT CONTAINS THE FOLLOWINGCERCLA HAZARDOUS SUBSTANCE(S)(SECTION302 AND 304):COMPONENTRQ(LBS)WEIGHT %N/AN/AN/ACARCINOGENITY:NTPIARC MONOGRAPHSOSHA3. THIS PRODUCT HAS THE FOLLOWING HAZARDS (SECTION 311 AND 312):NONONOYESNOIMMEDIATEXDELAYEDXFIREXP RESSUREXREACTIVITYXThe information provided in this MATERIAL SAFETY data SHEET has been obtained and compiled from sources believed to be reliable.

10 This information relates to the specific materialdesignated and may not be valid for such MATERIAL used in combination with any other MATERIAL or in any process. Such information is to the best of our knowledge and belief, accurateand reliable as of the date compiled. However, no representation, warranty or guarantee is made as to its accuracy, reliability, or completeness. It is the user's responsibility to satisfyhimself as to the suitability and completeness ofsuch information for his own particular use. Vance Brothers , Inc. does not accept liability for any loss or damage that may occurfrom the use of this information nor do we offer warranty against 15, 2012 Vance Brothers , BRIGHTON,KANSAS CITY, MO 64130(816) 923-4325380 W 62ndAVE, DENVER, CO 80216(303) 341-26044908 N BRYANT, OKLAHOMA CITY, OK 73121 (405) 427-13899306 E.