Methylcyclohexane - Chevron Phillips Chemical

1 SAFETY DATA SHEET. Methylcyclohexane Version Revision Date 2017-12-18. SECTION 1: Identification of the substance/mixture and of the company/undertaking Product information Product Name : Methylcyclohexane Material : 1098852, 1021714, 1021712, 1028351, 1021711, 1024851, 1028352, 1024850, 1021713. number Chemical name CAS-No. Legal Entity EC-No. Registration number Index No. Methylcyclohexane 108-87-2. 203-624-3 01-2119556887-18-XXXX. 601-018-00-7. Relevant Identified Uses : Solvent in other applications Supported Use in polymer processing professional, Solvent Use in coatings professional, Solvent Lubricants - Professional, Solvent Use as a cleaning agent professional, Solvent Solvent in other applications- Professional Company : Chevron Phillips Chemical Company LP. Specialty Chemicals 10001 Six Pines Drive The Woodlands, TX 77380. Local : Chevron Phillips Chemicals International Airport Plaza (Stockholm Building). Leonardo Da Vincilaan 19. 1831 Diegem Belgium SDS Requests: (800) 852-5530.

2 Technical Information: (832) 813-4862. Responsible Party: Product Safety Group Emergency telephone: SDS Number:100000014163 1/56. SAFETY DATA SHEET. Methylcyclohexane Version Revision Date 2017-12-18. Health: (North America). (International). Transport: CHEMTREC or (int'l). Asia: CHEMWATCH (+612 9186 1132) China: 0532 8388 9090. EUROPE: BIG + (phone) or + (telefax). Mexico CHEMTREC 01-800-681-9531 (24 hours). South America SOS-Cotec Inside Brazil: Outside Brazil: + Argentina: +(54)-1159839431. Responsible Department : Product Safety and Toxicology Group E-mail address : Website : SECTION 2: Hazards identification Classification of the substance or mixture REGULATION (EC) No 1272/2008. Aspiration hazard, Category 1 H304: May be fatal if swallowed and enters airways. Skin irritation, Category 2 H315: Causes skin irritation. Flammable liquids, Category 2 H225: Highly flammable liquid and vapor. Specific target organ systemic toxicity - H336: single exposure, Category 3, Central May cause drowsiness or dizziness.

3 Nervous system Acute toxicity, Category 1 H400: Very toxic to aquatic life. Chronic aquatic toxicity, Category 2 H411: Toxic to aquatic life with long lasting effects. Label elements Labeling (REGULATION (EC) No 1272/2008). Hazard pictograms : Signal Word : Danger Hazard Statements : H225 Highly flammable liquid and vapor. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H336 May cause drowsiness or dizziness. H411 Toxic to aquatic life with long lasting effects. Precautionary Statements : Prevention: P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P243 Take precautionary measures against static SDS Number:100000014163 2/56. SAFETY DATA SHEET. Methylcyclohexane Version Revision Date 2017-12-18. discharge. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/. eye protection/ face protection.

4 SECTION 3: Composition/information on ingredients Synonyms : Cyclohexylmethane Hexahydrotoluene MCH. Methylcyclohexane (Pure Grade). Molecular formula : C7H14. Mixtures Hazardous ingredients Chemical name CAS-No. Classification Concentration EC-No. (REGULATION (EC) No [wt%]. Index No. 1272/2008). Methylcyclohexane 108-87-2 Flam. Liq. 2; H225 99,8 - 100. 203-624-3 Skin Irrit. 2; H315. 601-018-00-7 STOT SE 3; H336. Asp. Tox. 1; H304. Aquatic Acute 1; H400. Aquatic Chronic 2; H411. For the full text of the H-Statements mentioned in this Section, see Section 16. SECTION 4: First aid measures General advice : Move out of dangerous area. Show this material safety data sheet to the doctor in attendance. Material may produce a serious, potentially fatal pneumonia if swallowed or vomited. If inhaled : Consult a physician after significant exposure. If unconscious, place in recovery position and seek medical advice. In case of skin contact : If on skin, rinse well with water.

5 If on clothes, remove clothes. In case of eye contact : Flush eyes with water as a precaution. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. If swallowed : Keep respiratory tract clear. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Take victim immediately to hospital. SDS Number:100000014163 3/56. SAFETY DATA SHEET. Methylcyclohexane Version Revision Date 2017-12-18. SECTION 5: Firefighting measures Flash point : -5,5 C (22,1 F). Method: Tagliabue Open Cup Autoignition temperature : 285 C (545 F). Suitable extinguishing : Alcohol-resistant foam. Carbon dioxide (CO2). Dry Chemical . media Unsuitable extinguishing : High volume water jet. media Specific hazards during fire : Do not allow run-off from fire fighting to enter drains or water fighting courses. Special protective : Wear self-contained breathing apparatus for firefighting if equipment for fire-fighters necessary.

6 Further information : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. For safety reasons in case of fire, cans should be stored separately in closed containments. Use a water spray to cool fully closed containers. Fire and explosion : Do not spray on an open flame or any other incandescent protection material. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapors). Use only explosion-proof equipment. Keep away from open flames, hot surfaces and sources of ignition. Hazardous decomposition : Hydrocarbons. Carbon oxides. products SECTION 6: Accidental release measures Personal precautions : Use personal protective equipment. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapors accumulating to form explosive concentrations.

7 Vapors can accumulate in low areas. Environmental precautions : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. Methods for cleaning up : Contain spillage, and then collect with non-combustible absorbent material, ( sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). SECTION 7: Handling and storage Handling SDS Number:100000014163 4/56. SAFETY DATA SHEET. Methylcyclohexane Version Revision Date 2017-12-18. Advice on safe handling : Avoid formation of aerosol. Do not breathe vapors/dust. Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Take precautionary measures against static discharges.

8 Provide sufficient air exchange and/or exhaust in work rooms. Open drum carefully as content may be under pressure. Dispose of rinse water in accordance with local and national regulations. Advice on protection : Do not spray on an open flame or any other incandescent against fire and explosion material. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapors). Use only explosion-proof equipment. Keep away from open flames, hot surfaces and sources of ignition. Storage Requirements for storage : No smoking. Keep container tightly closed in a dry and well- areas and containers ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Observe label precautions. Electrical installations / working materials must comply with the technological safety standards. SECTION 8: Exposure controls/personal protection Ingredients with workplace control parameters SK.

9 Zlo ky Podstata Hodnota Kontroln parametre Pozn mka Methylcyclohexane SK OEL NPEL priemern 200 ppm, 810 mg/m3. SK OEL NPEL kr tkodob 400 ppm, mg/m3. SI. Sestavine Osnova Vrednost Parametri nadzora Pripomba Methylcyclohexane SI OEL MV 500 ppm, mg/m3. PT. Componentes Bases Valor Par metros de Nota controlo irrita o do TRS, afe o Methylcyclohexane PT OEL VLE-MP 400 ppm, do SNC, afe o do SNC afe o do sistema nervoso central irrita o do irrita o do trato respirat rio superior TRS. PL. Sk adniki Podstawa Warto Parametry dotycz ce Uwaga kontroli Methylcyclohexane PL NDS NDS mg/m3. PL NDS NDSch mg/m3. NO. Komponenter Grunnlag Verdi Kontrollparametrer Nota FOR-2011-12-06- Methylcyclohexane 1358. TWA 200 ppm, 800 mg/m3. LT. Komponentai Pagrindas, baz Vert Kontrol s parametrai Pastaba Methylcyclohexane LT OEL IPRD 50 mg/m3. IE. Ingredients Basis Value Control parameters Note Methylcyclohexane IE OEL OELV - 8 hrs (TWA) 400 ppm, mg/m3. SDS Number:100000014163 5/56.

10 SAFETY DATA SHEET. Methylcyclohexane Version Revision Date 2017-12-18. GR.. Methylcyclohexane GR OEL TWA 500 ppm, mg/m3. GR OEL STEL 500 ppm, mg/m3. FR. Composants Base Valeur Param tres de Note contr le Methylcyclohexane FR VLE VME 400 ppm, mg/m3 normal, normal Valeurs limites indicatives FI. Aineosat Peruste Arvo Valvontaa koskevat Huomautus muuttujat Methylcyclohexane FI OEL HTP-arvot 8h 400 ppm, mg/m3. FI OEL HTP-arvot 15 min 500 ppm, mg/m3. ES. Componentes Base Valor Par metros de control Nota Methylcyclohexane ES VLA VLA-ED 400 ppm, mg/m3. EE. Komponendid, osad Alused V rtus Kontrolliparameetrid M rkused Methylcyclohexane EE OEL Piirnorm 400 ppm, mg/m3. DK. Komponenter Basis V rdi Kontrolparametre Note Methylcyclohexane DK OEL GV 200 ppm, 805 mg/m3. DE. Inhaltsstoffe Grundlage Wert Zu berwachende Bemerkung Parameter Methylcyclohexane DE TRGS 900 AGW 200 ppm, 810 mg/m3 DFG, DFG Senatskommission zur Pr fung gesundheitssch dlicher Arbeitsstoffe der DFG (MAK-Kommission).