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SAFETY DATA SHEET - ADAMA Agricultural Solutions

Orius 250 EWSAFETY data SHEETS afety data SHEET according to Regulation (EC) No. 1907/2006 (REACH) Annex IIRevision Date 15-Jun-2014 Version 1 Product No FNG56796-27 Publish Date 15-Jun-2014R-9129 HT 308 25 EWSection 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF Product identifier Orius 250 EWSynonymsTebuconazole 250 EWPure Relevant identified uses of the substance or mixture and uses advised against Recommended UseFungicideUses advised againstNo information Details of the supplier of the SAFETY data SHEET Supplier AddressADAMA SOUTH AFRICA (PTY) LTD21 Viben StreetBrankenfell7560 For further information, please contact Email Emergency telephone number Emergency Telephone+ 27 82 331 6463+ 27 21 982 1460 Section 2.

Orius 250 EW SAFETY DATA SHEET Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) Annex II Revision Date 15-Jun-2014 Version 1 …

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Transcription of SAFETY DATA SHEET - ADAMA Agricultural Solutions

1 Orius 250 EWSAFETY data SHEETS afety data SHEET according to Regulation (EC) No. 1907/2006 (REACH) Annex IIRevision Date 15-Jun-2014 Version 1 Product No FNG56796-27 Publish Date 15-Jun-2014R-9129 HT 308 25 EWSection 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF Product identifier Orius 250 EWSynonymsTebuconazole 250 EWPure Relevant identified uses of the substance or mixture and uses advised against Recommended UseFungicideUses advised againstNo information Details of the supplier of the SAFETY data SHEET Supplier AddressADAMA SOUTH AFRICA (PTY) LTD21 Viben StreetBrankenfell7560 For further information, please contact Email Emergency telephone number Emergency Telephone+ 27 82 331 6463+ 27 21 982 1460 Section 2.

2 HAZARD Classification of the substance or mixture Classification of the product is based on the coformulants listed in section 3 Repr. cat. 3;R63 - Xi;R36 - N;R51-53 Full text of R-phrases: see section Label elements The product is classified and labeled in accordance with Directive 1999/45/ECHazard symbolsPage 1 / 8Xn - HarmfulN - Dangerous for the environment_____Orius 250 EW - FNG56796-27 Revision Date 15-Jun-2014R-PhrasesR36 - Irritating to eyesR63 - Possible risk of harm to the unborn childR51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquaticenvironmentS phrasesS2 - Keep out of the reach of childrenS26 - In case of contact with eyes, rinse immediately with plenty of water and seek medicaladviceS36 - Wear suitable protective clothingS53 - Avoid exposure obtain special instructions before useS60 - This material and its container must be disposed of as hazardous Other hazards Other Information Section 3: COMPOSITION/INFORMATION ON Mixture Chemical NameWeight-%CAS NoEC NoIndex NoClassification accordingto Regulation (EC) [CLP]Classificationaccording to67/548/EECREACHR egistrationNumberTebuconazole25-27107534 -96-3-603-197-00-7 Acute Tox.

3 4 (H302)Repr. 2 (H361d)Aquatic Acute 1 (H400)Aquatic Chronic 1 (H410)Xn; ; R63N; R50-53-N,N-dimethyldecanamide60-7014433- 76-2238-405-1-Skin Irrit. 2 (H315) Eye Irrit. 2 (H319)Xi; R36-3801-2119485027-36-0001 Full text of R-phrases: see section 16 Section 4: FIRST AID Description of first aid measures General adviceIn case of accident or unwellness, seek medical advice immediately (show directions foruse or SAFETY data SHEET if possible). First aider: Pay attention to self-protection!.InhalationRemove to fresh air. If breathing is irregular or stopped, administer artificial respiration. Calla ContactWash off immediately with soap and plenty of water while removing all contaminatedclothes and shoes. Consult a physician if contact_____Immediately flush with plenty of water.

4 After initial flushing, remove any contact lenses andcontinue flushing for at least 15 minutes. Keep eye wide open while rinsing. If symptomspersist, call a NOT induce vomiting. Rinse mouth. Drink plenty of water. If symptoms persist, call of the first aiderUse personal protective equipment as 2 / Most important symptoms and effects, both acute and delayed _____Orius 250 EW - FNG56796-27 Revision Date 15-Jun-2014 SymptomsNone Indication of any immediate medical attention and special treatment needed Note to physiciansTreat 5: FIRE-FIGHTING Extinguishing media Suitable Extinguishing MediaUse extinguishing measures that are appropriate to local circumstances and the surrounding Extinguishing MediaNo information Special hazards arising from the substance or mixture No specific hazard Advice for firefighters In the event of fire, wear self-contained breathing apparatusIn the event of fire and/or explosion do not breathe fumesSection 6: ACCIDENTAL RELEASE Personal precautions, protective equipment and emergency procedures Personal precautionsUse personal protective equipment as required.

5 Evacuate personnel to safe areas. Keep people away from and upwind emergency respondersUse personal protection recommended in Section Environmental precautions Prevent entry into waterways, sewers, basements or confined areas. Do not flush into surface water or sanitary sewer further leakage or spillage if safe to do so. Prevent product from entering Methods and material for containment and cleaning up Methods for cleaning upTake up mechanically, placing in appropriate containers for Reference to other sections _____Other InformationSee also section 8,13 Section 7: HANDLING AND Precautions for safe handling Page 3 / 8 Advice on safe handlingUse personal protective equipment as required. Avoid contact with skin, eyes or clothing.

6 Wash contaminated clothing beforereuse. Do not breathe dust/fume/gas/mist/vapors/spray. Do not eat, drink or smoke when using this product. Use with local 250 EW - FNG56796-27 Revision Date 15-Jun-2014 General Hygiene ConsiderationsWhen using do not eat, drink or smoke. Wash contaminated clothing before reuse. Regular cleaning of equipment, work area andclothing is Conditions for safe storage, including any incompatibilities Storage ConditionsKeep container tightly closed in a dry and well-ventilated place. Keep out of the reach of children. Keep containers tightly closed ina cool, well-ventilated place. Keep in properly labeled Specific end use(s) Risk Management Methods (RMM)The information required is contained in this Material SAFETY data 8: EXPOSURE CONTROLS/PERSONAL Control parameters Derived No Effect Level (DNEL)No information availablePredicted No Effect Concentration(PNEC)No information Exposure controls Engineering ControlsEnsure adequate ventilation, especially in confined protective equipmentEye/face protectionTight sealing SAFETY ProtectionRubber boots, Apron, Wear impervious protective clothing, including boots, gloves, lab coat,apron or coveralls, as appropriate, to prevent skin contact, Gloves made of plastic Hygiene ConsiderationsWhen using do not eat, drink or smoke.

7 Wash contaminated clothing before reuse. Regularcleaning of equipment, work area and clothing is exposure controlsDo not allow into any sewer, on the ground or into any body of 9: PHYSICAL AND CHEMICAL Information on basic physical and chemical properties Property Values Method Remarks AppearancePhysical state:LiquidColor:light yellowOdor:characteristicOdor threshold:No data MT solution, 1 %Melting point/freezing point C: No data availableBoiling point/boiling range C:No data availableFlash point C: >79 CIPAC MT rate:Not ApplicableFlammability (solid, gas):Not ApplicableUpper/lower flammability orexplosive limits:No data available_____Vapor pressure kPa:No data availableVapor density.

8 No data availablePage 4 / 8_____Orius 250 EW - FNG56796-27 Revision Date Other information Section 10: STABILITY AND Reactivity Not Chemical stability Stable under normal Possibility of hazardous reactions None under normal Conditions to avoid To avoid thermal decomposition, do not Incompatible materials Strong bases, Strong Hazardous decomposition products Chemical NameTebuconazoleCarbon dioxide (CO2), Carbon monoxide, Nitrogen oxides (NOx), Hydrogen 11: TOXICOLOGY Information on toxicological effects Acute toxicityChronic toxicityGerm cell mutagenicityChemical NameTebuconazole:Not classifiedRelative MT (ies) mg/l:No data availablePartition Coefficient(n-octanol/water) Log Pow:See Section 12 for moreinformationAutoignition temperature C:357 EEC temperature C:No data availableKinematic viscosity mm2/s 40 D445-53 TExplosive properties:Not an explosiveOxidizing properties:NoBulk density g/ml:Surface tension mN/m:<60 Minimum ignition energy (MIE) mJ:Values Species Method Remarks Oral LD50 mg/kg: >2000 RatOECD 401 Dermal LD50 mg/kg: >2000 RatOECD 402 Inhalation LC50 mg/l/4h: > 403 Skin corrosion/irritation:Non-irritating to the skinRabbitOECD 404 Serious eye damage/eye irritation:Irritating to eyesRabbitOECD 405 Respiratory/skin sensitization.

9 Not a skin sensitizer_____Guinea pig(M&K test)Page 5 / 8_____Orius 250 EW - FNG56796-27 Revision Date NameTebuconazole:Not classifiedReproductive toxicity .Chemical NameTebuconazole:H361d - Suspected of damaging the unborn childSTOT - single exposureChemical NameTebuconazole:No information availableSTOT - repeated exposureChemical NameTebuconazole:No information availableAspiration hazardChemical NameTebuconazole:No information availableSection 12: ECOLOGICAL Toxicity Acute toxicityTerrestrial ToxicityBirds Oral LD50 mg/kgChemical NameTebuconazole:1988 Bobwhite quailBees Oral LD50 g/beeChemical Persistence and degradability Water DT50 daysChemical NameTebuconazole:365 Soil DT50 daysChemical NameTebuconazole.

10 Not readily biodegradableOECD Bioaccumulative potential Chemical NameAquatic toxicityValues Species Method Remarks Fish 96-hour LC50 mg/l: troutOECD 203 StaticCrustacea 48-hour EC50 mg/l: 16 Daphnia magnaOECD 202 Algae 72-hour EC50 mg/l: SubspicatusOECD 201 Other plants EC50 mg/l:No data available_____Abiotic DegradationValues Method Remarks Partition Coefficient(n-octanol/water) Log PowValues Page 6 / 8 Method Remarks _____Orius 250 EW - FNG56796-27 Revision Date 15-Jun-2014 factor (BCF)Chemical Mobility in soil Chemical Results of PBT and vPvB assessment The components in this formulation do not meet the criteria for classification as PBT or Other adverse effects No information 13.


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