Safety Data Sheet - Ak-Kim

1 Page No: 1/15 Safety data Sheet According To Regulation (EC) No 1907/2006 (REACH) SODIUM METABISULFITE (FOOD GRADE)- E223 Version: Preparation Date : 11/7/2013 Form No: 193223 Revision Date: 11/7/2013 | SODIUM METABISULFITE (FOOD GRADE)- E223 1. IDENTIFICATION OF THE PRODUCT AND OF THE COMPANY/UNDERTAKING Product Identifier Product Name SODIUM METABISULFITE (FOOD GRADE)- E223 SDS1 No 193223 CAS2 No 7681-57-4 EINECS3 No 231-673-0 Chemical Name Sodium metabisulfite Chemical Formula Na2S2O5 Structural Formula Relevant Identified Uses Of The Product And Uses Advised Against Relevant Identified Uses - Antichlore in bleaching in textile industry - Antiseptic in production of cellulose esters - Main raw material in production of sodium hydrosulfite.

2 Aromatic alcohols and aldehide - Preservative and disinfectant in food and beverage industries as a source of sulfur dioxide - Antiseptic in fermentation process - Color removing in paint and leather industries - Disinfectant in cosmetic and canned industry - Various applications in paper, fiber, rubber and adhesive industries Uses Advised Against See chapter 16 for a general overview Details Of The Supplier Of The Safety data Sheet Supplier (Manufacturer) AK-K M K MYA SAN. VE T C. A.. Address Factory Deniz al K y , Ta k pr Mevkii, 39 77600 Yalova / T RK YE Telephone 0 226 815 33 00 Fax 0 226 353 25 39 Information Providing Authority About Safety data Sheet Ali Haydar KET R Environmental Engineer Telephone +90 (226) 815 33 00 / 33304 Fax Emergency Telephone Number Company Emergency 0 226 815 33 00 Page No: 2/15 Safety data Sheet According To Regulation (EC) No 1907/2006 (REACH) SODIUM METABISULFITE (FOOD GRADE)- E223 Version: Preparation Date : 11/7/2013 Form No.

3 193223 Revision Date: 11/7/2013 | SODIUM METABISULFITE (FOOD GRADE)- E223 2. HAZARDS IDENTIFICATION Classification Of The Product Classification According to Regulation (EC) No 1272/2008 Acute toxicity, Category 4, oral; H302 Serious eye damage, Category 1; H318 Label elements Labeling According to Regulation (EC) No 1272/2008 [CLP4/GHS5] Product Identifier Hazard Component for Labeling Sodium metabisulfite Hazard Pictograms Signal Word Danger Hazard Statements H302 Harmful if swallowed H318 Causes serious eye damage Precautionary Statements General None Prevention P280 Wear protective gloves/ eye protection/ face protection Response P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes.

4 Remove contact lenses, if present and easy to do. Continue rinsing. P318 Get medical advice/attention Storage None Disposal None Supplemental Hazard Information (EU) Statements EUH031 Contact with acids liberates toxic gas. Special Rules For Supplemental Label Elements For Certain Mixtures None. Additional Labeling Not Applicable Hazard Identification Skin Contact May be harmful if absorbed through skin. May cause skin irritation Eye Contact Page No: 3/15 Safety data Sheet According To Regulation (EC) No 1907/2006 (REACH) SODIUM METABISULFITE (FOOD GRADE)- E223 Version: Preparation Date : 11/7/2013 Form No: 193223 Revision Date: 11/7/2013 | SODIUM METABISULFITE (FOOD GRADE)- E223 Causes eye burns.

5 Ingestion Harmful if swallowed. Inhalation May be harmful if inhaled. May cause respiratory tract irritation. Long term effects Repeated oral uptake of the substance did not cause substance-related effects. Repeated inhalative uptake of the substance did not cause substance-related effects. The product has not been tested. The statement has been derived from products of a similar structure or composition. Adverse Environmental Effects No data available Additional Information None 3. COMPOSITION/INFORMATION ON INGREDIENTS Description Of The Substance: Sodium Sulfite ( 97,5%) NAME EINECS NO CAS NO.

6 CONTENT (%) CLASSIFICATION CLP Sodium metabisulphite 231-673-0 7681-57-4 >= 98,00 % DANGER Acute toxicity, Category 4, oral; H302 Serious eye damage, Category 1; H318 Additional information None 4. FIRST AID MEASURES Description of first aid measures General information Remove contaminated clothing. In case of accident or unwellness, seek medical advice immediately (show directions for use or Safety data Sheet if possible). Following inhalation Whilst protecting yourself remove the casualty from the hazardous area and take him to the fresh air.

7 Lay the casualty down in a quiet place and protect him against hypothermia. If signs of difficulty in breathing or irritation appear As soon as possible repeatedly have the casualty deeply breath a glucocorticoid inhalation spray in. Arrange medical treatment. Following skin contact Remove contaminated clothing while protecting yourself. Immediately cleanse the affected skin areas with soap under running water. Arrange medical treatment. Page No: 4/15 Safety data Sheet According To Regulation (EC) No 1907/2006 (REACH) SODIUM METABISULFITE (FOOD GRADE)- E223 Version: Preparation Date : 11/7/2013 Form No: 193223 Revision Date: 11/7/2013 | SODIUM METABISULFITE (FOOD GRADE)- E223 Following eye contact Rinse the affected eye with widely spread lids for 10 minutes under running water whilst protecting the unimpaired eye.

8 Arrange medical treatment. Following ingestion Rinse the mouth and spit the fluids out. If the casualty is conscious have him drink copious amounts of liquids (water). Do not make the casualty vomit. Arrange medical treatment. During spontaneous vomiting hold the head of the casualty low with the body in a prone position in order to avoid penetration of the vomit into the air tube. Self-protection of the first aider Pay attention to self-protection Notes for the doctor Following contact with sodium metabisulfite acute hypersensitivity reactions are to be considered to be the most significant risk for persons with sensitivity to sulfites.

9 In general only irritation to the eyes, upper airways and other mucous membranes contacted are expected; systemic effects seem to be minor. The following information on first aid also takes the data available for sodium bisulfite into consideration. - Symptoms of acute poisoning: Eyes: irritation to the conjunctives, possible opacity of the cornea, in single cases hypersensitivity reactions (see below) Skin: following short-term contact generally weak/absent irritation, seldom allergic skin reactions (dermatitis, eczema) Inhalation: concentration dependent irritation predominantly in the upper respiratory tract, also bronchoconstriction,in extreme cases lung damage not to be excluded.

10 For persons with sensitivity to sulfites: mostly within some minutes up to 1 h bronchospasm, asthma attacks, more seldom urticaria, swelling of the nasal mucosa, angioedema, glottis edema, gastrointestinal symptoms, hypotension, shock Ingestion: following intake of high doses irritation to the mucous membranes and gastrointestinal complaints (nausea,vomiting); also possible systemic effects;for persons with sensitivity to sulfites immediate reactions, as desribed for inhalation, even after mg doses Absorption: no valid data on toxic effects available; possible nerval disturbances (indications from animal experiments).