SAFETY DATA SHEET - Alliance Chemicals

1 SAFETY data SHEET according to (EC) 1907/2006 Version: 5 Page: 1/ 13 Version Date: 16/07/2015 1. IDENTIFICATION OF THE SUBSTANCE/ PREPARATION AND OF THE COMPANY UNDERTAKING Product identifier Trade name Propylene Carbonate CAS number 108-32-7 EC number 203-572-1 Index number 607-194-00-1 Registration number 01-2119537232-48-xxxx Relevant identified uses of the substance or mixture and uses advised against: Uses advised against Applications of the substance Intermediate, Raw material for industrial application, Polar solvent, Lubricants, Adhesives, Plasticiser Details of the supplier of the SAFETY data SHEET Supplier/ Manufacturer: Alliance Chemicals Limited Old Walls, Chapel Lane, Penselwood, BA9 8LY United Kingdom Telephone: +44 (0) 1747841222 Fax: +44 (0) 1747841333 Email.

2 Emergency telephone number +44 (0) 1747841222 according to (EC) 1907/2006 Version: 5 Page: 2/ 13 Version Date: 16/07/2015 2. HAZARDS IDENTIFICATION Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 GHS07 Eye irritant: Category 2 H319 Causes serious eye irritation Classification according to Directive 67/548/EEC or Directive 1999/45/EC Xi; irritant R36: irritating to the eyes Information concerning particular hazards for human and environment Mainly resorbed via respiratory tract and skin Classification system: The classification is based on company information and on Regulation (EC) 1272/2008 including its amendments.

3 Label elements Label Elements Labelling (Regulation (EC) No 1272/2008; Symbol(s) GHS07 Signal word Warning Hazard statements H319 Causes serious eye irritation Precautionary statements Prevention: P264 Wash with plenty of water and soap thoroughly after handling P280 Wear eye protection/ face protection Response: P305 + P351 IF IN EYES: Rinse cautiously + P338 with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337 + P313 If eye irritation persists: Get medical advice/ attention Hazardous components which must be listed on the label: Propylene Carbonate according to (EC) 1907/2006 Version: 5 Page: 3/ 13 Version Date: 16/07/2015 Other hazards Results of PBT and vPvB assessment PBT: Not applicable due to data vPvB: Not applicable due to data 3.)

4 COMPOSITION/ INFORMATION ON INGREDIENTS Chemical characterisation: Substances Substances Description Propylene Carbonate CAS number: 108-32-7 EC number: 203-572-1 Index number: 607-194-00-1 4. FIRST AID MEASURES Description of first aid measures General Advice: In case of accident or if you feel unwell seek medical advice immediately Show this SAFETY date SHEET to the doctor in attendance If inhaled: Remove to fresh air immediately. Seek medical attention In case of skin contact: Remove contaminated clothes and shoes. Remove person from source of contamination Immediately flush with water for at least 15 minutes If skin irritation persists call a doctor In case of eye contact: Immediately rinse with water for at least 15 minutes holding the eyelids apart.

5 Get medical attention immediately If swallowed: Wash mouth out with water and then drink plenty of water Never give anything by mouth to an unconscious person Get medical attention immediately DO NOT induce vomiting! Most important symptoms an effects, both acute and delayed Irritation of eyes and mucous membrane After inhalation: Oedema of the lungs Information for doctor: After inhalation oedema of the lungs may occur. Symptoms can also occur several hours after over exposure. according to (EC) 1907/2006 Version: 5 Page: 4/ 13 Version Date: 16/07/2015 Indication of any immediate medical and special treatment needed Symptomatic treatment. If in doubt get medical attention immediately 5.

6 FIRE FIGHTING MEASURES Extinguishing media Suitable extinguishing agents: Water spray, dry powder, carbon dioxide. Fight larger fires with water spray or alcohol resistant foam For SAFETY reasons unsuitable extinguishing agents: High volume water jet Special hazards arising from the substance or mixture In case of fire the following can be released: Carbon monoxide (CO) Carbon dioxide (CO2) Advice for fire fighters Protective equipment: Wear self-contained breathing apparatus and protective suit Additional information: Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and fire extinguishing water must be disposed of in accordance with local regulations.

7 Heat leads to a pressure increase and risk of the packaging rupturing. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation Wear protective clothing Use respiratory protective device against the effects of fumes/dust/aerosol Environmental precautions Do not allow the product to penetrate the ground/soil Do not allow the product to reach any water course/ sewage systems Methods for cleaning up/ Methods for containment Soak up with inert absorbent material ( silica gel, universal binder, sawdust) Keep in suitable closed and labelled containers for disposal according to (EC) 1907/2006 Version: 5 Page: 5/ 13 Version Date.

8 16/07/2015 Reference to other sections Additional Advice: For personal protection see Section 8 For additional information on health hazards see Section 11 For additional information on safe handling see Section 7 For information on collection and disposal of spillages see Section 13 7. HANDLING AND STORAGE Precautions for safe handling Avoid contact with skin and eyes Avoid inhalation of vapours Wear full protective clothing for prolonged exposure Ensure good ventilation at the workplace Dispose of rinse water in accordance with local and national regulations Information about protection against explosions and fires: Keep ignition sources away No smoking Conditions for safe storage including any incompatibilities Requirements for storage areas and containers: No smoking Do not store near heat sources or expose to high temperatures Keep container tightly closed in a dry and well ventilated place Information about storage in one common storage facility.

9 Store away from feedstuffs or foodstuffs Store away from aluminium Storage class: 10 Combustible liquids Specific end uses No information is available according to (EC) 1907/2006 Version: 5 Page: 6/ 13 Version Date: 16/07/2015 8. EXPOSURE CONTROLS/ PERSONAL PROTECTION Control parameters Components with workplace control parameters: Not required propylene carbonate 108-32-7 DNEL: Oral DNEL/Cons/LSE 25 mg/kg bw/day (human) Dermal DNEL/Cons/LSE 25 mg/kg bw/day (human) DNEL/In/LSE 50 mg/kg bw/day (human) Inhalative DNEL/Cons/LLE 10/mg/m (human) DNEL/Cons/LSE mg/m (human) DNEL/In/LSE 176mg/m (human) propylene carbonate 108-32-7 PNEC.

10 PNEC 7400 mg/l (sewage treatment plant) PNEC/aq mg/l (fresh water) mg/l (intermittent release) mg/l (marine water) PNEC/soil mg/kg (-) Since the substance has no potential for bioaccumulation no PNEC oral was derived Abbreviations In = Industrial LLE = Long term, local effects aq = aqua Prof = Professional LSE = Long term, systemic effects sed = sediment Cons = Consumer SLE = Short term, local effects SSE = Short term, systemic effects Exposure controls Personal protective equipment General protective and hygienic measures: Handle in accordance with good industrial hygiene and SAFETY practice Avoid contact with eyes When using do not eat, drink or smoke Wash hands before breaks and at the end of the working day Respiratory protection: In the case of vapour formation use a respirator with an approved filter.