Safety Data Sheet - Americas International

1 Safety data Sheet According to GHS. SECTION 1: Identification of the substance/mixture and of the company/undertaking Product identifier Trade name: PILCURE MBTS. Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, (contains Dibenzothiazole disulphide). Other means of identification: MBTS. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Rubber Vulcanization Accelerator Uses advised against Advice against other uses: None identified Details of the supplier of the Safety data Sheet Supplier: NOCIL LIMITED. Address: MAFATLAL HOUSE, PAREKH MARG, BACKBAY RECLAMATION, CHURCHGATE, MUMBAI 400 020, MAHARASHTRA STATE, INDIA. Telephone: +9122 66364062. Fax: +9122 66364060. Emergency Contact NOCIL LIMITED.

2 (24 Hrs.) C-37, TTC INDUSTRIAL AREA, OFF THANE BELAPUR ROAD, TURBHE, NAVI MUMBAI-400705, MAHARASHTRA STATE, INDIA. Telephone No. :+91 22 66730555. FAX No. : +91 22 27671862. E-mail : SECTION 2: Hazards identification Classification of the substance or mixture Classification according to GHS. Classification Category Exposure Route Skin Sensitization 1 - Aquatic Acute 1 - Aquatic Chronic 1 - Other adverse physicochemical, human health and environmental effects No reliable data available. Label elements Labelling according to GHS. Hazard pictogram: Signal word: Warning Hazard Statements: H317: May cause an allergic skin reaction. H400: Very toxic to aquatic life H410:Very toxic to aquatic life with long lasting effects Date: 02 MARCH 2015 Issue : 2 Revision: 0 Page : 1 of 6.

3 Safety data Sheet According to GHS. Precautionary Statements: Prevention: P261: Avoid breathing dust. P272: Contaminated work clothing should not be allowed out of the workplace. P273: Avoid release to the environment. P280: Wear protective gloves/protective clothing/eye protection/face protection. Response: P302+352: IF ON SKIN: Wash with plenty of soap and water. P333+313: If skin irritation or rash occurs: Get medical advice/attention. P363: Wash contaminated clothing before reuse. P391: Collect spillage. Disposal: P501 Dispose of contents/container in accordance with local/regional/national/ International regulation. NFPA Ratings (Scale 0 4): Health: 1, Fire: 1, Reactivity: 0. Other hazards EUH031: Contact with acids liberates toxic gas SECTION 3: Composition/information on ingredients Substances Name CAS No.

4 EC No. % wt/wt Dibenzothiazole disulphide 120-78-5 204-424-9 >96%. Mercaptobenzothiazole 149 30 4 205-736-8 <1%. White mineral oil 8042-47-5 232-455-8 1-2%. Synonyms: 2, 2'-Dibenzothiazolyl Disulphide Mixtures Not applicable. SECTION 4: First aid measures Description of first aid measures Inhalation: Move victim to fresh air. If not breathing, give artificial respiration. Get medical attention. Skin contact: Immediately wash with plenty of soap and water. Get medical attention if irritation occurs. Eye contact: Immediately flush eyes with running water for at least 20 minutes holding eyelids open. Get medical attention. Ingestion: Do not induce vomiting. Give 1-2 glasses of water to a conscious victim. Never give anything by mouth to an unconscious victim.

5 Get medical attention. Advice for the doctor: Symptomatic treatment. Most important symptoms and effects, both acute and delayed May cause sensitization by skin contact;. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Indication of any immediate medical attention and special treatment needed No reliable data available. SECTION 5: Firefighting measures Extinguishing media Suitable extinguishing media: Foam. Dry chemical powder. Carbon dioxide. Water spray or fog - Large fires only Special hazards arising from the substance or mixture Fire/explosion hazard: Emits toxic fumes under fire conditions. Main combustion gas : carbon monoxide, carbon dioxide gases, nitrogen oxides and sulphur dioxide fumes.

6 Date: 02 MARCH 2015 Issue : 2 Revision: 0 Page: 2 of 6. Safety data Sheet According to GHS. Advice for firefighters Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves. Prevent, by any means available, spillage from entering drains or water courses. Use water delivered as a fine spray to control fire and cool adjacent area. DO NOT approach containers suspected to be hot. Cool fire exposed containers with water spray from a protected location. If safe to do so, remove containers from path of fire. SECTION 6: Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency personnel Wear suitable protective equipment. For emergency responders Remove ignition sources and provision of sufficient ventilation, evacuate the danger area and consult experts.

7 Environmental precautions Take precautions to prevent entry into waterways, sewers, or surface drainage systems. Dispose according to local or International regulations. Methods and material for containment and cleaning up Use appropriate tools to put the spilled solid in suitable container for recovery or disposal, avoid raising dust. SECTION 7: Handling and storage Precautions for safe handling Avoid ingestion, inhalation, skin and eye contact. Minimize dust generation and accumulation. Handle in accordance with good industrial hygiene practice and any legal requirements. Conditions for safe storage, including any incompatibilities Suitable container: Metal can or drum. Check all containers are clearly labelled and free from leaks.

8 Storage incompatibility: Avoid reaction with strong acid, alkali and oxidizing agents. SECTION 8: Exposure controls/personal protection Control parameters At this time no TLV has been established, even though this material may produce adverse health effects (as evidenced in animal experiments or clinical experience). Airborne concentrations must be maintained as low as is practically possible and occupational exposure must be kept to a minimum. Derived No Effect Level (DNEL). Exposure Pattern Workers General Population Acute - systemic effects 40 mg/kg bw/day 20 mg/kg bw/day Acute - systemic effects 70 mg/m mg/m . Acute - local effects No data available 10 mg/kg bw/day Long-term - systemic effects 5 mg/kg bw/day mg/kg bw/day Long-term - systemic effects mg/m mg/m.

9 Long-term - local effects Not relevant data mg/kg bw/day PNEC. water PNEC aqua (freshwater): mg/L sediment PNEC sediment (freshwater): Stp PNEC stp (mg/L) mg/kg sediment dw PNEC aqua (marine water): PNEC sediment (marine water): mg/L sediment dw Soil PNEC soil: mg/kg soil dw Exposure controls Appropriate engineering controls Use: process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. General Personal Protection: Safety goggles or face shield, protective chemical resistant gloves, protective clothing. SECTION 9: Physical and chemical properties Information on basic physical and chemical properties Physical state: Organic solid Colour: Cream Odour: Aromatic Date: 02 MARCH 2015 Issue : 2 Revision: 0 Page : 3 of 6.

10 Safety data Sheet According to GHS. Oduour threshold No data available pH: Not applicable Melting range 164 - 179 C. Boiling point: Decomposes before boiling. Flash point: 271 C (open cup). Evapotation rate: Not applicable Flammability (solid, gas): Not a readily combustible solid Upper/lower flammability: >= Kg/m3. Explosive limits: No data available Vapour pressure: *10-9hPa at 25 C. Relative density: at 19 C compared to water at 4 C. Solubility(ies): - mg/L at 25 C. Partition coefficient: n-octanol/water: at pH 7. Auto-ignition temperature: Does not undergo spontaneous combustion Viscosity: No data available Explosive properties: Dust Explosion Hazard Oxidising properties: No data available SECTION 10: Stability and reactivity Reactivity See section Chemical stability Stable under normal condition.