Transcription of Safety Data Sheet - Sinochem Australia
1 Safety data Sheet1. IDENTIFICATION OF THE MATERIAL AND SUPPLIERP roduct Name:Roundup Biactive HerbicideRecommended Use of the Chemicaland Restrictions on : Sinochem International Australia Pty LtdStreet Address:Level 8 / 606 St Kilda RoadMelbourne, Victoria, 3004 AustraliaTelephone Number:+61 3 9520 8888 Facsimile:+61 3 9520 8888 Emergency Telephone: Australia 1800 033 111 or +61 3 9663 2130 (All Hours)Please ensure you refer to the limitations of this Safety data Sheet as set out in the "Other Information" section at the end of this data HAZARDS IDENTIFICATIONNot classified as Dangerous Goods by the criteria of the Australian Dangerous Goods Code (ADG Code) for transportby Road and Rail; NON-DANGEROUS on available information, not classified as hazardous according to Safe Work Australia ; of the chemical:The following health/environmental hazard categories fall outside the scope of the Workplace Health and Safety Regulations:Eye damage/irritation - Category 2 BPoisons Schedule (SUSMP):S5 COMPOSITION AND INFORMATION ON INGREDIENTSP roduct Description: Active ingredient is Isopropylamine salt of NumberProportionHazard CodesIsopropylamine salt of (s), water and minor FIRST AID MEASURESP roduct Name: Roundup Biactive HerbicideIssued: 14/10/2016 Substance No: 000000062004 For advice, contact a Poisons Information Centre ( phone Australia 131 126.)
2 New Zealand 0800 764 766) or : 1 Inhalation:Remove victim from area of exposure - avoid becoming a casualty. Remove contaminated clothing and loosenremaining clothing. Allow patient to assume most comfortable position and keep warm. Keep at rest until fullyrecovered. Seek medical advice if effects 1 of 5 Skin Contact:Remove contaminated clothing and wash skin with running water. If irritation occurs seek medical data SheetEye Contact:If in eyes, hold eyelids apart and flush the eye continuously with running water. Continue flushing until advised to stopby a Poisons Information Centre or a doctor, or for at least 15 :Rinse mouth with water. If swallowed, do NOT induce vomiting. Give a glass of water. Never give anything by themouth to an unconscious patient. Seek medical of immediate medical attention and special treatment needed:This product is not an inhibitor of cholinesterase.
3 Treatment with atropine and oximes is not FIRE FIGHTING MEASURESS uitable Extinguishing Media:Not combustible, however, if material is involved in a fire use: Fine water spray, normal foam, dry agent (carbondioxide, dry chemical powder).Specific hazards arising from the chemical:Not combustible, however following evaporation of the water component of the material, the residual material canburn if ignited. On burning will emit toxic fumes, including those of oxides of carbon, oxides of phosphorus, oxides protective equipment and precautions for fire-fighters:Fire fighters to wear self-contained breathing apparatus and suitable protective clothing if risk of exposure to vapouror products of combustion. Equipment should be thoroughly decontaminated after ACCIDENTAL RELEASE MEASURESE mergency procedures/Environmental precautions:Clear area of all unprotected personnel.
4 Do not allow container or product to get into drains, sewers, streams orponds. If contamination of sewers or waterways has occurred advise local emergency precautions/Protective equipment/Methods and materials for containment and cleaning up:Slippery when spilt. Avoid accidents, clean up immediately. Contain - prevent run off into drains and waterways. Useabsorbent (soil, sand or other inert material). Collect and seal in properly labelled containers or drums for cleaning, flush away any residual traces with HANDLING AND STORAGEP roduct Name: Roundup Biactive HerbicideIssued: 14/10/2016 This material is a Scheduled Poison S5 and must be stored, maintained and used in accordance with the No: 000000062004 Precautions for safe handling:Avoid skin and eye contact and breathing in vapour, mists and aerosols.
5 When using do not eat, drink or smoke. Keepout of reach of children. Wash hands thoroughly after handling. Thoroughly clean equipment after use. Laundercontaminated clothing before reuse. Follow label warnings even after container is emptied since empty containersmay retain product : 1 Conditions for safe storage, including any incompatibilities:Store in a cool, dry, well ventilated place and out of direct sunlight. Do not store above 50 C. Store in the originalcontainer, tightly closed and away from foodstuffs. Store away from food, drink and animal feeding stuffs. Store awayfrom incompatible materials described in Section 10. Keep containers closed when not in use - check regularly 2 of 58. EXPOSURE CONTROLS/PERSONAL PROTECTIONS afety data SheetControl Parameters: No value assigned for this specific material by Safe Work engineering controls:Use in well ventilated areas.
6 Keep containers closed when not in protection measures, such as Personal Protective Equipment (PPE):The selection of PPE is dependent on a detailed risk assessment. The risk assessment should consider the worksituation, the physical form of the chemical, the handling methods, and environmental factors. OVERALLS, Safety SHOES, CHEMICAL GOGGLES, overalls, chemical goggles and impervious gloves. Always wash hands before smoking, eating, drinking orusing the toilet. Wash contaminated clothing and other protective equipment before storage or determined by a risk assessment an inhalation risk exists, wear a suitable mist respirator meeting the requirementsof AS/NZS 1715 and AS/NZS PHYSICAL AND CHEMICAL PROPERTIESP hysical state:LiquidColour:Green - Dark GreenOdour:SlightSolubility:Miscible in @ 25 CRelative Vapour Density (air=1):Not availableVapour Pressure (20 C):Not availableFlash Point ( C):Not applicableFlammability Limits (%):Not applicableAutoignition Temperature ( C):Not availableBoiling Point/Range ( C):Not - (80 g/L)Viscosity:Not availableEvaporation Rate:Not availablePartition Coefficient:log Pow: @ 25 C (glyphosate)10.
7 STABILITY AND REACTIVITYR eactivity:Reacts with mild steel, galvanised steel / zinc producing hydrogen gas which mayform explosive mixture with stability:Stable under normal conditions of of hazardousreactions:Product Name: Roundup Biactive HerbicideNone : 14/10/2016 Substance No: 000000062004 Conditions to avoid:Avoid exposure to direct sunlight. Avoid contact with : 1 Incompatible materials:Page 3 of 5 Incompatible with strong data SheetHazardous decompositionproducts:Oxides of carbon. Oxides of phosphorus. Oxides of TOXICOLOGICAL INFORMATIONNo adverse health effects expected if the product is handled in accordance with this Safety data Sheet and theproduct label. Symptoms or effects that may arise if the product is mishandled and overexposure occurs are:Ingestion:No adverse effects expected, however, large amounts may cause nausea contact:An eye contact:Contact with skin may result in :Breathing in mists or aerosols may produce respiratory toxicity: No LD50 data available for the product.
8 However, based on similar product(s):Oral LD50 (rat): >2000 mg/kgDermal LD50 (rabbit): >2000 mg/kgSkin corrosion/irritation:Minimal irritant (rabbit).Serious eye damage/irritation:Moderate irritant (rabbit).Respiratory or skinsensitisation:Not a skin sensitiser (guinea pig).Chronic effects: No information available for the ECOLOGICAL INFORMATIONE cotoxicityAvoid contaminating EC50 (Daphnia magna):243 mg/L (for similar formulation)96hr LC50 (rainbow trout):>1039 mg/L (for similar formulation)13. DISPOSAL CONSIDERATIONSP roduct Name: Roundup Biactive HerbicideDisposal methods:Triple or preferably pressure rinse containers before disposal. Add rinsings to spray tank. Do not dispose ofundiluted chemicals on recycling, replace cap and return clean containers to recycler or designated collection point.
9 If not recycling, break,crush or puncture and deliver empty packaging to an approved waste management facility. If an approved wastemanagement facility is not available, bury the empty packaging 500 mm below the surface in a disposal pit specificallymarked and set up for this purpose, clear of waterways, desirable vegetation and tree roots in compliance withrelevant local, state or territory government regulations. Do not burn empty containers or refillable container, empty contents fully into application equipment. Close all valves and return to point of supplyfor refill or storage. Do not reuse empty : 14/10/2016 Substance No: 00000006200414. TRANSPORT INFORMATIONV ersion: 1 Road and Rail TransportNot classified as Dangerous Goods by the criteria of the Australian Dangerous Goods Code (ADG Code) for transportby Road and Rail; NON-DANGEROUS 4 of 5 Safety data SheetMarine TransportNot classified as Dangerous Goods by the criteria of the International Maritime Dangerous Goods Code (IMDG Code)for transport by sea; NON-DANGEROUS TransportNot classified as Dangerous Goods by the criteria of the International Air Transport Association (IATA) DangerousGoods Regulations for transport by air; NON-DANGEROUS REGULATORY INFORMATIONC lassification:Based on available information, not classified as hazardous according to Safe Work Australia .
10 Of the chemical:The following health/environmental hazard categories fall outside the scope of the Workplace Health and SafetyRegulations:Eye damage/irritation - Category 2 BPoisons Schedule (SUSMP):S5 product is registered in Australia by the Australian Pesticides & Veterinary Medicines Authority (APVMA).APVMA product number 4851816. OTHER INFORMATIONP roduct Name: Roundup Biactive HerbicideIssued: 14/10/2016 References:Supplier Safety data Sheet ; 09/ No: 000000062004 This Safety data Sheet has been prepared by Ixom Operations Pty Ltd Toxicology & SDS : 1 Reason(s) for Issue:First Issue Primary SDSThis SDS summarises to our best knowledge at the date of issue, the chemical health and Safety hazards of thematerial and general guidance on how to safely handle the material in the workplace.