SAFETY DATA SHEET - Solvent Free Paint

1 SAFETY data SHEET for Linus Wall Paintpage 1(10)P:\64mas2\6706\61670618429\5-A_PROJ \DOK\SDB under arbete\Engelska msds under arbete\ msds Allb ck Linus Wall SAFETY data SHEETI ssue date: 17 Sep. 2012 Supersedes: 10 Feb. 2010 Section 1: Identification of the substance/mixture and of Product identifierLinusWall Relevant identified uses ofthe substance or mixture anduses advised againstFor outdoor and indoor painting. For painting on wood,concrete, wallpaper and other Use- SU:SU19 Building and construction workSU20 Health servicesSU21 Private households (= general public = consumers)SU22 Professional uses: Public domainChemical Product Category: PC9a Coatings and paintsProcess categories[PROC]: PROC10 Roller applicationor brushingEnvironmental Release Categories:ERC 8C Wide dispersive indoor use resulting in inclusioninto or onto a matrix ( Paint )ERC 8F Wide dispersive outdoor use resulting in inclusioninto or onto a matrix ( Paint ) Details of the supplier of thesafety data sheetSupplier/Importer EUAllb ck Linoljeprodukter ABAddress stra Balk krav gen 18SE-271 91 YstadSwedenTelephone number+46-411-606 02 Fax+46-411-602 41 Contact personSonja Allb Emergency telephonenumber24 hours service isavailable at NHS Direct in UK:Phone 0845 46 47 or call 112 or 999 See.

2 Issued byAnn Martens, Ramb ll Sverige AB,+46 (0)10-615 54 47 Section 2: Hazards Classification of the substance or mixtureNot classified as hazardous for health or Label elementsNo hazard label data SHEET for Linus Wall Paintpage 2(10)P:\64mas2\6706\61670618429\5-A_PROJ \DOK\SDB under arbete\Engelska msds under arbete\ msds Allb ck Linus Wall label required according to DSD Interior and exterior minimal build woodstains, category f, VOC < 8 g/l. Limit Phase II, from 2010300 g/l. Eller?" SAFETY data SHEET for professional users available upon request Other hazardsRisk for spontaneous combustion if the linseed oil is absorbed by porous organic material (cottonwaste or rag). This oxidation, which give rise to heat, can happen even at room temperature, butraised temperature increases the 3: Composition/information on MixturesEC-noCAS-noName of acid,manganese salt(only in boiled linseedoil)0,05mg/litrepaintCLP:Skin Irrit2, H315 DSD:Xi; R38-236-675-513463-67-7 REACH-regnr.

3 01-2119489379-17-0021och 01-2119489379-17-0022 Titaniumdioxide0-30 %.Varies withthe (Calciumcarbonate)Varieswiththe colour(4-20 %)-WEL231-791-27732-18-5 Water25-30 %--Differentcolours-236-675-5215-279-613 463-67-71317-65-3 WhiteTitanium dioxideCalcium carbonate27-30 %TitaniumdioxideCalciumcarbonate15-20 %--WELWEL215-277-5215-279-61317-61-91317 -65-3 BlackIron oxide (Fe3O4)Calcium carbonate0 %Titaniumdioxide40-45 %Iron oxide4-5 %-WELS afety data SHEET for Linus Wall Paintpage 3(10)P:\64mas2\6706\61670618429\5-A_PROJ \DOK\SDB under arbete\Engelska msds under arbete\ msds Allb ck Linus Wall redIron oxide (Fe2O3)-WELO ther colours aremixtures of the abovecolours and addedpigment mixture is doneby the %Titaniumdioxide40-45 %Iron oxide4-5 %CalciumcarbonateWELE xplanation of abbreviations:CAS-nr. = Chemical Abstracts Service; EU-nr (Einecs- or Elincsnumber) = European Inventory of Existing Commercial ChemicalSubstances or European LIst of Notified Chemical Substances, DSD = Dangerous Substance Directive.

4 CLP = RegulationClassification and Labelling of specified as; %, %wt/wt, %vol/wt, %vol/vol, mg/m3, ppb, ppm, wt%, vol%.WEL = The product have a workplace exposure limit, PBT = The product is declared since it s a PBT- or a : Linseed oil contains mainly natural triglycerides from oleic, linoleic, cetylic acid,linolenic acid and stearic acid. CAS 8554-56-3 is also possible for linseed product contains % quartz as a natural contaminate in chalk. The amount ofrespirable quartz is very pigments for other colours are distributed as powders for own mixture in the Paint and is notcovered in this risk phrases in plain text, see section 4: First aid of first aidmeasuresInhalationNot relevant, except when spraying the product. Ifirritation occurs, move to fresh air and contactWash the skin withwaterand linseed contactRemove contact lenses. Rinse the eyes for a couple ofminutes. If symptoms persist, seek a copious amountsof milk.

5 The product is a laxativein large amounts, but no risk for intoxication. Do notprovoke Most important symptomsand effects, both acute anddelayedInhalationMay cause some transient irritation to the contactHas no effect on contactProvides transient mild Indication of any immediatemedical attention and specialtreatment neededAccess to waterfor rinsing eyesat the working data SHEET for Linus Wall Paintpage 4(10)P:\64mas2\6706\61670618429\5-A_PROJ \DOK\SDB under arbete\Engelska msds under arbete\ msds Allb ck Linus Wall 5: Firefighting mediaa. Recommended Extinguishingmediab. Not Recommended Extinguishingmediaa. The product does not burn. Extinguish surrounding firewith foam, carbon dioxide, powder or water spraydepending on what is burningb. Foam containing substances that are harmful for theenvironment, Perfluoro octane sulfonate (PFOS) andNonyl hazards arising fromthe substance or for firefightersDo not inhale for fire fighting if necessary.

6 Cool surfacesexposed to the 6: Accidental Personal precautions,protective equipment andemergency non-emergency personnelWash skin orcontaminatedclotheswith ForemergencyrespondersNone Environment precautionsPrevent dischargetothe sewage Methods and material forcontainment and cleaning Surrounding Recommended cleaning Non-recommended measuresMake embankments with sand or otherinert absorbentand collect. Small amounts can be washed away withwater. The product is easily biodegradable in Reference to other sectionsFor personal protection see section 8. For disposal ofwaste, see section 7: Handling and forsafe handlingAvoid spills and prevent large quantities of the product toreach sewage system or surface water. Avoid eating,drinking and smoking in the working area. Wash handsafter using the product. Remove contaminated clothingbefore meals are for safe storage,including any incompatibilitiesStoretheproduct at room temperature.

7 Storeout ofreach of children and away from end use(s)No specific end data SHEET for Linus Wall Paintpage 5(10)P:\64mas2\6706\61670618429\5-A_PROJ \DOK\SDB under arbete\Engelska msds under arbete\ msds Allb ck Linus Wall 8: Exposure controls/personal Control parametersNational occupational exposure limits values, EH 40, 2005 with updatesNo workplace exposure values for linseed nameWEL8 hWEL5 minWEL15 min13463-67-7 Titanium dioxideTotal inhalablerespirable10 mg/m34 mg/m3 Iron oxide, fume (as Fe)5mg/m310 mg/m31317-65-3 Calcium carbonateTotal inhalablerespirable10 mg/m34 mg/m3 WEL=Workplace Exposure LimitPNEC and DNEL/DMEL not established for linseed below are from REACH registration of titanium dioxideCAS-noSubstancePNEC(type ofenvironment)DN(M)EL(route of exposure)Expo-surescen-arioannex13463-67 -7 TitaniumdioxidPNEC (aquafreshwater)0,127 mg/LPNEC (aqua marinewater)1 mg/LPNEC aqua(intermittentreleases)0,61 mg/LPNEC STP100 mg/LPNEC sediment(fresh water)1000 mg/kgSediment dwPNEC sediment(marine water)

8 100 mg/kgsediment DdWorkersLongtime exposure localeffectDNEL Inhalation10 mg/m ConsumersLongtime exposure systemiceffectOral DNEL700 mg/kg bodyweight/dayFor other DNEL/DMEL data ismissingSaknasSafety data SHEET for Linus Wall Paintpage 6(10)P:\64mas2\6706\61670618429\5-A_PROJ \DOK\SDB under arbete\Engelska msds under arbete\ msds Allb ck Linus Wall soil100 mg/kg dwBiologicallimit Exposure Recommended technicalcontrol Individual protectionmeasures, personalprotection equipmentEye/faceprotectionNone when the product,usesafety protectioni) Hand protection (material,thickness, breakthrough time)ii) Other protectioni)None normally necessary. If prolongedcontact with the product use gloves of , PVC or ) Normal working clothes. No specialprotectionRespiratory protectionIf spraying the product and a hazard to surpass anyoccupational exposure value use a half mask with particlefilter exposurelimitsAvoid large leakage to surface water or sewage systemSection 9: Physical and chemical Information on basic physical and chemical propertiesAppearance/Form /StateLiquidOdourCharacteristiclinseed point/freezing pointAppr.

9 0 CInitial boiling point and CFlashpointNot determinedFlammabilityNot flammableUpper/lower flammability orexplosive limitsNot determinedVapourpressureNot determinedVapourdensityNot on the oil will only emulsify in water. Low watersolubility <1 g/l. The product is partly soluble in severalsolvents, but it is not recommended to mix with coefficient n-octanol/waterNot determinedfor linseed oil in the product. Probably >3. Oleic acid that normally is a part of linseed oil with 18- SAFETY data SHEET for Linus Wall Paintpage 7(10)P:\64mas2\6706\61670618429\5-A_PROJ \DOK\SDB under arbete\Engelska msds under arbete\ msds Allb ck Linus Wall % haslog Kow temperatureNot determinedViscosityNot determinedExplosivepropertiesNoneOxidizi ngpropertiesNoneof the substances areclassified as olio can however have on oxidising effect inporous organic material if the water has content< 8 Other informationEmission Factor, Volatile organiccompounds, TVOC64 Njg/(m2xh) after 4 drying time of linseed oilpaint(white Paint ), 18 Njg/(m2xh) after 26 week drying 10: Stability and product is not reactive duringnormal handling andstorage stabilityStable at normal storing of not store above normal room temperature and below+4 acids, bases and oxidizing 11.

10 Toxicological Information on toxicological effectsa) Acute toxicityShort term exposureLinseed oil LD50, rat > 15000 mg/kg body : The product is probably a mild laxative and ingestion of small amounts will not give anysymptomsInhalation: Not relevant. Only a risk when spraying the product. The product could in this casecause minor irritation to respiratory contact: Could cause mild transient irritation if contact with the eyesSkin contact: Gives no effect on the skinLong term exposure:Ingestion: The product is probably a laxative, but adverse effects are not expected if : Not relevant except when spraying the product. The product consumes oxygen whendrying and if the ventilation is insufficient during indoor painting there is a risk of contact: Repeated exposure may cause irritation to the eyes, but will probably not give anyremaining effect on the eye. Not eye contact: Repeated contact might dry the skin and cause irritation or atopic eczema, but duringnormal use the risk is ) Skin corrosion/irritation:The product is not corrosive or irritating to the ) Serious eye damage/irritation: SAFETY data SHEET for Linus Wall Paintpage 8(10)P:\64mas2\6706\61670618429\5-A_PROJ \DOK\SDB under arbete\Engelska msds under arbete\ msds Allb ck Linus Wall product will not give serious eye damage or eye ) Respiratory or skin sensitisation:The product is not sensitizing.