Safety Data Sheet Triethanolamine 99% Tech

1 Safety Data Sheet Triethanolamine 99% Tech Version Revision Date: 10/01/2014 MSDS Number: 100000004531 1 / 21 Triethanolamine 99% Tech SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Triethanolamine 99% Tech Manufacturer or supplier's details Company : Nexeo Solutions LLC Address 3 Waterway Square Place Suite 1000 Woodlands, Tx. 77380 United States of America Emergency telephone number: Health North America: 1-855-NEXEO4U (1-855-639-3648) Health International: 1-855-NEXEO4U (1-855-639-3648) Transport North America: CHEMTREC Additional Infor-mation: : Responsible Party: Product Safety Group E-Mail: SDS Requests: 1-855-429-2661 SDS Requests Fax: 1-281-500-2370 Website: SECTION 2. HAZARDS IDENTIFICATION GHS Classification Skin irritation : Category 2 Eye irritation : Category 2A Carcinogenicity : Category 2 Specific target organ tox-icity - repeated exposure (Oral) : Category 2 (Liver, Blood, Kidney) GHS Label element Hazard pictograms : Signal word : Warning Hazard statements : H315 Causes skin irritation.

2 H319 Causes serious eye irritation. H351 Suspected of causing cancer. H373 May cause damage to organs (Liver, Blood, Kidney) through prolonged or repeated exposure if Safety Data Sheet Triethanolamine 99% Tech Version Revision Date: 10/01/2014 MSDS Number: 100000004531 2 / 21 Triethanolamine 99% Tech swallowed. Precautionary statements : Prevention: P201 Obtain special instructions before use. P202 Do not handle until all Safety precautions have been read and understood. P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. P264 Wash skin thoroughly after handling. P280 Wear eye protection/ face protection. P280 Wear protective gloves. P281 Use personal protective equipment as required. Response: P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.

3 Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P332 + P313 If skin irritation occurs: Get medical advice/ attention. P337 + P313 If eye irritation persists: Get medical advice/ attention. P362 Take off contaminated clothing and wash before reuse. Storage: P405 Store locked up. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. Potential Health Effects Carcinogenicity: IARC Group 2B: Possibly carcinogenic to humans 111-42-2 Diethanolamine ACGIH No component of this product present at levels greater than or equal to is identified as a carcinogen or potential carcinogen by ACGIH. OSHA No component of this product present at levels greater than or equal to is identified as a carcinogen or potential carcinogen by OSHA.

4 NTP No component of this product present at levels greater than or equal to is identified as a known or antici-pated carcinogen by NTP. Safety Data Sheet Triethanolamine 99% Tech Version Revision Date: 10/01/2014 MSDS Number: 100000004531 3 / 21 Triethanolamine 99% Tech Emergency Overview Appearance viscous, liquid Colour light yellow, clear Odour ammoniacal, amine-like Hazard Summary No information available. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous components CAS-No. Chemical Name Concentration (%) 102-71-6 Triethanolamine 90 - 100 111-42-2 Diethanolamine - SECTION 4. FIRST AID MEASURES General advice : Move out of dangerous area. Show this Safety data Sheet to the doctor in attend-ance. Do not leave the victim unattended. If inhaled : If unconscious place in recovery position and seek medical advice.

5 If symptoms persist, call a physician. In case of skin contact : If skin irritation persists, call a physician. If on skin, rinse well with water. If on clothes, remove clothes. In case of eye contact : Immediately flush eye(s) with plenty of water. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. If swallowed : Clean mouth with water and drink afterwards plenty of water. Induce vomiting immediately and call a physician. Keep respiratory tract clear. Do not give milk or alcoholic beverages. Safety Data Sheet Triethanolamine 99% Tech Version Revision Date: 10/01/2014 MSDS Number: 100000004531 4 / 21 Triethanolamine 99% Tech Never give anything by mouth to an unconscious per-son. If symptoms persist, call a physician.

6 Take victim immediately to hospital. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use an extinguishing media appropriate for surround-ing fire. Unsuitable extinguishing media : High volume water jet Hazardous combustion products : Carbon oxides Nitrogen oxides (NOx) Specific extinguishing methods : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Further information : Standard procedure for chemical fires. Special protective equip-ment for firefighters : Wear self-contained breathing apparatus for fire-fighting if necessary. NFPA Flammable and Combustible Liquids Classification: Combustible Liquid Class IIIB SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Use personal protective equipment.

7 Environmental precau-tions : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. Methods and materials for containment and cleaning up : Neutralise with acid. Soak up with inert absorbent material ( sand, sili-ca gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. SECTION 7. HANDLING AND STORAGE Safety Data Sheet Triethanolamine 99% Tech Version Revision Date: 10/01/2014 MSDS Number: 100000004531 5 / 21 Triethanolamine 99% Tech Advice on safe handling : Do not breathe vapours/dust. Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area.

8 Dispose of rinse water in accordance with local and national regulations. Conditions for safe stor-age : Keep container tightly closed in a dry and well-ventilated place. Observe label precautions. Electrical installations / working materials must com-ply with the technological Safety standards. Storage temperature : 86 - 109 C Storage period : 24 Months SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters CAS-No. Components Value type (Form of exposure) Control parame-ters / Permissi-ble concentra-tion Basis 102-71-6 Triethanolamine TWA 5 mg/m3 ACGIH 111-42-2 Diethanolamine TWA (In-halable fraction and vapor) 1 mg/m3 ACGIH TWA 3 ppm 15 mg/m3 NIOSH REL TWA 3 ppm 15 mg/m3 OSHA P0 Personal protective equipment Respiratory protection : No personal respiratory protective equipment normally required.

9 In the case of vapour formation use a respirator with an approved filter. Hand protection Remarks : The suitability for a specific workplace should be dis-cussed with the producers of the protective gloves. Safety Data Sheet Triethanolamine 99% Tech Version Revision Date: 10/01/2014 MSDS Number: 100000004531 6 / 21 Triethanolamine 99% Tech Eye protection : Eye wash bottle with pure water Tightly fitting Safety goggles Wear face-shield and protective suit for abnormal pro-cessing problems. Skin and body protection : impervious clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place. Hygiene measures : When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : viscous, liquid Colour : light yellow, clear Odour : ammoniacal, amine-like Odour Threshold : No data available pH : - 11 @ 2 % Freezing Point (Melting point/freezing point) : C ( F) Boiling Point (Boiling point/boiling range) : - 340 C ( - 644 F) (1013 hPa) Flash point : 179 - C (354 - F) Evaporation rate : n-Butyl Acetate Flammability (solid, gas) : No data available Burning rate : No data available Upper explosion limit : %(V) Lower explosion limit : - %(V) Vapour pressure : mmHg @ 21 C (70 F) Safety Data Sheet Triethanolamine 99% Tech Version Revision Date: 10/01/2014 MSDS Number: 100000004531 7 / 21 Triethanolamine 99% Tech Relative vapour density : 5 Relative density.

10 @ 20 C (68 F) Reference substance: (water = 1) Density : g/cm3 @ 20 C (68 F) Bulk density : No data available Solubility(ies) Water solubility : 1,000 g/l completely miscible @ 20 C (68 F) Solubility in other sol-vents : No data available Partition coefficient: n-octanol/water : log Pow: Auto-ignition temperature : 324 - 350 C Thermal decomposition : > 120 C Viscosity Viscosity, dynamic : 934 @ 20 C (68 F) Viscosity, kinematic : 934 mm2/s @ 20 C (68 F) Explosive properties : Not explosive SECTION 10. STABILITY AND REACTIVITY Reactivity : No decomposition if stored and applied as directed. Chemical stability : Stable under normal conditions. Possibility of hazardous reactions : No hazards to be specially mentioned. Conditions to avoid : elevated temperatures Possible emission of gaseous decomposition products may lead to a dangerous pressure build-up.