SAFETY DATA SHEET - Valero

1 SAFETY data SHEET1. IdentificationProduct identifierCondensed Distillers SolublesOther means of identificationNot , CDSR ecommended useNot restrictionsNone informationManufacturer/SupplierValero Marketing & Supply Company and AffiliatesOne Valero WaySan Antonio, TX 78269-6000 General PersonIndustrial HygienistEmergency Telephone24 Hour Emergency 866-565-52201-800-424-9300 (CHEMTREC USA)2. Hazard(s) identificationNot hazardsNot hazardsNot defined hazardsLabel symbolSignal wordNot statementNot statementPreventionObserve good industrial hygiene hands after container tightly of waste and residues in accordance with local authority (s) not otherwiseclassified (HNOC)None Composition/information on ingredientsSubstancesN/A100 Condensed Distillers SolublesCAS numberCommon name andsynonyms%Chemical nameComposition commentsAll concentrations are in percent by weight unless ingredient is a gas.

2 Gas concentrations are inpercent by First-aid measuresInhalationIf symptomatic, move to fresh air. Get medical attention if symptoms contactImmediately flush with plenty of water for at least 15 minutes while removing contaminated clothingand shoes. If skin irritation or an allergic skin reaction develops, get medical attention. Washcontaminated clothing before contactAny material that contacts the eye should be washed out immediately with water. If easy to do,remove contact lenses. Get medical attention promptly if symptoms occur after medical attention if discomfort Distillers SolublesPrepared by 3E Company915037 Version #: 01 Revison date: 28-May-2014 Print date: 28-May-20141 / 5 Most importantsymptoms/effects, acute anddelayedIrritant Fire-fighting measuresSuitable extinguishing mediaWater spray.

3 Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).Unsuitable extinguishingmediaNone hazards arising fromthe chemicalNone protective equipmentand precautions for firefightersNot protective equipment appropriate for surrounding Accidental release measuresPersonal precautions,protective equipment andemergency proceduresWear appropriate personal protective equipment (See Section 8).Methods and materials forcontainment and cleaning upFlush area with water. Prevent runoff from entering drains, sewers, or streams. Dike for Handling and storagePrecautions for safe handlingAvoid contact with eyes, skin, and clothing. Wash thoroughly after handling. Observe goodindustrial hygiene for safe storage,including any incompatibilitiesKeep container closed. Protect from light. Store in a cool Exposure controls/personal protectionOccupational exposure limitsNo exposure limits noted for ingredient(s).

4 Biological limit valuesNo biological exposure limits noted for the ingredient(s).Exposure guidelinesNo exposure standards engineeringcontrolsEnsure adequate ventilation, especially in confined protection measures, such as personal protective equipmentEye/face protectionWear SAFETY glasses with side shields (or goggles).Skin protectionHand protectionWear chemical-resistant, impervious protective clothing appropriate for the risk of protectionIf engineering controls do not maintain airborne concentrations below recommended exposurelimits (where applicable) or to an acceptable level (in countries where exposure limits have notbeen established), an approved respirator must be worn. In the United States of America, ifrespirators are used, a program should be instituted to assure compliance with OSHA 29 Respirator type: Use NIOSH approved respirator with organic vapor/acid gas hazardsNot hygieneconsiderationsAlways observe good personal hygiene measures, such as washing after handling the materialand before eating, drinking, and/or smoking.

5 Routinely wash work clothing and protectiveequipment to remove Physical and chemical propertiesAppearanceTan thresholdNot point/freezing pointNot Distillers SolublesPrepared by 3E Company915037 Version #: 01 Revison date: 28-May-2014 Print date: 28-May-20142 / 5 Initial boiling point and boilingrangeNot pointNot rateNot (solid, gas)Not flammability or explosive limitsFlammability limit - lower(%)Not limit - upper(%)Not limit - lower (%)Not limit - upper (%)Not pressureNot densityNot densityNot (ies)Solubility (water)Not coefficient(n-octanol/water)Not temperatureNot temperatureNot informationMoisture (% by Wt.): ~ 60%Weighted solids~40%10. Stability and reactivityReactivityNot stabilityMaterial is stable under normal of hazardousreactionsHazardous polymerization does not to avoidAvoid contact with strong oxidizing materialsStrong oxidizing decompositionproductsNo hazardous decomposition products are Toxicological informationInformation on likely routes of exposureIngestionNo harmful effects expected in amounts likely to be ingested by normal conditions of intended use, this material is not expected to be an inhalation contactProlonged or repeated contact may dry skin and cause contactDirect contact with eyes may cause temporary related to thephysical, chemical andtoxicological characteristicsIrritant on toxicological effectsAcute toxicityBased on available data .

6 The classification criteria are not corrosion/irritationBased on available data , the classification criteria are not eye damage/eyeirritationBased on available data , the classification criteria are not or skin sensitizationRespiratory sensitizationBased on available data , the classification criteria are not sensitizationProlonged and repeated exposure may increase the risk of more serious skin disorders such asdermatitis and Distillers SolublesPrepared by 3E Company915037 Version #: 01 Revison date: 28-May-2014 Print date: 28-May-20143 / 5 Germ cell mutagenicityBased on available data , the classification criteria are not product is not considered to be a carcinogen by IARC, ACGIH, NTP, or toxicityBased on available data , the classification criteria are not target organ toxicity -single exposureBased on available data , the classification criteria are not target organ toxicity -repeated exposureBased on available data , the classification criteria are not hazardBased on available data .

7 The classification criteria are not Ecological informationEcotoxicityNot expected to be harmful to aquatic and degradabilityThe product is expected to be potentialThe product is not expected to in soilNot adverse effectsNot Disposal considerationsDisposal instructionsDispose of contents/container in accordance with local/regional/national/international waste codeNot from residues / unusedproductsDispose of in accordance with local packagingSince emptied containers may retain product residue, follow label warnings even after container Transport informationDOTNot regulated as dangerous regulated as dangerous regulated as dangerous in bulk according toAnnex II of MARPOL 73/78 andthe IBC Code15. Regulatory informationUS federal regulationsThis product is not hazardous according to OSHA 29 CFR Section 12(b) Export Notification (40 CFR 707, Subpt.)

8 D)Not OSHA Specifically Regulated Substances (29 CFR )Not Hazardous Substance List (40 CFR )Not Amendments and Reauthorization Act of 1986 (SARA)Hazard categoriesImmediate Hazard - NoDelayed Hazard - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - NoSARA 302 Extremely hazardous substanceNot 311/312 HazardouschemicalNoSARA 313 (TRI reporting)Not Distillers SolublesPrepared by 3E Company915037 Version #: 01 Revison date: 28-May-2014 Print date: 28-May-20144 / 5 Other federal regulationsClean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) ListNot Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR )Not Drinking Water Act(SDWA)Not state regulationsThis product does not contain a chemical known to the State of California to cause cancer, birthdefects or other reproductive Massachusetts RTK - Substance ListNot New Jersey Worker and Community Right-to-Know ActNot Pennsylvania Worker and Community Right-to-Know LawNot Rhode Island RTKNot California Proposition 65US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT).

9 Listed substanceNot Other information, including date of preparation or last revisionIssue date28-May-2014 Revision date-Version #01 Further informationHMIS is a registered trade and service mark of the Ratings010 ReferencesEPA: AQUIRE databaseUS. IARC Monographs on Occupational Exposures to Chemical AgentsHSDB - Hazardous Substances data BankNational Toxicology Program (NTP) Report on CarcinogensACGIH Documentation of the Threshold Limit Values and Biological Exposure IndicesDisclaimerThis material SAFETY data SHEET (SDS) was prepared in accordance with 29 CFR byValero Marketing & Supply Co., (" Valero "). Valero does not assume any liability arising out ofproduct use by others. The information, recommendations, and suggestions presented in this SDSare based upon test results and data believed to be reliable.

10 The end user of the product has theresponsibility for evaluating the adequacy of the data under the conditions of use, determining thesafety, toxicity and suitability of the product under these conditions, and obtaining additional orclarifying information where uncertainty exists. No guarantee expressed or implied is made as tothe effects of such use , the results to be obtained, or the SAFETY and toxicity of the product in anyspecific application. Furthermore, the information herein is not represented as absolutelycomplete, since it is not practicable to provide all the scientific and study information in the formatof this document, plus additional information may be necessary under exceptional conditions ofuse, or because of applicable laws or government Distillers SolublesPrepared by 3E Company915037 Version #: 01 Revison date: 28-May-2014 Print date: 28-May-20145 / 5