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SAFETY DATA SHEET - Valero Energy

SAFETY data SHEET1. IdentificationProduct identifierUNLEADED GASOLINEO ther means of identificationSDS number002-GHSS ynonymsRegular/Premium/Midgrade - Unleaded Gasoline, RFG - Reformulated Unleaded Gasoline,Conventional Unleaded Gasoline, Oxygenated Unleaded Gasoline, Non-Oxygenated UnleadedGasoline, CARB (California Air Resource Board) Unleaded Gasoline, RBOB - ReformulatedBlendstock for Oxygenate Blending, CBOB - Conventional Blendstock for Oxygenate Blending,Petrol, Motor section 16 for complete useMotor FuelMotor restrictionsNone informationManufacturer/SupplierValero Marketing & Supply Company and AffiliatesOne Valero WaySan Antonio, TX 78269-6000 General PersonIndustrial HygienistEmergency Telephone24 Hour Emergency 866-565-52201-800-424-9300 (CHEMTREC USA)2.

dizziness. May cause damage to organs (blood, liver, kidney) through prolonged or repeated exposure. May be fatal if swallowed and enters airways. Toxic to aquatic life with long lasting effects. UNLEADED GASOLINE Prepared by 3E Company 913457 Version #: 03 Revison date: 23-May-2014 Print date: 23-May-2014 1 / 15

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Transcription of SAFETY DATA SHEET - Valero Energy

1 SAFETY data SHEET1. IdentificationProduct identifierUNLEADED GASOLINEO ther means of identificationSDS number002-GHSS ynonymsRegular/Premium/Midgrade - Unleaded Gasoline, RFG - Reformulated Unleaded Gasoline,Conventional Unleaded Gasoline, Oxygenated Unleaded Gasoline, Non-Oxygenated UnleadedGasoline, CARB (California Air Resource Board) Unleaded Gasoline, RBOB - ReformulatedBlendstock for Oxygenate Blending, CBOB - Conventional Blendstock for Oxygenate Blending,Petrol, Motor section 16 for complete useMotor FuelMotor restrictionsNone informationManufacturer/SupplierValero Marketing & Supply Company and AffiliatesOne Valero WaySan Antonio, TX 78269-6000 General PersonIndustrial HygienistEmergency Telephone24 Hour Emergency 866-565-52201-800-424-9300 (CHEMTREC USA)2.

2 Hazard(s) identificationCategory 1 Flammable liquidsPhysical hazardsCategory 2 Skin corrosion/irritationHealth hazardsCategory 1 BGerm cell mutagenicityCategory 1 BCarcinogenicityCategory 2 Reproductive toxicityCategory 3 narcotic effectsSpecific target organ toxicity, single exposureCategory 2 Specific target organ toxicity, repeatedexposureCategory 1 Aspiration hazardCategory 2 Hazardous to the aquatic environment,long-term hazardEnvironmental hazardsNot defined hazardsLabel elementsSignal wordDangerHazard statementExtremely flammable liquid and vapor. Causes skin irritation. May cause genetic defects. Maycause cancer. Suspected of damaging fertility or the unborn child.

3 May cause drowsiness ordizziness. May cause damage to organs ( blood , liver, kidney) through prolonged or repeatedexposure. May be fatal if swallowed and enters airways. Toxic to aquatic life with long GASOLINEP repared by 3E Company913457 Version #: 03 Revison date: 23-May-2014 Print date: 23-May-20141 / 15 Precautionary statementPreventionObtain special instructions before use. Do not handle until all SAFETY precautions have been readand understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keepcontainer tightly closed. Ground/bond container and receiving equipment. Use explosion-proofelectrical/ventilating/li ghting// equipment.

4 Use only non-sparking tools. Take precautionarymeasures against static discharge. Do not breathe gas/mist/vapors/spray. Wash thoroughly afterhandling. Wear protective gloves/protective clothing/eye protection/face protection. Use onlyoutdoors or in a well-ventilated area. Avoid release to the exposed or concerned: Get medical advice/attention. If inhaled: Remove person to fresh air andkeep comfortable for breathing. If swallowed: Immediately call a poison center/doctor. Do NOTinduce vomiting. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skinwith water/shower. If skin irritation occurs: Get medical advice/attention. In case of fire: Usealcohol-resistant foam, carbon dioxide, dry powder or water fog for extinction.

5 Collect locked up. Store in a well-ventilated place. Keep container tightly closed. Keep of contents/container in accordance with local/regional/national/international (s) not otherwiseclassified (HNOC)None Composition/information on ingredientsMixtures86290-81-580-100 GasolineCAS number%Chemical name108-88-30-30 Toluene96-14-05-25 Hexane (Other Isomers)1330-20-70-25 Xylene (o, m, p isomers) (All isomers)64-17-50-10 Ethanol95-63-60-61,2,4, First-aid measuresInhalationMove to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Getmedical contactRemove contaminated clothing and shoes. Wash off immediately with soap and plenty of medical attention if irritation develops or persists.

6 Wash clothing separately before or thoroughly clean contaminated shoes. If high pressure injection under the skin occurs,always seek medical contactImmediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing. Get medical mouth thoroughly. Do not induce vomiting without advice from poison control center. Do notgive mouth-to-mouth resuscitation. If vomiting occurs, keep head low so that stomach contentdoes not get into the lungs. Never give anything by mouth to a victim who is unconscious or ishaving convulsions. Get medical attention importantsymptoms/effects, acute anddelayedIrritation of nose and throat.

7 Irritation of eyes and mucous membranes. Skin Corneal damage. Narcosis. Cyanosis (blue tissue condition, nails, lips, and/orskin). Decrease in motor functions. Behavioral changes. Edema. Liver enlargement. Proteinuria. Defatting of the skin. GASOLINEP repared by 3E Company913457 Version #: 03 Revison date: 23-May-2014 Print date: 23-May-20142 / 15 Indication of immediatemedical attention and specialtreatment neededIn case of shortness of breath, give oxygen. Keep victim warm. Keep victim under may be informationIf exposed or concerned: get medical attention/advice. Ensure that medical personnel are aware ofthe material(s) involved, and take precautions to protect themselves.

8 Show this SAFETY data sheetto the doctor in attendance. Wash contaminated clothing before Fire-fighting measuresSuitable extinguishing mediaWater spray. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).Unsuitable extinguishingmediaDo not use a solid water stream as it may scatter and spread hazards arising fromthe chemicalVapor may cause flash fire. Vapors can flow along surfaces to distant ignition source and flashback. Sensitive to static protective equipmentand precautions for firefightersWear full protective clothing, including helmet, self-contained positive pressure or pressuredemand breathing apparatus, protective clothing and face full protective clothing, including helmet, self-contained positive pressure or pressuredemand breathing apparatus, protective clothing and face mask.

9 Withdraw immediately in case ofrising sound from venting SAFETY devices or any discoloration of tanks due to fire. Fight fire frommaximum distance or use unmanned hose holders or monitor nozzles. Move containers from firearea if you can do it without risk. In the event of fire, cool tanks with water spray. Cool containersexposed to flames with water until well after the fire is out. For massive fire, use unmanned hoseholders or monitor nozzles; if this is impossible, withdraw from area and let fire burn. Vapors mayform explosive air mixtures even at room temperature. Prevent buildup of vapors or gases toexplosive concentrations. Some of these materials, if spilled, may evaporate leaving a flammableresidue.

10 Water runoff can cause environmental damage. Use compatible foam to minimize vaporgeneration as methodsUse water spray to cool unopened fire hazardsExtremely flammable liquid and vapor. Containers may explode when Accidental release measuresPersonal precautions,protective equipment andemergency proceduresKeep unnecessary personnel away. Local authorities should be advised if significant spills cannotbe contained. Keep upwind. Keep out of low areas. Ventilate closed spaces before entering. Donot touch damaged containers or spilled material unless wearing appropriate protective Section 8 of the SDS for Personal Protective and materials forcontainment and cleaning upEliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area).


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