SIPOMER® Novecare Specialty Monomers For ... - …

1 SIPOMER Specialty MonomersFor enhanced performanceNovecareCommitted to YOUR coatings successNovecare Coatings is a global leader in surfactant and Specialty Monomers committed to emulsion and Specialty polymers. With over 40 years serving this industry, we have developed one of the most extensive portfolios of Specialty Monomers (SIPOMER ) dedicated to improve architectural, industrial coatings and adhesives. Leveraging our portfolio of chemistries and local application expertise, we continue designing structures that will help you solve today s challenges and define tomorrow s standards. Solvay Novecare CoatingsNovecare Coatings / 1 CONTENTSP rocess / Adhesion / Surface Properties.

2 Page 4w SIPOMER PAM 100w SIPOMER PAM 200w SIPOMER PAM 300w SIPOMER PAM 4000w SIPOMER PAM 5000 Polymerizable Stabilizers ..Page 16w SIPOMER COPS-1w SIPOMER COPS-3w SIPOMER AES-100w SIPOMER AAE 10 Wet Adhesion, Alkyd / Wood Adhesion ..Page 20w SIPOMER WAMw SIPOMER WAM IIw SIPOMER WAM E W50w SIPOMER WAM E MMA25w SIPOMER WAM E MMA50 Resin Modifiers ..Page 28w SIPOMER IBOMA Hardness w SIPOMER IBOA Hardnessw SIPOMER -CEA Cohesive strengthRheology ..Page 29w SIPOMER BEMw SIPOMER SEM 25w SIPOMER HPM seriesNote: These products are produced at worldwide locations through through the Novecare division of / Specialty MonomersSIPOMER So little delivers so much SIPOMER s are very efficient.

3 In most application, addition of to 3% of these Monomers deliver significant performance and bring functionality to your polymers. By leveraging our diverse chemistry platforms, Solvay designs solutions adapted to both monomer systems and formulation performance . Whether your formulation is waterborne, solventborne or you seek support in transitioning towards waterborne, SIPOMER will deliver in the following properties: From Technology to SolutionsProcessSurface PropertiesAdhesionMechanicalProperties Clean EP Process Improved mechanical, thermal & salt stability Limit foaming High Scrub Gloss Low water sensitivity EZ Clean Scratch resistance Wet Adhesion Metal & Inorganic Wood Interaction with Pigments Tg depletion Tg Increase Peel StrengthSIPOMER s / 34 / Specialty MonomersSIPOMER PAM Adhesion and Much More performance Benefits w Improves binder robustness w Adhesion to metal w Adhesion to inorganic substratew Adhesion to glass w Scrub resistance w Color developmentw Gloss enhancementReactive GroupNature of Extender Application SIPOMER PAM 100 MethacrylateHydrophilicIndustrial SIPOMER PAM 200 MethacrylateHydrophobicIndustrial/ Architectural / Adhesive SIPOMER PAM 300 Acrylate

4 HydrophobicUV/EB Cure SIPOMER PAM 4000 Methacrylate~ArchitecturalSIPOMER PAM 5000 Allyl EtherSlightly PAM200 control After 2000 scrub cyclesConcreteConcreteApplications to 1 wt% PHM000H0 HPExtenderPhosphate groupPolymerizablegroupSIPOMER PAM / 5 Uses SIPOMER PAMs are available in a variety of structures compatible with most coatings chemistries, technologies and applications. Effective in Different Polymer SystemsEffective on a Variety of Substratesw Acrylicw Styrene/acrylicw VeoVa/acrylicw Vinyl VeoVAw Polyurethane (via acrylic polyols)w Aluminium (plain and chromated)w Cold rolled steelw Zinc phosphated steelw Iron phosphated steelw Galvanized steelw Stainless steelw Glassw ConcreteSIPOMER PAM Adhesion and Much More Technologies for different marketsSIPOMER PAM in various resins by either emulsion or solution PAM-100 SIPOMER PAM-200 SIPOMER PAM-300 SIPOMER PAM-4000 SIPOMER PAM-5000 EMULSION POLYMERIZATION> You want to add the phosphate monomer with no other modification to an existing latex PAM-100 can be addedto the monomer feed in acidic form or to a separate feed inneutralized to its surfactantcy properties,SIPOMER PAM-200 may generateproblems such as to its surfactantcy properties.

5 SIPOMER PAM-300 may generateproblems such as PAM 4000 is perfectly suited to be used in monomer mixSIPOMER PAM 5000 is perfectly suited to be used in monomer mix> You want to minimize or or eliminate the primary surfactant.*reduce the total amount of surfactant needed* cannot beused as a primary drastically the use of surfactant or may be used as the sole surfactant in drastically the use of surfactant or may be used as the sole surfactant in emulsionpolymerization.*reduce the total amount of surfactant needed*cannot beused as a primary surfactant.*reduce the total amount of surfactant needed*cannot beused as a primary surfactant.> You want to stabilize a pre-emulsion without any conventional Surface activeSIPOMER PAM-200 may be used as a sole emulsifer to PAM-300 may be used as a sole emulsifer to Surface active Not Surface active SOLUTION POLYMERIZATION> Water solubleSIPOMER PAM-100 is morehydrophilic and totally solublein water when to poor solubility in water,using SIPOMER PAM-200 maylead to micellar to poor solubility in water,using SIPOMER PAM 300 maylead to micellar SolubleWater Soluble> Solventborne (Polyacrylate )

6 SIPOMER PAM-100 can be used tomake resins but might havecompatibility issues with PAM-200 is soluble ina broad range of monomersand PAM-300 is soluble ina broad range of Monomers and solvents and suitable for UV/EB CureUV/EB cureThe acrylic functionality of SIPOMER PAM-300 provides a higher reactivity in radiation cure application n Best n Possible n Not suitable 6 / Specialty MonomersALUMINUMIMMERSION HOURS DRY 2 4 Control1B0B0B1% PAM 3-4B0B0B4% PAM5B0B0 BCOLD-ROLLED STEELIMMERSION HOURS DRY 2 482448 Control5B4-5B2B0B0B0B1% PAM 5B2B2B1B0B0B4% PAM5B5B5B5B4-5B4-5 BAdhesion is evaluated according to ASTM D3359 test: OB poor adhesion - 5B perfect : Car Refinish: More cars coated with fewer problemsDirect-to-metal substrates represent a significant field for innovation yielding process simplification and environmentally friendly solutions such as: w Direct-to-metal priming that consolidates a complex process into one step w Shift from solventborne to waterborne resin systemsStandard primers for car refinishing are based on 2K polyurethanesolventborne resin systems.

7 Either SIPOMER PAM-100 or SIPOMER PAM-200, based on the formulation and technology used, will be effective in improving metal adhesion of such Data in 2K Polyurethane Solventborne Systems SIPOMER PAM-200 can significantly improve the dry and wet adhesion on both aluminum and cold-rolled steel. SIPOMER PAM is used to make acrylic to their superior MAP/DAP ratio, SIPOMER PAM-100 and SIPOMER PAM-200 are easily incorporated into polyurethane systems with minimum impact on viscosity. SIPOMER PAM 200 can be used in polyurethane waterborne systems where it provides improved adhesion with system and stabilization PAM / 7 Example: Coil Coating: Improved efficiency and environmentally friendlyCoil coating is a continuous and highly automated process whereas the metal coil is unwound and both the top and bottom sides are cleaned, chemically treated, primed, oven cured, top coated, oven cured again, and rewound for shipment.

8 Thanks to this process, large coils can be coated at high speed before fabrication. Resins incorporating SIPOMER PAMs will boost primer adhesion and anti-corrosion properties eliminating the need for pre-treatment step(s) translating into less waste, energy & process coatPrimerPre-treatmentMetalTop coatTreating PrimerMetalStandard Removal of Pre-treatment100%89%100%75%50%25%0 Coil-Coating Cost ($)Standard SystemRemoval of Pre-treatmentBenefits :w Process savings: one step vs. two stepsw Eliminate waste treatment and reporting/regulation requirements Linked to the use of heavy metals such as chrome and PAM Adhesion and Much More Automotive Refinish: Direct-to-Metal (DTM) BenefitsReady-to-apply top coat with DTM primer in 30 minutes instead of 12 hours with standard systemsClear coatTop coatPrimerPre-treatmentMetalClear coatTop coatTreating PrimerMetallateM ot tceriDmetsyS dradnatS100%92%100%75%50%25%0 Coating Cost ($)Standard SystemDirect to Metal8 / Specialty MonomersExample: Maintenance Coatings: An environmental solution that works!

9 Organic coatings play an important role in corrosion protection. One of the key challenges to convert solventborne systems to more sustainable, water-based formulation resides in significant loss in adhesion and anticorrosion to it s excellence in metal adhesion, SIPOMER PAM-200 boosts the performance of acrylic waterborne resins enabling matching performance versus solventborne anticorrosion coatings, allowing low VOC coatings formulations and consumers who are demanding new products that meet or exceed the requirements for lower VOC Adhesion ResultsSIPOMER PAM-200 was used to modify a waterborne styrene/acrylic resin. An anticorrosion paint was formulated and tested for adhesion and corrosion-resistance properties.

10 Compared with a control paint formulated without SIPOMER PAM-200, the results are below:Good Anti-Corrosion ResultsPAINT-BASED ON S/ALATEX WITH 1%PAINT-BASED ON S/ACONTROL LATEXS/A: Styrene/AcrylicAdhesion is evaluatedaccording to ASTM D3359test: 0B poor adhesion 5B perfect is evaluated after 24 hours and after 520 hours of immersion in RESULTSAFTER WATER IMMERSIONCROSSHATCH RESULTSAFTER WATER IMMERSION24 hrs520 hrs24 hrs520 hrs> Cold-rolled steel5B5B4B2B> Iron phosphate steel5B5B1B1B> Zinc phosphate steel3B3B0B0 BSIPOMER PAM / 9 Special-Purpose Coatings: Improved performance and efficiencyThis segment includes coatings for various metal substrates mainly applied by Original Equipment Manufacturers.