Supplementary document JP

1 GHS .. 1..1..1..2..2. 2 ..3. 2-3-6 ..3. 2-3-9 UNRTDG GHS ..4. 2-4-2 / ( ) ..6..7. 3..8. 3-3-1 ..8. 3-3-2 / .. 11. 3-3-3 / ..12. 3-3-4 ..14. 3-3-5 ..15. 3-3-6 ..16. 3-3-7 ..17. 3-3-8 ( ) ..18. 3-3-9 ( ) ..19. 3-3-10 ..20. 4..21. 4-3-1 ( ) ..21. 4-3-2 ..25. ( 25 ).. GHS . 1.. GHS ( ) . GHS .. JIS Z7252:2014 JIS Z7253:2012 ( 25. ) GHS . GHS GHS .. GHS 4 ( UN) .. ( JIS) .. UN. GHS GHS . GHS 4 (2011 ) . JIS Z 7253:2012. GHS . (SDS) . JIS. GHS GHS 4 (2011 ) . GHS (Building block approach ) JIS Z7252:2014 GHS.. JIS Z 7253:2012 GHS . (SDS) . JIS Z 7252:2014 GHS . GHS ( 25 ) . 1. GHS .. (1) 100% .. (2) 100% .. (3) . ( ) (1) . ( ) (1),(2) .. GHS . ( 3500 ) 2.

2 GHS .. 2. GHS . 2 . 2-3-6 p19 . 2-3-6-1( ) . GHS 4 . GHS (JIS Z 7252:2009) .. 2-3-6-1( ) .. 2-4-1 . 2-4-2 ( ) . 2-4-3 . 2-4-4 . 2-4-5 . 2-4-6 . 2-4-7 . 2-4-8 . 2-4-9 . 2-4-10 . 2-4-11 . 2-4-12 . 2-4-13 . 2-4-14 . 2-4-15 . 2-4-16 .. 3. GHS . 2-3-9 UNRTDG GHS (p25). UNRTDG ( ) GHS. GHS . UNRTTDG .. 2-3-9-1( ) GHS UNRTDG .. GHS GHS . ( () ).. ( ) 1 . ( ). 2. - A. - B. ( ). 1 . UN1950(aerosol). ( ). 2. UN1950(aerosol). 3. UN1950(aerosol). ( ) ( ) 1 .. 3 1. 3 2 . 3 3. ( 60 ) 4. 1.. 2. ( ). 4. GHS . ( () . GHS GHS . ). 8 A. UN3221,3222,3231,3232 B. UN3223,3224,3233,3234 C. UN3225,3226,3235,3236 D . UN3227,3228,3237,3238 E. UN3229,3230,3239,3240 F. G.

3 9 . ( ) 1.. 10 . ( ) 1.. 11 1.. 2. 12 ( ) 1.. 2.. 3. 13 ( ) 1.. ( ) 2.. ( ) 3. 14 ( ) 1.. ( ) 2.. ( ) 3. 15 A. UN3101,3102,3111,3112 B. UN3103,3104,3113,3114 C. UN3105,3106,3115,3116 D . UN3107,3108,3117,3118 E. UN3109,3110,3119,3120 F. G. 16 8 . 1.. 5. GHS . 2-4-2 / ( ) (p40). (6) (p42).. 1 2 1 2 . 1 .. n Vi %. i T. ci Vi% . Tci .. (Tci ISO 10156: 2010 Table 2 ). i i . n . Ki . (Ki ISO 10156: 2010 Table 1 ). Tc 1 / .. Tc<1 Tct2 1 . 1 .. Ai: ( ). Li: . ISO10156 2010 . 6. GHS .. 7. GHS .. 3. (p117). 3-3-1 (p117). ( ) .. (5) (p128).. 1% 1% .. 1 2 . 1 2 GHS .. (6) (p131). 3-1-1 3-1-2 . ATE 3-3-1-1( ) . 5 GHS . ppm mg/L 2 ( ) ppm . ppm mg/L 2 . 5 ( ).

4 ( ) ( ) . 3-3-1-1( ) (ATE) . 1 2 3 4 5.. ATE 5 5 ATE 50 50 ATE 300 300 ATE 2000 2000 ATE 5000. (mg/kg ).. ATE 50 50 ATE 200 200 ATE 1000 1000 ATE 2000 2000 ATE 5000. (mg/kg ).. ATE 100 100 ATE 500 500 ATE 2500 2500 ATE 20000 20000 ATE 50000. (ppmV).. ATE ATE ATE 10 10 ATE 20 20 ATE 50. (mg/ ).. ATE ATE ATE ATE ATE (mg/L). ATE . (a) LD50 ( ) LC50( ) . (b) 3-3-1-2( ) . (c) 3-3-1-2( ) . 8. GHS . 3-3-1-2( ) .. (Conversion Value). 0 1 5 5 2 50 5. 50 3 300 100. (mg/kg ) 300 4 2000 500. 2000 5 5000 2500. 5000 . 0 1 50 5. 50 2 200 50. 200 3 1000 300. (mg/kg ) 1000 4 2000 1100. 2000 5 5000 2500. 5000 . 0 1 100 10. 100 2 500 100. 500 3 2500 700. (ppmV) 2500 4 20000 4500.

5 20000 1 5 50000 1 25000 2. 50000 . 0 1 2 3 3. (mg/ l) 4 11. 1 5 1 25 2.. 0 1 2 / 3 (mg/ l) 4 1 5 1 2.. 1 GHS 4 . 5 4 .. 2 GHS 5 . 5 /10 . A) . ATEmix ATEmix .. n ATEmix ATE. 100 Ci Ci i . ( 3-1-1). ATEmix i 1 ATEi ATEi i ATE. n i 1 n . B) 1 . b) .. x% .. 9. GHS . c) 10% . 3-1-2 ( ).. a b . 100 C unknown if 10% n Ci . ( 3-1-2) ATEmix i 1 ATEi C unknown if >10% 10 % . ATEmix ATE. ATEi i ATE. Ci i . n (i 1 n ).. 5 JIS 5 .. 10. GHS . 3-3-2 / (p134). / .. (5) (p143). / C .. C .. 1% 1% .. 1 GHS GHS . 2 3 1% .. 3-3-2-3( ) . 3-3-2-3( ) ( ).. 1 2 3. 1 5 % 5 % 1 %. 2 10 % 10 % 1 %. 3 10 %. (10 1) 2 10 % 10 % 1 %. (10 1) 2 3 10 %. 1A 1B 1C 5 1A . 5 1A+1B 5 1B 1A+1B.

6 5 1A+1B+1C 5 1C . 1 5% . 1 .. 3 JIS 3 .. 11. GHS . 3-3-3 / (p147). / .. (5) P157 . / C .. C) . / .. 1% 1% . / .. 1 GHS GHS .. / .. 3-3-3-3 .. 3-3-3-3 ( ).. 1 2 2. 1 3 % 3 % 1 %. 2 2A 10 %. (10 1) 2 2A 10%. 1 1 1 3 % 3 % 1 %. 10 ( 1 1) 2A 2B 10 %. 1 1 1 . 2 2 2A 2B . 2B . D .. 1 % .. GHS 4 .. 12. GHS . 3-3-3-4 . 3-3-3-4 .. pH 2 1 % 1. pH 1 % 1. ( 1) 1 % 1. ( 2) . 3 % 2. ( ). (4) .. 13. GHS . 3-3-4 (p161).. (5) (P168). C .. C) .. 3-3-4-5 .. GHS 3-3-4-5 .. 3-3-4-5 .. 1 % % . 1A % % . 1B % % . 1 %. 1A %. 1B %.. 100% .. 14. GHS . 3-3-5 (p170).. (5) (P182).. 1 1 2 . 1 2 3-3-5-3 .. 3-3-5-3 .. 1. 2. 1A 1B. 1A % . 1B % . 2 %. NITE 1 .. 15. GHS . 3-3-6 (p184).

7 (5) (P191).. A) . A) . 1 2 . 1 2 3-3-6-3 .. 3-6-2 .. 1. 2. 1A 1B. 1A % . 1B % . 2 %. (NITE) 1 .. 16. GHS . 3-3-7 (p193).. (5) (P203).. A) . A) .. 1) 1 2 1 . 2 3-3-7-3 .. 2) . 3-3-7-3 .. GHS 4 . 3-3-7-3 .. 1 . 2. 1A 1B .. % . 1A.. % . 1B. 2 % .. %.. NITE 1 .. 17. GHS . 3-3-8 ( ) (p205). ( ) .. (6) (P214). ( ) .. C . C) .. ( ) . 1) 1 2 1 2 . 3-3-8-3 .. 2) .. GHS 4 2 JIS 10 . 3-3-8-3 1 2 .. 1 2. 1 10 % % 10 %. 2 10 %. F) 3 . 3 . 20 % 3 .. 18. GHS . 3-3-9 ( ) (p217). ( ) .. (5) P224 . C) .. ( ) . 1) 1 2 1 2 . 3-3-9-3 .. 2) .. GHS 4 2 JIS 10 . 3-3-9-3 .. 1 2. 1 10 % % 10 %. 2 10 %.. C .. 19. GHS . 3-3-10 (p227).. (5) (P231).. 2a 1 10 % 40 . mm2/s.

8 2b . 1 10 % 40 . mm2/s . mm2/s .. 2 JIS 2 .. 20. GHS . 4.. 4-3-1 ( )(p243). ( ) .. ( ) .. (1) .. (2) GHS A B C 3 .. (2-1) A. 2-1-1 3 ( ) . 2-1-1-1 ( 4-2-1 ). 3 .. 2-1-1-2 ( 4-3-1-4 ). 2-1-1-1 .. 2-1-2 . 2-1-1 3 .. (2-2) B. 2-2-1 3 1 .. 2-2-2 2-2-1 .. (2-3) C.. (3) .. 21. GHS . 4-2-1 .. Ci i ( ). L(E)C50i i LC50 EC50(mg/l). n (i 1 n ). L(E)C50m L(E)C50.. 1 4-3-1-4 . 4-3-1-3 . (%) . 1 M 25% 1. (M 10 1)+ 2 25% 2. (M 100 1)+(10 2)+ 3 25% 3. 4-3-1-4 M. M. 1 1. 10. 100. 1000. 10000. ( 10 ). 22. GHS . ( ) .. (1) .. (2) GHS A B C 3 .. (2-1) A. 2-1-1 . 2-1-1-1 ( 4-2-2 ). 3 .. 2-1-1-2 ( 4-3-1-5 ). 2-1-1-1 .. 2-1-2 . 1 3 .. (2-2) B. 2-2-1 3 1 . 2-2-2 2-2-1.

9 (2-3) C.. (3) .. 23. GHS . 4-2-2 .. Ci i ( ). Cj j ( ). NOECi i NOEC( . )(mg/l). NOECj j NOEC( . )(mg/l). n (i j 1 n ). EqNOECm NOEC. 1 4-3-1-4 . 4-3-1-6( ) M. M M. L(E)C50 NOEC NRD RD . L(E)C50 1 1 NOEC 1 . L(E)C50 10 NOEC 10 1. L(E)C50 100 NOEC 100 10. L(E)C50 1000 NOEC 1000 100.. 10000 10000 1000. L(E)C50 NOEC ( 10 ) ( 10 ). NRD RD . 4-3-1-5( ) . (%) . 1 M 25% 1. (M 10 1)+ 2 25% 2. (M 100 1)+(10 2)+ 3 25% 3. 1+ 2+ 3+ 4 25 % 4. 4 .. 4 .. 24. GHS . 4-3-2 .. (4) .. 1 . 25.