Tide Revision Date - P&G

1 This Safety Data Sheet (SDS) is not required under local legislation, implementing the UN Globally Harmonized System(GHS). This SDS is being provided as a courtesy to help assist in the safe handling and proper use of the productSAFETY DATA SHEETI ssuing date : 17-Dec-2015 Revision date : 25-Oct-2016 Version 31. IDENTIFICATIONP roduct NameTideProduct Identifier90785649_RET_NGProduct Type:Finished Product - Consumer (Retail) Use OnlyRecommended UseLaundry on UseUse only as directed on of the supplier of the safetydata sheetPROCTER & GAMBLE - Fabric and Home Care DivisionIvorydale Technical Centre 5289 Spring Grove Avenue Cincinnati, Ohio 45217-1087 USAP rocter & Gamble Box 355, Station AToronto, ON M5W 1C51-800-331-3774E-mail TelephoneTransportation (24 HR)CHEMTREC - 1-800-424-9300( Canada) or 1-703-527-3887 Mexico toll free in country: 800-681-95312.

2 HAZARD IDENTIFICATION"Consumer Products", as defined by the US Consumer Product Safety Act and which are used as intended (typical consumerduration and frequency), are exempt from the OSHA Hazard Communication Standard (29 CFR ). This SDS is beingprovided as a courtesy to help assist in the safe handling and proper use of the product is classifed under 29 CFR (d) and the Canadian Hazardous Products Regulation as follows:.Hazard Category Skin corrosion/irritationCategory 2 Eye Damage / IrritationCategory 2 ASignal WordWARNINGH azard StatementsCauses serious eye irritationCauses skin irritationHazard pictogramsPage 1 / 890785649_RET_NG - TideRevision date : 25-Oct-20163. COMPOSITION/INFORMATION ON INGREDIENTSI ngredients are listed according to 29 CFR Appendix D and the Canadian Hazardous Products Regulation 4.

3 FIRST AID MEASURESF irst aid measures for different exposure routesEye contactRinse with plenty of water. Get medical attention immediately if irritation contactRinse with plenty of water. Get medical attention if irritation develops and 1 or 2 glasses of water. Do NOT induce vomiting. Get medical attention immediately ifPrecautionary StatementsWash hands thoroughly after handlingPrecautionary Statements -ResponseIF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsingIf eye irritation persists: Get medical advice/attentionIF SWALLOWED:Drink 1 or 2 glasses of waterIF ON SKIN:Rinse with plenty of waterIf skin irritation occurs, get medical advice/attentionPrecautionary Statements - StorageNonePrecautionary Statements - DisposalNoneHazards not otherwise classified(HNOC)NoneChemical NameSynonymsTrade SecretCAS-NoWeight %Sodium carbonateCarbonic acid sodiumsalt (1:2)No497-19-825 - 30 Benzenesulfonic acid,mono-C10-16-alkyl derivs.

4 , sodiumsaltsBenzenesulfonic acid,mono-C10-16-alkylderivs., sodium saltsNo68081-81-210 - 15 Silicic acid, aluminum sodium saltSilicic acid, aluminumsodium saltNo1344-00-910 - 15 Carbonic acid disodium salt, hydrogen peroxideCarbonic acid disodiumsalt, compd. withhydrogen peroxideNo15630-89-45 - 10 Sodium2-(nonanoyloxy)benzenesulfonateNon anoic acid,sulfophenyl ester,sodium salt (1:1)No91125-43-81 - 5 Silicic acid, sodium saltSilicic acid, sodium saltNo1344-09-81 - 5 Poly(oxy-1,2-ethanediyl),alpha-sulfo-ome ga-hydroxy-,C10-16-alkyl ethers, sodium saltsPoly(oxy-1,2-ethanediyl),alpha-sulf o-omega-hydroxy-, C10-16-alkyl ethers,sodium saltsNo68585-34-21 - 5 Page 2 / 890785649_RET_NG - TideRevision date : 25-Oct-2016symptoms to fresh air. If symptoms persist, call a important symptoms/effects,acute and delayedNone under normal use of immediate medical attention and special treatment needed, if necessaryNotes to PhysicianTreat FIRE-FIGHTING MEASURESS uitable extinguishing mediaDry chemical, CO 2, alcohol-resistant foam or water Extinguishing hazardNone protective equipment forfire-fightersAs in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH(approved or equivalent) and full protective hazards arising from ACCIDENTAL RELEASE MEASURESP ersonal precautions, protective equipment and emergency proceduresPersonal precautionsUse personal protective equipment.

5 Do not get in eyes, on skin, or on for emergency respondersUse personal protective equipment as and materials for containment and cleaning upMethods for containmentPrevent dust cloud. Prevent further leakage or spillage if safe to do for cleaning upSweep up and shovel into suitable containers for disposal. Dispose of in accordance withlocal HANDLING AND STORAGEP recautions for safe handlingAdvice on safe handlingUse personal protective equipment as required. Keep container closed when not in return spills in original containers for re-use. Keep out of the reach of for safe storage, including any incompatibilities Storage ConditionsKeep containers tightly closed in a dry, cool and well-ventilated productsNone EXPOSURE CONTROLS/PERSONAL PROTECTIONC ontrol parametersExposure 3 / 890785649_RET_NG - TideRevision date : 25-Oct-2016 Chemical NameCAS-NoAlbertaQuebecOntario TWAEVB ritish ColumbiaSilicic acid, aluminum sodiumsalt1344-00-9 TWA: 1 mg/m3 TWA: mg/m3No relevant exposure guidelines for other ingredientsExposure controlsEngineering Measures Distribution, Workplace and Household Settings:Ensure adequate ventilation Product Manufacturing Plant (needed at Product-Producing Plant ONLY).

6 Where reasonably practicable this should be achieved by the use of local exhaustventilation and good general extractionPersonal Protective Equipment Eye Protection Distribution, Workplace and Household Settings:No special protective equipment required Product Manufacturing Plant (needed at Product-Producing Plant ONLY):Use appropriate eye protectionHand Protection Distribution, Workplace and Household Settings:For sensitive skin or prolonged use, wear gloves Product Manufacturing Plant (needed at Product-Producing Plant ONLY):Protective glovesSkin and Body Protection Distribution, Workplace and Household Settings:No special protective equipment required Product Manufacturing Plant (needed at Product-Producing Plant ONLY):Wear suitable protective clothingRespiratory Protection Distribution, Workplace and Household Settings:No special protective equipment required Product Manufacturing Plant (needed at Product-Producing Plant ONLY):In case of inadequate ventilation wear respiratory protection9.

7 PHYSICAL AND CHEMICAL PROPERTIESP hysical State @20 CSolidAppearancewhite powder blue specksOdorScentedOdor thresholdNo information availableProperty Values Note pH value10 - pointNo information availableBoiling point/boiling rangeNo information availableFlash pointNo information rateNo information availableFlammability (solid, gas)No information availableFlammability Limits in AirUpper flammability limitNo information availableLower Flammability LimitNo information availablePage 4 / 890785649_RET_NG - TideRevision date : 25-Oct-2016 VOC Content (%)Products comply with US state and federal regulations for VOC content in STABILITY AND REACTIVITYR eactivityNone under normal use under normal polymerizationHazardous polymerization does not ReactionsNone under normal to AvoidNone under normal to avoidNone in Decomposition ProductsNone under normal use TOXICOLOGICAL INFORMATIONP roduct Information Information on likely routes of exposureInhalationNo known contactIrritating to known contactCauses serious eye and immediate effects as well as chronic effects from short and long-term exposureAcute toxicityNo known corrosion/irritationIrritating to eye damage/eye irritationCauses serious eye sensitizationNo known sensitizationNo known cell mutagenicityNo known EffectsNo known toxicityNo known toxicityNo known

8 Known - single exposureNo known - repeated exposureNo known Organ EffectsNo known hazardNo known known Information Chemical NameCAS-NoOral LD50 Dermal LD50 Inhalation LC50 Sodium carbonate497-19-82800 mg/kg bw> 2000 mg/kg bw (US EPA16 CFR )-Silicic acid, aluminum sodium salt1344-00-9> 10000 mg/kg bw(//OECD 401)> 5000 mg/kg bw (//OECD402)> mg/L air (//OECD403)Carbonic acid disodium salt, hydrogen peroxide15630-89-4893 mg/kg bw ( EPAO ffice of Pesticides and> 2000 mg/kg bw (EPAG uideline; standard acute-Vapor pressureNo information availableVapor densityNo information availableRelative density 400 - 650 g/lWater solubilityNo information availablePartition coefficient: n-octanol/waterNo information availableAutoignition temperatureNo information temperatureNo information of ProductNo information availablePage 5 / 890785649_RET_NG - TideRevision date : 25-Oct-2016 Toxic Substances (1984)"Acute Exposure OralToxicity"; standard acutemethod; rat)method; rabbit)Silicic acid, sodium salt1344-09-83400 mg/kg bw (Similar toOECD 401; standard acutemethod; rat)> 5000 mg/kg bw (Readacross data on AgSil TM25 Potassium silicatesolution; rat)> mg/L air (Readacross data AgSil TM 25 Potassium silicate solution;EPA OPPTS ;standard acute method.)

9 Rat)Poly(oxy-1,2-ethanediyl),alpha-sulfo -omega-hydroxy-,C10-16-alkyl ethers, sodium salts68585-34-2>2001 mg/kg--12. ECOLOGICAL INFORMATIONE cotoxicity The product is not expected to be hazardous to the and degradabilityNo information potentialNo information information adverse effectsNo information DISPOSAL CONSIDERATIONSW aste treatmentWaste from Residues / UnusedProductsDisposal should be in accordance with applicable regional, national and local laws packagingDisposal should be in accordance with applicable regional, national and local laws Hazardous Waste Codes(non-household setting)33114. TRANSPORT INFORMATIONDOT Not regulatedIMDG Not regulatedIATA Not regulated15. REGULATORY Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA).

10 This product does not contain anychemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 CERCLAThis material, as supplied, contains one or more substances regulated as a hazardous substance under the ComprehensiveEnvironmental Response Compensation and Liability Act (CERCLA) (40 CFR 302):.Page 6 / 890785649_RET_NG - TideRevision date : 25-Oct-2016 Chemical NameCAS-NoHazardousSubstances RQsExtremely HazardousSubstances RQsCERCLA/SARA 302 TPQS ulphuric acid7664-93-91000 lb1000 lb1000 lbSodium hydroxide1310-73-21000 lb-Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61)This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air ActAmendments of Water ActThis product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 40 CFR ).