光硬化型樹脂 - Toagosei

1 Special Monomers and Oligomers M .. ARONIX M Series ARON OXETANE Series Toagosei 's light curable resins .. UV .. As a manufacturer of light curable resins, Toagosei owns world-leading technologies and provides two different series of products: ARONIX and ARON OXETANE. ARONIX is the brand name for special acrylic monomers and oligomers. We deal mainly in radically curable varieties. ARON OXETANE is the brand name for oxetane resin commercialized earlier by Toagosei than any other business in the world. Falling under the category of cationic curable resins, it is chiefly used in combination with epoxy resins. Both of them can be cured in a short time by irradiation, especially by that of ultraviolet rays, and have opened the way for products with a minimal solvent content to earn high marks as environmentally friendly products.

2 In addition, they have certain unique features unavailable with conventional resins and are used for a broad array of purposes, ranging from relatively general-purpose uses such as inks and coating agents, to data storage, electronic materials and other cutting-edge applications. Toagosei offers both radically curable resins and cationic curable resins to explore new possibilities of light curable resins. We offer a significant number of other ARONIX and ARON OXETANE products, in addition to those featured in the catalog. We will also undertake new product design and development, dilution with solvent, mixing of multiple brands, design of blended products and provision of products in the ARONIX UV Series upon request.

3 Please feel free to contact a Toagosei representative for any inquiries.. Types of ARONIX.. Aronix is classified according to the resin structure and the number of acryloyl groupes as listed in the following tables. Special acrylates .. Type of products Trade name Chemical Nomenclature General Code Characteristics M 101A EO n 2 . M 106 o EO n 1 . M 110 EO n 1. 2 . Monofunctional M 113 EO n 4 . M 120 2 EO n 2 . M 140 N . M 208 F EO n 2 . M 211B A EO n 2 .. M 215 EO . Bifunctional . M 220 n 3 TPGDA. M 240 n 4 TEGDA. M 309 TMPTA.. TMPTA M 321 PO n 2 POTMPTA.. M 350 EO n 1 EOTMPTA. THEIC M 315 EO . PETA M 305 PETA.. Multifunctional PETTA M 450 PETTA.

4 DTMP M 408 DTMPTA .. M 400 . DPHA DPHA. M 402. M 460 EO . M 5300 n 2 . COOH . M 5400 . Monofunctional M 5700 2 3 OH . M 510 COOH .. Multifunctional M 520 . Urethane acrylates .. Type of products Trade name Characteristics M 1100 . Bifunctional M 1200 . Polyester acrylates .. Type of products Trade name Characteristics M 6000 . Bifunctional M 7000 . M 8000 . Multifunctional M 9000 . Types of ARON OXETANE. Oxetane resins .. Type of products Trade name Chemical Nomenclature General Code Characteristics OXT 101 3 3 OXA . Monofunctional OXT 212 2 EHOX. OXT 121 XDO. Bifunctional OXT 221 3 3 3 3 DOX .. ARONIX. 1 .. Type of products Main Structural formula Color Viscosity Acid value Refractive APHA mPa s/ mgKOH/g index n D.

5 Trade name 25. M 101A n 2 300 10 20/25 CH2=CHCO_(OC2H4)n_O. M 102 n 4 300 20 40/25 EO . H2C=CHCO_(OC2H4)n_O. M 106 n 1 100 75 175/25 n o- EO . H2C=CHCO_(OC2H4)n_O. M 110 n 1. 2. n 100 100 210/25 EO .. M 111 CH2=CHCO_(OC2H4)n_O C9H19 n 1 350 60 90/25 . M 113 Monofunctional n 4 200 80 110/25 EO . CH2=CHCO_(OC3H6)n_O C9H19. M 117 200 90 140/25 PO n . CH2=CHCO_(OC2H4)2_OCH2CH(C2H5)C4H9. M 120 150 4 7/25 2 EO n 2 . O. C. CH2=CHCOO_C2H4 _N. M 140 C 500 350 550/25 O. N . CH2=CH_CO_(OC2H4)n_O. CH2. M 208 CH2=CH_CO_(OC2H4)n_O 150 500 700/25 F EO n 2 . CH2=CH_CO_(OC2H4)n_O. CH3_C_CH3. M 211B 300 950 1,350/25 CH2=CH_CO_(OC2H4)n_O. A EO n 2 . O. HO CH2CH2 CH2CH2 OCOCH=CH2.

6 N N.. M 215 O N O 100 3,500 15,000/25 CH2CH2 OCOCH=CH2. Bifunctional EO . M 220. n 3 250 8 16/25 TPGDA . M 225 CH2=CHCO_(OC3H6)n_OCOCH=CH2 n 7 200 30 40/25 PPGDA . M 270. n 12 200 65 85/25 PPGDA . M 240 CH2=CHCO_(OCH2CH2)n_OCOCH=CH2. 100 13 24/25 TEGDA n 4 . 1 before curing liquid . The data shown in the table is based on the results of experiments conducted with the utmost care, but they are not meant to guarantee actual shop- oor results. 2) A circle ( ) symbol represents that a reference has been con rmed. A cross ( ) symbol represents that there is no reference or that the reference has not been con rmed. Please refer to our sales division for further information.

7 Our checks have been performed with the utmost care but we ask that you perform your own checks before use. 3.. 2 . Registration Properties of cured film .. Inhibitor Skin irritation Tg Package Characteristics Flash point Tensile strength Elongation . ppm METI TSCA ECL CRC. MPa .. 17kg 177 170 8 . 190kg 186 240 18 17kg . 18kg 193 210 30 . 200kg 201 470 300 35 17kg . 17kg 156 90 250 17 . 190kg 17kg 224 130 50 20 Tg . 190kg 17kg 195 160 60 3 . 190kg 16kg . 140 480 65. 180kg Tg .. 460/. 190. HQ. LVE 0 5 56 18kg .. 155 18kg .. 770 58 5 75. 200kg . 210 18kg . 460 52 0 10 75. 200kg . 4 9 . 18kg OH . 35 1470 49 0 10 166. 200kg .. 17kg . 157 370 24 0 5 90.

8 200kg . 17kg PPG#400. 208 100 10 8. 190kg . 240 17kg .. 110 5 32. 190kg PPG#700. 154 18kg PEG#200. 200 19 0 10 50. 200kg .. 2 .. 4. 1 .. Type of products Main Structural formula Color Viscosity Acid value Refractive APHA mPa s/ mgKOH/g index n D . Trade name 25. M 309 (CH2=CHCOOCH2)3_CCH2CH3 200 60 110/25 TMPTA .. M 310 n 1 160 60 110/25 [CH2=CHCO_(OC3H6)n_OCH2]3_CCH2CH3.. M 321 n 2 300 70 170/25 POTMPTA TMPTA . PO . Multifunctional M 350. n 1 100 45 65/25 EOTMPTA . [CH2=CHCO_(OC2H4)n_OCH2]3_CCH2CH3. M 360 n 2 200 65 90/25 EO .. M 313 100 20,000 36,000/25 O 30 40. CH2=CHCOOCH2CH2 CH2CH2_O_R. N N.. THEIC O N O. CH2CH2 OCOCH=CH2. Multifunctional 500.

9 M 315 600 1,200/50 . 3 13 . EO . M 306 . 150 400 650/25 PETA 65 70. M 305 . 100 180 800/25 PETA 55 63.. (CH2=CHCOOCH2)3_C_CH2_O_R. M 303 . R="H" "COCH=CH2" 300 500 1,200/25 . PETA PETA . PETTA 40 60. Multifunctional M 452 . 100 . PETTA 25 40 300 800/25. M 450 . 200 60 100/50 . PETTA 10. ( ).. CH2=CH_COOCH2. M 408 CH3CH2_C_CH2_O 300 470 670/25 DTMPTA DTMP . CH2=CH_COOCH2 2. Multifunctional . 1 before curing liquid . The data shown in the table is based on the results of experiments conducted with the utmost care, but they are not meant to guarantee actual shop-floor results. 2) A circle ( ) symbol represents that a reference has been confirmed.

10 A cross ( ) symbol represents that there is no reference or that the reference has not been confirmed. Please refer to our sales division for further information. Our checks have been performed with the utmost care but we ask that you perform your own checks before use.. 2 . Registration Properties of cured film .. Inhibitor Skin irritation Tg Package Characteristics Flash point Tensile strength Elongation . ppm METI TSCA ECL CRC. MPa .. 250 18kg 167 100 23 0 5 . 200kg 190 . 430 17 0 5 120 18kg .. 230 18kg 450 25 5 50. 200kg 178 18kg 290 44 3 . 200kg 200 . 960 28 5 53 18kg . 180 250 18kg . 550 35 0 5. 200kg .. 164 250 18kg 1270 69 0 10 . 200kg.