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Lecture 3 Sorption equilibrium - CHERIC

Lecture 3. Sorption equilibrium Pure Gas Adsorption-Linear isotherm-Freundlichisotherm-Langmuir isotherm-Other adsorption isotherms-BET isotherm Gas Mixtures and Extended Isotherms Liquid Adsorption Ion-Exchange EquilibriaAdsorption equilibrium Dynamic equilibrium in adsorption: solute distribution between fluid and solid surface-[concentration (if the fluid is a liquid) or partial pressure (if the fluid is a gas) of the adsorbatein the fluid] vs. [solute loading on the adsorbent (mass, moles, or volume of adsorbateper unit mass or surface area)] Adsorption isotherm: equilibrium data at a constant temperature-A limit on the extent to which a solute is adsorbed from a specific fluid mixture on a given adsorbent for one set of conditionsClassification of Adsorption Isotherms (1) Type I isotherm-Typical

adsorbent (mass, moles, or volume of adsorbateper unit mass or surface area)] •Adsorption isotherm: equilibrium data at a constant temperature-A limit on the extent to which a solute is adsorbed from a specific fluid mixture on a given adsorbent for one set of conditions.

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